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Cited by 259

The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.

Role of Hydroxyl Radicals and Mechanism of Escherichia coli Inactivation on Ag/AgBr/TiO2 Nanotube Array Electrode under Visible Light Irradiation

Hou, Yang, Li, Xinyong, Zhao, Qidong, Chen, Guohua, Raston, Colin L.·2012·Environmental Science & Technology

Abstract

A ternary Ag/AgBr/TiO(2) nanotube array electrode with enhanced visible-light activity was synthesized by a two-step approach including electrochemical process of anodization and an in situ photoassisted deposition strategy. The dramatically enhanced photoelectrocatalytic activity of the composite electrode was evaluated via the inactivation of Escherichia coli under visible light irradiation (λ>420 nm), whose performance of complete sterilization was much superior to other reference photocatalysts. PL, ESR, and radicals trapping studies revealed hydroxyl radicals were involved as the main active oxygen species in the photoelectrocatalytic reaction. The process of the damage of the cell wall and the cell membrane was directly observed by ESEM, TEM, and FTIR, as well as further confirmed by determination of potassium ion leakage from the killed bacteria. The present results pointed to oxidative attack from the exterior to the interior of the Escherichia coli by OH(•), O(2)(•-), holes and Br(0), causing the cell to die as the primary mechanism of photoelectrocatalytic inactivation.

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Metadata

Authors
Hou, Y., Li, X., Zhao, Q., Chen, G., & Raston, C. L.
Venue
Environmental Science & Technology
Published
2012-03-13
Volume
46
Issue
7
Pages
4042-4050
ISSN
  • 0013-936X (ISSN-L)
  • 1520-5851
OpenAlex
W2079715857
Cited by
259
References
1
FWCI
8.75
Type
journal article
Language
en
Open access
closed

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