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Hydrogen Storage in Microporous Metal-Organic Frameworks
Abstract
Metal-organic framework-5 (MOF-5) of composition Zn 4 O(BDC) 3 (BDC = 1,4-benzenedicarboxylate) with a cubic three-dimensional extended porous structure adsorbed hydrogen up to 4.5 weight percent (17.2 hydrogen molecules per formula unit) at 78 kelvin and 1.0 weight percent at room temperature and pressure of 20 bar. Inelastic neutron scattering spectroscopy of the rotational transitions of the adsorbed hydrogen molecules indicates the presence of two well-defined binding sites (termed I and II), which we associate with hydrogen binding to zinc and the BDC linker, respectively. Preliminary studies on topologically similar isoreticular metal-organic framework-6 and -8 (IRMOF-6 and -8) having cyclobutylbenzene and naphthalene linkers, respectively, gave approximately double and quadruple (2.0 weight percent) the uptake found for MOF-5 at room temperature and 10 bar.
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Citations
Cited by
Materials for hydrogen storage
Züttel, A. (2003) · Materials Today · doi:10.1016/s1369-7021(03)00922-2 · Cited by 2,216
Crabtree, G. W., Dresselhaus, M. S., & Buchanan, M. V. (2004) · Physics Today · doi:10.1063/1.1878333 · Cited by 1,610
Large-scale screening of hypothetical metal–organic frameworks
Wilmer, C. E., Leaf, M., Lee, C. Y., Farha, O. K., Hauser, B. G., Hupp, J. T., & Snurr, R. Q. (2012) · Nature Chemistry · doi:10.1038/nchem.1192 · Cited by 1,439
Dybtsev, D. N., Chun, H., & Kim, K. (2004) · Angewandte Chemie International Edition · doi:10.1002/anie.200460712 · Cited by 1,208
Metal–organic frameworks as platforms for clean energy
Li, S.-L., & Xu, Q. (2013) · Energy & Environmental Science · doi:10.1039/c3ee40507a · Cited by 970
Metadata
- Authors
- Rosi, N. L., Eckert, J., Eddaoudi, M., Vodak, D. T., Kim, J., O'Keeffe, M., & Yaghi, O. M.
- Venue
- Science
- Published
- 2003-05-16
- Volume
- 300
- Issue
- 5622
- Pages
- 1127-1129
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W1975501285
- Cited by
- 4,846
- References
- 0
- FWCI
- 102.60
- Type
- journal article
- Language
- en
- Open access
- closed
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- Rosi, N. L., Eckert, J., Eddaoudi, M., Vodak, D. T., Kim, J., O'Keeffe, M., & Yaghi, O. M. (2003). Hydrogen Storage in Microporous Metal-Organic Frameworks. Science. https://doi.org/10.1126/science.1083440
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