The DOI matches its Crossref record; 18 of the 18 references it cites were found in a registry or an index.
Polyethylene Devices: Passive Samplers for Measuring Dissolved Hydrophobic Organic Compounds in Aquatic Environments
Abstract
We demonstrate the use of polyethylene devices (PEDs) for assessing hydrophobic organic compounds (HOCs) in aquatic environments. Like semipermeable membrane devices (SPMDs) and solid-phase microextraction (SPME), PEDs passively accumulate HOCs in proportion to their freely dissolved concentrations. Polyethylene-water partition constants (K(PEW)S) were measured in the laboratory for eight polycyclic aromatic hydrocarbons (PAHs), five polychlorinated biphenyls (PCBs), and one polychlorinated dibenzop-dioxin (PCDD), and these were found to correlate with octanol-water partition constants (K(OW)s; log K(PEW) = 1.13 log K(OW) - 0.86, R2 = 0.89). Temperature and salinity dependencies of K(PEW) values for the HOCs tested were well predicted with excess enthalpies of solution in water and Setschenow constants, respectively. We also showed that standards, impregnated in the PED before deployment, can be used to correct for incomplete equilibrations. Using PEDs, we measured phenanthrene and pyrene at ng/L concentrations and 2,2',5,5'-tetrachlorobiphenyl at pg/L concentrations in Boston Harbor seawater, consistent with our findings using traditional procedures. PEDs are cheap and robust samplers, competent to accomplish in situ, time-averaged passive sampling with fast equilibration times (approximately days) and simplified laboratory analyses.
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Citations
Cites
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Self-citationCalibrating the uptake kinetics of semipermeable membrane devices using exposure standards
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Use of Passive Samplers To Mimic Uptake of Polycyclic Aromatic Hydrocarbons by Benthic Polychaetes
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Cited by
Microplastics in the marine environment
Andrady, A. L. (2011) · Marine Pollution Bulletin · doi:10.1016/j.marpolbul.2011.05.030 · Cited by 8,105
Strong Sorption of PCBs to Nanoplastics, Microplastics, Carbon Nanotubes, and Fullerenes
Velzeboer, I., Kwadijk, C. J. A. F., & Koelmans, A. A. (2014) · Environmental Science & Technology · doi:10.1021/es405721v · Cited by 939
Environmental Factors Support the Formation of Specific Bacterial Assemblages on Microplastics
Oberbeckmann, S., Kreikemeyer, B., & Labrenz, M. (2018) · Frontiers in Microbiology · doi:10.3389/fmicb.2017.02709 · Cited by 549
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Lohmann, R. (2017) · Integrated Environmental Assessment and Management · doi:10.1002/ieam.1914 · Cited by 204
Self-citation
Metadata
- Authors
- Adams, R. G., Lohmann, R., Fernandez, L. A., MacFarlane, J. K., & Gschwend, P. M.
- Venue
- Environmental Science & Technology
- Publisher
- American Chemical Society (ACS)
- Published
- 2007-01-13
- Volume
- 41
- Issue
- 4
- Pages
- 1317-1323
- ISSN
- 0013-936X (ISSN-L)
- 1520-5851
- OpenAlex
- W2068284889
- Cited by
- 287
- References
- 18
- FWCI
- 9.71
- Type
- journal article
- Language
- en
- Open access
- closed
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