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Iridium-Catalyzed Dehydrogenation of Substituted Amine Boranes: Kinetics, Thermodynamics, and Implications for Hydrogen Storage
Abstract
Dehydrogenation of amine boranes is catalyzed efficiently by the iridium pincer complex (kappa (3)-1,3-(OP ( t )Bu 2) 2C 6H 3)Ir(H) 2 ( 1). With CH 3NH 2BH 3 (MeAB) and with AB/MeAB mixtures (AB = NH 3BH 3), the rapid release of 1 equiv of H 2 is observed to yield soluble oligomeric products at rates similar to those previously reported for the dehydrogenation of AB catalyzed by 1. Delta H for the dehydrogenation of AB, MeAB, and AB/MeAB mixtures has been determined by calorimetry. The experimental heats of reaction are compared to results from computational studies.
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Crabtree, G. W., Dresselhaus, M. S., & Buchanan, M. V. (2004) · Physics Today · doi:10.1063/1.1878333 · Cited by 1,610
Cited by
Ammonia–Borane and Amine–Borane Dehydrogenation Mediated by Complex Metal Hydrides
Rossin, A., & Peruzzini, M. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00043 · Cited by 421
Staubitz, A., Sloan, M. E., Robertson, A. P. M., Friedrich, A., Schneider, S., Gates, P. J., Schmedt auf der Günne, J., & Manners, I. (2010) · Journal of the American Chemical Society · doi:10.1021/ja104607y · Cited by 302
Metadata
- Authors
- Dietrich, B. L., Goldberg, K. I., Heinekey, D. M., Autrey, T., & Linehan, J. C.
- Venue
- Inorganic Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 2008-09-12
- Volume
- 47
- Issue
- 19
- Pages
- 8583-8585
- ISSN
- 0020-1669 (ISSN-L)
- 1520-510X
- OpenAlex
- W1986735880
- Cited by
- 164
- References
- 1
- FWCI
- 10.44
- Type
- journal article
- Language
- en
- Open access
- closed
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- Dietrich, B. L., Goldberg, K. I., Heinekey, D. M., Autrey, T., & Linehan, J. C. (2008). Iridium-Catalyzed Dehydrogenation of Substituted Amine Boranes: Kinetics, Thermodynamics, and Implications for Hydrogen Storage. Inorganic Chemistry. https://doi.org/10.1021/ic801161g
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