The DOI matches its Crossref record; 52 of the 52 references it cites were found in a registry or an index.
Manifestations of Noninnocent Ligand Behavior
Abstract
The potential of redox-active ligands to behave "noninnocently" in transition-metal coordination compounds is reflected with respect to various aspects and situations. These include the question of establishing "correct" oxidation states, the identification and characterization of differently charged radical ligands, the listing of structural and other consequences of ligand redox reactions, and the distinction between barrierless delocalized "resonance" cases M(n)/L(n) ↔ M(n+1)L(n-1) versus separated valence tautomer equilibrium situations M(n)/L(n) ⇌ M(n+1)L(n-1). Further ambivalence arises for dinuclear systems with radical bridge M(n)(μ-L(•))M(n) versus mixed-valent alternatives M(n+1)(μ-L(-))M(n), for noninnocent ligand-bridged coordination compounds of higher nuclearity such as (μ(3)-L)M(3), (μ(4)-L)M(4), (μ-L)(4)M(4), or coordination polymers. Conversely, the presence of more than one noninnocently behaving ligand at a single transition-metal site in situations such as L(n)-M-L(n-1) or L(•)-M-L(•) may give rise to corresponding ligand-to-ligand interaction phenomena (charge transfer, electron hopping, and spin-spin coupling) and to redox-induced electron transfer with counterintuitive oxidation-state changes. The relationships of noninnocent ligand behavior with excited-state descriptions and perspectives regarding material properties and single-electron or multielectron reactivity are also illustrated briefly.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
(1999) · Choice Reviews Online · doi:10.5860/choice.37-0940 · Cited by 14,314
Mixed Valence Complexes of d 5 ‐ d 6 Metal Centers
Creutz, C. (1983) · Progress in Inorganic Chemistry · doi:10.1002/9780470166314.ch1 · Cited by 1,191
The Localized-to-Delocalized Transition in Mixed-Valence Chemistry
Demadis, K. D., Hartshorn, C. M., & Meyer, T. J. (2001) · Chemical Reviews · doi:10.1021/cr990413m · Cited by 1,074
Radical Ligands Confer Nobility on Base-Metal Catalysts
Chirik, P. J., & Wieghardt, K. (2010) · Science · doi:10.1126/science.1183281 · Cited by 926
Metals and DNA: Molecular Left-Handed Complements
Barton, J. K. (1986) · Science · doi:10.1126/science.3016894 · Cited by 752
Hawecker, J., Lehn, J.-M., & Ziessel, R. (1983) · J. Chem. Soc., Chem. Commun. · doi:10.1039/c39830000536 · Cited by 710
Hawecker, J., Lehn, J., & Ziessel, R. (1986) · Helvetica Chimica Acta · doi:10.1002/hlca.19860690824 · Cited by 688
Pierpont, C. G. (2001) · Coordination Chemistry Reviews · doi:10.1016/s0010-8545(01)00309-5 · Cited by 684
Chaudhuri, P., Verani, C. N., Bill, E., Bothe, E., Weyhermüller, T., & Wieghardt, K. (2001) · Journal of the American Chemical Society · doi:10.1021/ja003831d · Cited by 602
Non-innocent ligands in bioinorganic chemistry—An overview
Kaim, W., & Schwederski, B. (2010) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2010.01.009 · Cited by 564
Self-citationMolecular Quantum-Dot Cellular Automata
Lent, C. S., Isaksen, B., & Lieberman, M. (2003) · Journal of the American Chemical Society · doi:10.1021/ja026856g · Cited by 444
A Linear, O-Coordinated η 1 -CO 2 Bound to Uranium
Castro-Rodriguez, I., Nakai, H., Zakharov, L. N., Rheingold, A. L., & Meyer, K. (2004) · Science · doi:10.1126/science.1102602 · Cited by 362
Jørgensen, C. K. (1966) · Coordination Chemistry Reviews · doi:10.1016/s0010-8545(00)80170-8 · Cited by 349
Cramer, C. J., & Tolman, W. B. (2007) · Accounts of Chemical Research · doi:10.1021/ar700008c · Cited by 348
Bachler, V., Olbrich, G., Neese, F., & Wieghardt, K. (2002) · Inorganic Chemistry · doi:10.1021/ic0113101 · Cited by 335
Ray, K., Petrenko, T., Wieghardt, K., & Neese, F. (2007) · Dalton Transactions · doi:10.1039/b700096k · Cited by 322
Metal–dioxygen and metal–dinitrogen complexes: where are the electrons?
