The DOI matches its Crossref record; 9 of the 9 references it cites were found in a registry or an index.
Bisolute Sorption and Thermodynamic Behavior of Organic Pollutants to Biomass-derived Biochars at Two Pyrolytic Temperatures
Abstract
The bisolute sorption and thermodynamic behavior of organic pollutants on low temperature biochars (LTB) at 300 °C and high temperature biochars (HTB) at 700 °C were determined to elucidate sorptive properties of biochar changed with pyrolytic temperatures. The structural characteristics and isotherms shape of the biochar were more dependent on the pyrolytic temperature than on the biomass feedstocks, which included orange peel, pine needle, and sugar cane bagasse. For LTB, the thermally altered organic matter colocalized with the carbonized matter, and the visible fine pores of the fixed carbons were plugged by the remaining volatile carbon. For HTB, most of the volatile matter was gone and the fixed matter was composed of fully carbonized adsorptive sites. Monolayer adsorption of 1-naphthol to HTB was dominant but was suppressed by phenol. In comparison, LTB displayed exceptional sorption behavior where partition and adsorption were concurrently promoted by a cosolute and elevated temperature. In addition to monolayer surface coverage, pore-filling mechanisms may contribute to the increase of adsorption fraction. Moreover, the entropy gain was a dominant force driving the partition and adsorption processes in LTB. Thus, the colocalizing partition phase and adsorptive sites in LTB are proposed to be in interencased states rather than in physical separation.
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Cites
Characteristics of hemicellulose, cellulose and lignin pyrolysis
Yang, H., Yan, R., Chen, H., Lee, D. H., & Zheng, C. (2007) · Fuel · doi:10.1016/j.fuel.2006.12.013 · Cited by 8,155
Dynamic Molecular Structure of Plant Biomass-Derived Black Carbon (Biochar)
Keiluweit, M., Nico, P. S., Johnson, M. G., & Kleber, M. (2010) · Environmental Science & Technology · doi:10.1021/es9031419 · Cited by 3,230
Lehmann, J. (2007) · Nature · doi:10.1038/447143a · Cited by 2,477
Chen, B., Zhou, D., & Zhu, L. (2008) · Environmental Science & Technology · doi:10.1021/es8002684 · Cited by 1,823
Self-citationCompositions and sorptive properties of crop residue-derived chars
Chun, Y., Sheng, G., Chiou, C. T., & Xing, B. (2004) · Environmental Science & Technology · doi:10.1021/es035034w · Cited by 1,079
Simultaneous immobilization of lead and atrazine in contaminated soils using dairy-manure biochar
Cao, X., Ma, L., Liang, Y., Gao, B., & Harris, W. (2011) · Environmental Science & Technology · doi:10.1021/es103752u · Cited by 584
Kookana, R. S. (2010) · Soil Research · doi:10.1071/sr10007 · Cited by 280
Enhanced sorption of polycyclic aromatic hydrocarbons by soil amended with biochar
Chen, B., & Yuan, M. (2011) · Journal of Soils and Sediments · doi:10.1007/s11368-010-0266-7 · Cited by 271
Self-citationSorption of Deisopropylatrazine on Broiler Litter Biochars
Uchimiya, M., Wartelle, L. H., Lima, I. M., & Klasson, K. T. (2010) · Journal of Agricultural and Food Chemistry · doi:10.1021/jf102152q · Cited by 182
Cited by
Application of biochar for the removal of pollutants from aqueous solutions
Tan, X., Liu, Y., Zeng, G., Wang, X., Hu, X., Gu, Y., & Yang, Z. (2015) · Chemosphere · doi:10.1016/j.chemosphere.2014.12.058 · Cited by 2,081
Zhu, X., Chen, B., Zhu, L., & Xing, B. (2017) · Environmental Pollution · doi:10.1016/j.envpol.2017.04.032 · Cited by 1,021
Self-citationXiao, X., Chen, B., Chen, Z., Zhu, L., & Schnoor, J. L. (2018) · Environmental Science & Technology · doi:10.1021/acs.est.7b06487 · Cited by 914
Self-citationAmbaye, T. G., Vaccari, M., van Hullebusch, E. D., Amrane, A., & Rtimi, S. (2021) · International Journal of Environmental Science and Technology · doi:10.1007/s13762-020-03060-w · Cited by 886
Fang, G., Gao, J., Liu, C., Dionysiou, D. D., Wang, Y., & Zhou, D. (2014) · Environmental Science & Technology · doi:10.1021/es4048126 · Cited by 802
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Metadata
- Authors
- Chen, Z., Chen, B., Zhou, D., & Chen, W.
- Venue
- Environmental Science & Technology
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-11-09
- Volume
- 46
- Issue
- 22
- Pages
- 12476-12483
- ISSN
- 0013-936X (ISSN-L)
- 1520-5851
- OpenAlex
- W2313294126
- Cited by
- 175
- References
- 9
- FWCI
- 6.98
- Type
- journal article
- Language
- en
- Open access
- closed
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