The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
An Iodide-Adduct High-Resolution Time-of-Flight Chemical-Ionization Mass Spectrometer: Application to Atmospheric Inorganic and Organic Compounds
Abstract
A high-resolution time-of-flight chemical-ionization mass spectrometer (HR-ToF-CIMS) using Iodide-adducts has been characterized and deployed in several laboratory and field studies to measure a suite of organic and inorganic atmospheric species. The large negative mass defect of Iodide, combined with soft ionization and the high mass-accuracy (<20 ppm) and mass-resolving power (R>5500) of the time-of-flight mass spectrometer, provides an additional degree of separation and allows for the determination of elemental compositions for the vast majority of detected ions. Laboratory characterization reveals Iodide-adduct ionization generally exhibits increasing sensitivity toward more polar or acidic volatile organic compounds. Simultaneous retrieval of a wide range of mass-to-charge ratios (m/Q from 25 to 625 Th) at a high frequency (>1 Hz) provides a comprehensive view of atmospheric oxidative chemistry, particularly when sampling rapidly evolving plumes from fast moving platforms like an aircraft. We present the sampling protocol, detection limits and observations from the first aircraft deployment for an instrument of this type, which took place aboard the NOAA WP-3D aircraft during the Southeast Nexus (SENEX) 2013 field campaign.
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Cites
High levels of nitryl chloride in the polluted subtropical marine boundary layer
Osthoff, H. D., Roberts, J. M., Ravishankara, A. R., Williams, E. J., Lerner, B. M., Sommariva, R., Bates, T. S., Coffman, D., Quinn, P. K., Dibb, J. E., et al. (2008) · Nature Geoscience · doi:10.1038/ngeo177 · Cited by 483
Cited by
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Self-citationLee, B. H., Mohr, C., Lopez-Hilfiker, F. D., Lutz, A., Hallquist, M., Lee, L., Romer, P., Cohen, R. C., Iyer, S., Kurtén, T., et al. (2016) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1508108113 · Cited by 389
Self-citationPhotochemical processing of aqueous atmospheric brown carbon
Zhao, R., Lee, A. K. Y., Huang, L., Li, X., Yang, F., & Abbatt, J. P. D. (2015) · Atmospheric Chemistry and Physics · doi:10.5194/acp-15-6087-2015 · Cited by 373
Veres, P. R., Neuman, J. A., Bertram, T. H., Assaf, E., Wolfe, G. M., Williamson, C. J., Weinzierl, B., Tilmes, S., Thompson, C. R., Thames, A. B., et al. (2020) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1919344117 · Cited by 328
A large and ubiquitous source of atmospheric formic acid
Millet, D. B., Baasandorj, M., Farmer, D. K., Thornton, J. A., Baumann, K., Brophy, P., Chaliyakunnel, S., de Gouw, J. A., Graus, M., Hu, L., et al. (2015) · Atmospheric Chemistry and Physics · doi:10.5194/acp-15-6283-2015 · Cited by 301
Self-citationHuang, W., Saathoff, H., Pajunoja, A., Shen, X., Naumann, K.-H., Wagner, R., Virtanen, A., Leisner, T., & Mohr, C. (2018) · Atmospheric Chemistry and Physics · doi:10.5194/acp-18-2883-2018 · Cited by 129
Self-citationLow temperature thermal treatment of gas-phase fluorotelomer alcohols by calcium oxide
Riedel, T. P., Wallace, M. A. G., Shields, E. P., Ryan, J. V., Lee, C. W., & Linak, W. P. (2021) · Chemosphere · doi:10.1016/j.chemosphere.2021.129859 · Cited by 47
Gaffney, J. S., & Marley, N. A. (2021) · ACS Earth and Space Chemistry · doi:10.1021/acsearthspacechem.1c00143 · Cited by 29
Metadata
- Authors
- Lee, B. H., Lopez-Hilfiker, F. D., Mohr, C., Kurtén, T., Worsnop, D. R., & Thornton, J. A.
- Venue
- Environmental Science & Technology
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-05-21
- Volume
- 48
- Issue
- 11
- Pages
- 6309-6317
- ISSN
- 0013-936X (ISSN-L)
- 1520-5851
- OpenAlex
- W2319053189
- Cited by
- 602
- References
- 1
- FWCI
- 9.52
- Type
- journal article
- Language
- en
- Open access
- closed
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