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Fast Synthesis of ZnO Nanostructures by Laser-Induced Decomposition of Zinc Acetylacetonate
Abstract
A CO2 laser (lambda = 10.6 microm) was used to heat a solution of water and alcohol saturated by Zn(AcAc)2 on a fused quartz substrate in open air. After only a few seconds of irradiation, various zinc oxide (ZnO) nanostructures including nanorods and nanowires are formed near the center of the irradiated zone, surrounded by a porous thin film of ZnO nanoparticles. The type of structures produced and their localization on the substrate can be varied by selecting adequate irradiation time and laser power ranges. The deposits have been analyzed using SEM, TEM, EDS, XRD, and Raman spectroscopy, revealing that the nanorods (aspect ratio ~6) and nanowires (aspect ratio ~94) are single-crystalline structures which grow along the c axis of wurtzite ZnO. The nanoparticles are also single-crystalline and have an average diameter of 16 nm. A qualitative model for nanostructure growth is proposed, based on previous studies of aqueous solution and hydrothermal processing.
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“The formation mechanism for ZnO involves the oriented attachment in which small particles are aggregated to form rod-shaped bigger solid particles through the self-assembly process.”
From Fundamentals and comprehensive insights on pulsed laser synthesis of advanced materials for diverse photo- and electrocatalytic applications (2022) · cites this paper as [92]
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Metadata
- Authors
- Fauteux, C., Longtin, R., Pegna, J., & Therriault, D.
- Affiliations
- Research Center for High Performance Polymer and Composite Systems (CA)
- Corresponding author
- Fauteux, Christian
- Venue
- Inorganic Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 2007-11-21
- Volume
- 46
- Issue
- 26
- Pages
- 11036-11047
- ISSN
- 0020-1669 (ISSN-L)
- 1520-510X
- OpenAlex
- W1985183096
- Cited by
- 63
- References
- 60
- Citations by year
- 2026: 1 · 2025: 1 · 2024: 2 · 2023: 1 · 2022: 2 · 2021: 2 · 2020: 2 · 2019: 4 · 2018: 6 · 2017: 6 · 2016: 2 · 2015: 1 · 2014: 4 · 2013: 4 · 2012: 3
- FWCI
- 2.76
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Inorganic Chemistry (publishedVersion)
- PubMed (publishedVersion)
- PolyPublie (École Polytechnique de Montréal) (submittedVersion)
- Topics
- Physical Sciences › Materials Science › Materials Chemistry › ZnO doping and properties
- Physical Sciences › Materials Science › Electronic, Optical and Magnetic Materials › Nanowire Synthesis and Applications
- Physical Sciences › Materials Science › Materials Chemistry › Laser-Ablation Synthesis of Nanoparticles
- Keywords
- ZnO nanostructures, laser-induced decomposition, zinc acetylacetonate, CO2 laser, nanorods, nanowires, zinc oxide nanoparticles, single-crystalline nanostructures, wurtzite structure, aqueous processing, hydrothermal treatment
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