Holland, P. L. (2010) · Dalton Transactions · doi:10.1039/c001397h · Cited by 257
Nature of the Fe−O2Bonding in Oxy-Myoglobin: Effect of the Protein
Chen, H., Ikeda-Saito, M., & Shaik, S. (2008) · Journal of the American Chemical Society · doi:10.1021/ja805434m · Cited by 250
Smith, A. L., Hardcastle, K. I., & Soper, J. D. (2010) · Journal of the American Chemical Society · doi:10.1021/ja106212w · Cited by 246
Patra, S., Sarkar, B., Mobin, S. M., Kaim, W., & Lahiri, G. K. (2003) · Inorganic Chemistry · doi:10.1021/ic034469h · Cited by 214
Self-citationRedox-Switched Oxidation of Dihydrogen Using a Non-Innocent Ligand
Ringenberg, M. R., Kokatam, S. L., Heiden, Z. M., & Rauchfuss, T. B. (2008) · Journal of the American Chemical Society · doi:10.1021/ja076801k · Cited by 193
The quinoprotein dehydrogenases for methanol and glucose
Anthony, C. (2004) · Archives of Biochemistry and Biophysics · doi:10.1016/j.abb.2004.03.038 · Cited by 192
Trovitch, R. J., Lobkovsky, E., Bill, E., & Chirik, P. J. (2008) · Organometallics · doi:10.1021/om701091z · Cited by 187
Ruthenium complexes with non-innocent ligands: Electron distribution and implications for catalysis
Boyer, J. L., Rochford, J., Tsai, M.-K., Muckerman, J. T., & Fujita, E. (2010) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2009.09.006 · Cited by 183
Zhang, J., Du, P., Schneider, J., Jarosz, P., & Eisenberg, R. (2007) · Journal of the American Chemical Society · doi:10.1021/ja071789h · Cited by 181
Remenyi, C., & Kaupp, M. (2005) · Journal of the American Chemical Society · doi:10.1021/ja051811b · Cited by 170
“Oxidative Addition” to a Zirconium(IV) Redox-Active Ligand Complex
Blackmore, K. J., Ziller, J. W., & Heyduk, A. F. (2005) · Inorganic Chemistry · doi:10.1021/ic050997c · Cited by 169
Wanat, A., Schneppensieper, T., Stochel, G., van Eldik, R., Bill, E., & Wieghardt, K. (2002) · Inorganic Chemistry · doi:10.1021/ic010628q · Cited by 159
Four‐Electron Oxidative Formation of Aryl Diazenes Using a Tantalum Redox‐Active Ligand Complex
Zarkesh, R. A., Ziller, J. W., & Heyduk, A. F. (2008) · Angewandte Chemie International Edition · doi:10.1002/anie.200800812 · Cited by 153
Coordination compounds of pteridine, alloxazine and flavin ligands: structures and properties
Kaim, W., Schwederski, B. E., Heilmann, O., & Hornung, F. M. (1999) · Coordination Chemistry Reviews · doi:10.1016/s0010-8545(98)00193-3 · Cited by 137
Self-citationThe chemistry and biochemistry of the copper–radical interaction
Kaim, W. (2003) · Dalton Transactions · doi:10.1039/b210193a · Cited by 130
Self-citationZakharieva, O., Schünemann, V., Gerdan, M., et al. (2002) · Journal of the American Chemical Society · doi:10.1021/ja012701h · Cited by 128
Speier, G., Tyeklár, Z., Tóth, P., Speier, E., Tisza, S., Rockenbauer, A., Whalen, A. M., Alkire, N. L., & Pierpont, C. G. (2001) · Inorganic Chemistry · doi:10.1021/ic010373g · Cited by 117
Kupfer – ein “modernes” Bioelement
Kaim, W., & Rall, J. (1996) · Angewandte Chemie · doi:10.1002/ange.19961080105 · Cited by 105
Self-citationCopper Corroles: the Question of Noninnocence
Pierloot, K., Zhao, H., & Vancoillie, S. (2010) · Inorganic Chemistry · doi:10.1021/ic100866z · Cited by 98
Dithiolene complexes and the nature of molybdopterin
Hine, F. J., Taylor, A., & Garner, C. D. (2010) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2010.01.017 · Cited by 86
