The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Color Tuning and White Light Emission via in Situ Doping of Luminescent Lanthanide Metal–Organic Frameworks
Abstract
Isostructural lanthanide metal-organic frameworks (MOFs) are synthesized through the spontaneous self-assembly of H3BTPCA (1,1',1″-(benzene-1,3,5-triyl)tripiperidine-4-carboxylic acid) ligands and lanthanide ions (we term these MOFs Ln-BTPCA, Ln = La(3+), Tb(3+), Sm(3+), etc.). Prompted by the observation that the different lanthanide ions have identical coordination environment in these MOFs, we explored and succeeded in the preparation of mixed-lanthanide analogues of the single-lanthanide MOFs by way of in situ doping using a mixture of lanthanide salts. With careful adjustment of the relative concentration of the lanthanide ions, the color of the luminescence can be modulated, and white light-emission can indeed be achieved. The mechanisms possibly responsible for the observed photophysical properties of these mixed-lanthanide MOFs are also discussed.
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Cites
Metal-organic framework materials as catalysts
Lee, J., Farha, O. K., Roberts, J., Scheidt, K. A., Nguyen, S. T., & Hupp, J. T. (2009) · Chemical Society Reviews · doi:10.1039/b807080f · Cited by 7,969
Cited by
Zhu, X., Feng, W., Chang, J., Tan, Y.-W., Li, J., Chen, M., Sun, Y., & Li, F. (2016) · Nature Communications · doi:10.1038/ncomms10437 · Cited by 1,013
MOF based luminescence tuning and chemical/physical sensing
Müller-Buschbaum, K., Beuerle, F., & Feldmann, C. (2015) · Microporous and Mesoporous Materials · doi:10.1016/j.micromeso.2015.03.036 · Cited by 337
Feng, X., Feng, Y., Guo, N., Sun, Y., Zhang, T., Ma, L., & Wang, L. (2017) · Inorganic Chemistry · doi:10.1021/acs.inorgchem.6b02851 · Cited by 287
Metal–organic frameworks based on multicarboxylate linkers
Ghasempour, H., Wang, K.-Y., Powell, J. A., ZareKarizi, F., Lv, X.-L., Morsali, A., & Zhou, H.-C. (2021) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2020.213542 · Cited by 284
Metadata
- Authors
- Tang, Q., Liu, S., Liu, Y., He, D., Miao, J., Wang, X., Ji, Y., & Zheng, Z.
- Venue
- Inorganic Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-12-13
- Volume
- 53
- Issue
- 1
- Pages
- 289-293
- ISSN
- 0020-1669 (ISSN-L)
- 1520-510X
- OpenAlex
- W2074538584
- Cited by
- 222
- References
- 1
- FWCI
- 12.41
- Type
- journal article
- Language
- en
- Open access
- closed
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- Tang, Q., Liu, S., Liu, Y., He, D., Miao, J., Wang, X., Ji, Y., & Zheng, Z. (2014). Color Tuning and White Light Emission via in Situ Doping of Luminescent Lanthanide Metal–Organic Frameworks. Inorganic Chemistry. https://doi.org/10.1021/ic402228g
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