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Negative pH and Extremely Acidic Mine Waters from Iron Mountain, California

Nordstrom, Darrell Kirk, Alpers, Charles N., Ptacek, Carol J., Blowes, David W.·2000·Environmental Science & Technology

Abstract

Extremely acidic mine waters with pH values as low as −3.6, total dissolved metal concentrations as high as 200 g/L, and sulfate concentrations as high as 760 g/L, have been encountered underground in the Richmond Mine at Iron Mountain, CA. These are the most acidic waters known. The pH measurements were obtained by using the Pitzer method to define pH for calibration of glass membrane electrodes. The calibration of pH below 0.5 with glass membrane electrodes becomes strongly nonlinear but is reproducible to a pH as low as −4. Numerous efflorescent minerals were found forming from these acid waters. These extreme acid waters were formed primarily by pyrite oxidation and concentration by evaporation with minor effects from aqueous ferrous iron oxidation and efflorescent mineral formation.

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Metadata

Authors
Nordstrom, D. K., Alpers, C. N., Ptacek, C. J., & Blowes, D. W.
Venue
Environmental Science & Technology
Published
1999-12-10
Volume
34
Issue
2
Pages
254-258
ISSN
  • 0013-936X (ISSN-L)
  • 1520-5851
OpenAlex
W2009172246
Cited by
545
References
0
FWCI
10.41
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Negative pH and Extremely Acidic Mine Waters from Iron Mountain, California. https://app.cochat.ai/papers/10.1021/es990646v
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Nordstrom, D. K., Alpers, C. N., Ptacek, C. J., & Blowes, D. W. (2000). Negative pH and Extremely Acidic Mine Waters from Iron Mountain, California. Environmental Science & Technology. https://doi.org/10.1021/es990646v

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