Olivier, C., Costuas, K., Choua, S., Maurel, V., Turek, P., Saillard, J., Touchard, D., & Rigaut, S. (2010) · Journal of the American Chemical Society · doi:10.1021/ja908948g · Cited by 82
Isolation of a radical dianion of nitrogen oxide (NO)2−
Evans, W. J., Fang, M., Bates, J. E., Furche, F., Ziller, J. W., Kiesz, M. D., & Zink, J. I. (2010) · Nature Chemistry · doi:10.1038/nchem.701 · Cited by 78
Graphical Abstract: Angew. Chem. Int. Ed. 49/2010
(2010) · Angewandte Chemie International Edition · doi:10.1002/anie.201090153 · Cited by 73
Roy, S., Sarkar, B., Bubrin, D., Niemeyer, M., Záliš, S., Lahiri, G. K., & Kaim, W. (2008) · Journal of the American Chemical Society · doi:10.1021/ja804429v · Cited by 70
Self-citationElectronic structure alternatives in nitrosylruthenium complexes
Lahiri, G. K., & Kaim, W. (2010) · Dalton Transactions · doi:10.1039/c002173c · Cited by 65
Self-citationChimeric Triterpene Synthase. A Possible Model for Multifunctional Triterpene Synthase
Kushiro, T., Shibuya, M., & Ebizuka, Y. (1999) · Journal of the American Chemical Society · doi:10.1021/ja983012h · Cited by 60
Singh, P., Das, A. K., Sarkar, B., Niemeyer, M., Roncaroli, F., Olabe, J. A., Fiedler, J., Záliš, S., & Kaim, W. (2008) · Inorganic Chemistry · doi:10.1021/ic702371t · Cited by 54
Self-citationSieger, M., Sarkar, B., Záliš, S., Fiedler, J., Escola, N., Doctorovich, F. A., Olabe, J. A., & Kaim, W. (2004) · Dalton Transactions · doi:10.1039/b404121f · Cited by 53
Self-citationHeme-mediated oxygen activation in biology: cytochrome c oxidase and nitric oxide synthase
Poulos, T. L., Li, H., & Raman, C. S. (1999) · Current Opinion in Chemical Biology · doi:10.1016/s1367-5931(99)80024-6 · Cited by 48
Singh, P., Sarkar, B., Sieger, M., Niemeyer, M., Fiedler, J., Záliš, S., & Kaim, W. (2006) · Inorganic Chemistry · doi:10.1021/ic0517669 · Cited by 46
Self-citationOxidation of Dihydrogen by Iridium Complexes of Redox-Active Ligands
Ringenberg, M. R., Nilges, M. J., Rauchfuss, T. B., & Wilson, S. R. (2010) · Organometallics · doi:10.1021/om9010593 · Cited by 46
Pohl, K., Wieghardt, K. E., Kaim, W., & Steenken, S. (1988) · Inorganic Chemistry · doi:10.1021/ic00276a003 · Cited by 40
Self-citationWada, T., Muckerman, J. T., Fujita, E., & Tanaka, K. (2010) · Dalton Transactions · doi:10.1039/c0dt00977f · Cited by 38
Redox Behavior of Rhodium 9,10-Phenanthrenediimine Complexes
Shaffer, D. W., Ryken, S. A., Zarkesh, R. A., & Heyduk, A. F. (2010) · Inorganic Chemistry · doi:10.1021/ic1007632 · Cited by 36
Kaim, W. (1994) · Topics in current chemistry · doi:10.1007/3-540-57565-0_77 · Cited by 32
Self-citationPellegrino, J., Hübner, R., Doctorovich, F. A., & Kaim, W. (2011) · Chemistry - A European Journal · doi:10.1002/chem.201003516 · Cited by 29
Self-citation
Cited by
The Shrinking World of Innocent Ligands: Conventionaland Non‐Conventional Redox‐Active Ligands
Kaim, W. (2012) · European Journal of Inorganic Chemistry · doi:10.1002/ejic.201101359 · Cited by 290
Self-citation
Metadata
- Authors
- Kaim, W.
- Venue
- Inorganic Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 2011-07-11
- Volume
- 50
- Issue
- 20
- Pages
- 9752-9765
- ISSN
- 0020-1669 (ISSN-L)
- 1520-510X
- OpenAlex
- W2043194193
- Cited by
- 498
- References
- 52
- FWCI
- 15.77
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
