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Cited by 507

The DOI matches its Crossref record; 22 of the 22 references it cites were found in a registry or an index.

Effect of Dissolved Organic Matter on the Transformation of Contaminants Induced by Excited Triplet States and the Hydroxyl Radical

Open access
Wenk, Jannis, von Gunten, Urs, Canonica, Silvio·2011·Environmental Science & Technology

Abstract

Dissolved organic matter (DOM) has recently been shown to reduce the transformation rate of various aqueous organic contaminants submitted to oxidation by excited triplet states, apparently by inhibiting the transformation of oxidation intermediates. The main goals of the present study were to evaluate in more detail the effect of concentration and type of DOM on the triplet-induced transformation rate of four selected organic compounds and to check for an analogous inhibition effect in the case of oxidation induced by hydroxyl radical. A marked inhibition by DOM of triplet-induced oxidation was observed for N,N-dimethylaniline (DMA) and the two antibiotics sulfamethoxazole (SMX) and trimethoprim (TRI), with DOM of terrestrial origin being a more effective inhibitor than DOM of aquatic origin. The results are important to understand the role of DOM both as a photosensitizer and as an inhibitor for the triplet-induced transformation of aquatic contaminants. In contrast, no DOM-induced reduction in second-order rate constant could be observed in competition kinetics experiments for the reaction of hydroxyl radical with a series of 15 organic compounds, covering several classes of aromatic contaminants, indicating that Suwannee River fulvic acid (SRFA) used as reference DOM does not affect this reaction mechanism.

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Metadata

Authors
Wenk, J., von Gunten, U., & Canonica, S.
Venue
Environmental Science & Technology
Published
2011-01-27
Volume
45
Issue
4
Pages
1334-1340
ISSN
  • 0013-936X (ISSN-L)
  • 1520-5851
OpenAlex
W2157189768
Cited by
507
References
22
FWCI
24.33
Type
journal article
Language
en
Open access
green

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