The DOI matches its Crossref record; 59 of the 59 references it cites were found in a registry or an index.
Enhanced Hydrostability in Ni-Doped MOF-5
Abstract
Ni-doped MOF-5s were successfully synthesized for the first time via solvothermal crystallization process to enhance the hydrostability. Several characterization techniques, including X-ray diffraction (XRD), thermogravimetrical analysis (TGA), scanning electron microscopy (SEM), energy-dispersive spectroscopy instrument (EDS), inductively coupled plasma (ICP), infrared spectroscopy (IR), atomic sorption, diffuse-reflectance UV-vis spectroscopy, and gas sorption measurement, strongly support the effective incorporation of Ni(II) ions into the framework. The results demonstrated that the Ni-doped MOF-5s not only exhibit larger Langmuir specific surface areas and larger pores than the undoped MOF-5, but also significantly enhance water resistance of the framework. The H(2) uptake capacity of undoped MOF-5 drops rapidly when exposed to the ambient air, whereas the H(2) adsorptions of the Ni-doped MOF-5s remain stable for 4 days.
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Citations
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Metadata
- Authors
- Li, H., Shi, W., Zhao, K., Li, H., Bing, Y., & Cheng, P.
- Venue
- Inorganic Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-08-17
- Volume
- 51
- Issue
- 17
- Pages
- 9200-9207
- ISSN
- 0020-1669 (ISSN-L)
- 1520-510X
- OpenAlex
- W2320210466
- Cited by
- 263
- References
- 59
- FWCI
- 8.57
- Type
- journal article
- Language
- en
- Open access
- closed
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