The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Complete Destruction of p-Nitrophenol in Aqueous Medium by Electro-Fenton Method
Abstract
An indirect electrochemical method, which is very efficient for the degradation of organic pollutants in water, is described. The method, named electro-Fenton, is based on electrocatalytical generation of Fenton's reagent to produce hydroxyl radicals, which are very active toward organic compounds. An industrial pollutant, p -nitrophenol (PNP), was chosen for this study and was eventually mineralized. The major intermediary degradation products such as hydroquinone, benzoquinone, 4-nitrocatechol, 1,2,4-trihydroxybenzene and 3,4,5-trihydroxy- nitrobenzene were unequivocally identified by HPLC and GC-MS methods. The rate constants of the hydroxylation reactions were determined. The mineralization of the initial pollutant and the intermediates formed during electro-Fenton treatment was followed by total organic carbon (TOC) analyses. Dependence of mineralization on the amount of electrical energy consumed is shown by the relative decrease of TOC values. A mineralization reaction mechanism is proposed.
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Buxton, G. V., Greenstock, C. L., Helman, W. P., & Ross, A. B. (1988) · Journal of Physical and Chemical Reference Data · doi:10.1063/1.555805 · Cited by 12,332
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Pignatello, J. J., Oliveros, E., & MacKay, A. (2006) · Critical Reviews in Environmental Science and Technology · doi:10.1080/10643380500326564 · Cited by 4,133
Electro-Fenton Process and Related Electrochemical Technologies Based on Fenton’s Reaction Chemistry
Brillas, E., Sirés, I., & Oturan, M. A. (2009) · Chemical Reviews · doi:10.1021/cr900136g · Cited by 3,437
Self-citationRemoval of hydrophobic organic pollutants from soil washing/flushing solutions: A critical review
Trellu, C., Mousset, E., Pechaud, Y., Huguenot, D., van Hullebusch, E. D., Esposito, G., & Oturan, M. A. (2016) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2015.12.008 · Cited by 470
Self-citationPimentel, M., Oturan, N., Dezotti, M., & Oturan, M. A. (2008) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2008.02.011 · Cited by 438
Self-citationElectrochemistry: as cause and cure in water pollution—an overview
Vasudevan, S., & Oturan, M. A. (2014) · Environmental Chemistry Letters · doi:10.1007/s10311-013-0434-2 · Cited by 355
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Metadata
- Authors
- Oturan, M. A., Peiroten, J., Chartrin, P., & Acher, A. J.
- Venue
- Environmental Science & Technology
- Publisher
- American Chemical Society (ACS)
- Published
- 2000-07-13
- Volume
- 34
- Issue
- 16
- Pages
- 3474-3479
- ISSN
- 0013-936X (ISSN-L)
- 1520-5851
- OpenAlex
- W2087001183
- Cited by
- 547
- References
- 1
- FWCI
- 8.02
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
