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Formation of Hollow Ni2P Nanoparticles Based on the Nanoscale Kirkendall Effect
Abstract
Colloidal hollow nanoparticles (NPs) of Ni2P have been prepared by a one-pot reaction from a mixture of nickel acetate, oleylamine, trioctylphosphine (TOP), and 1-octadecene. The mechanism to the hollow structure is related to the nanoscale Kirkendall effect. The process contains two important steps. First, oleylamine-stabilized Ni NPs were formed, which can protect them from TOP etching and slow down the inward diffusion of P atoms. Second, the solid-state reaction between the Ni NPs occurred when the TOP concentration and the reaction temperature were correctly adjusted.
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Citations
Cited by
Nanostructured Nickel Phosphide as an Electrocatalyst for the Hydrogen Evolution Reaction
Popczun, E. J., McKone, J. R., Read, C. G., Biacchi, A. J., Wiltrout, A. M., Lewis, N. S., & Schaak, R. E. (2013) · Journal of the American Chemical Society · doi:10.1021/ja403440e · Cited by 2,911
Highly Active Electrocatalysis of the Hydrogen Evolution Reaction by Cobalt Phosphide Nanoparticles
Popczun, E. J., Read, C. G., Roske, C. W., Lewis, N. S., & Schaak, R. E. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201402646 · Cited by 1,240
Pan, Y., Liu, Y., Zhao, J., Yang, K., Liang, J., Liu, D., Hu, W., Liu, D., Liu, Y., & Liu, C. (2015) · Journal of Materials Chemistry A · doi:10.1039/c4ta04867a · Cited by 652
Callejas, J. F., Read, C. G., Popczun, E. J., McEnaney, J. M., & Schaak, R. E. (2015) · Chemistry of Materials · doi:10.1021/acs.chemmater.5b01284 · Cited by 509
Chen, N., Wang, H., Veeresh, P., Li, J., Oswald, J., Xi, L., Wagner, S., Sekol, R., Liu, V., Wang, K., et al. (2021) · Materials & Design · doi:10.1016/j.matdes.2020.109435 · Cited by 21
Metadata
- Authors
- Chiang, R.-K., & Chiang, R.-T.
- Venue
- Inorganic Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 2006-12-19
- Volume
- 46
- Issue
- 2
- Pages
- 369-371
- ISSN
- 0020-1669 (ISSN-L)
- 1520-510X
- OpenAlex
- W2033688638
- Cited by
- 266
- References
- 0
- FWCI
- 8.68
- Type
- journal article
- Language
- en
- Open access
- closed
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- Chiang, R.-K., & Chiang, R.-T. (2007). Formation of Hollow Ni2P Nanoparticles Based on the Nanoscale Kirkendall Effect. Inorganic Chemistry. https://doi.org/10.1021/ic061846s
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