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Mononuclear Lanthanide Single Molecule Magnets Based on the Polyoxometalates [Ln(W5O18)2]9− and [Ln(β2-SiW11O39)2]13−(LnIII = Tb, Dy, Ho, Er, Tm, and Yb)
Abstract
The first two families of polyoxometalate-based single-molecule magnets (SMMs) are reported here. Compounds of the general formula [Ln(W(5)O(18))(2)](9-) (Ln(III) = Tb, Dy, Ho, and Er) and [Ln(SiW(11)O(39))(2)](13-) (Ln(III) = Tb, Dy, Ho, Er, Tm, and Yb) have been magnetically characterized with static and dynamic measurements. Slow relaxation of the magnetization, typically associated with SMM-like behavior, was observed for [Ln(W(5)O(18))(2)](9-) (Ln(III) = Ho and Er) and [Ln(SiW(11)O(39))(2)](13-) (Ln(III) = Dy, Ho, Er, and Yb). Among them, only the [Er(W(5)O(18))(2)](9-) derivative exhibited such a behavior above 2 K with an energy barrier for the reversal of the magnetization of 55 K. For a deep understanding of the appearance of slow relaxation of the magnetization in these types of mononuclear complexes, the ligand-field parameters and the splitting of the J ground-state multiplet of the lanthanide ions have been also estimated.
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Cites
[20] Processing of X-ray diffraction data collected in oscillation mode
Otwinowski, Z., & Minor, W. (1997) · Methods in Enzymology · doi:10.1016/s0076-6879(97)76066-x · Cited by 33,475
Dispersion and Absorption in Dielectrics I. Alternating Current Characteristics
Cole, K. S., & Cole, R. H. (1941) · The Journal of Chemical Physics · doi:10.1063/1.1750906 · Cited by 10,152
Cited by
Lanthanide Single-Molecule Magnets
Woodruff, D. N., Winpenny, R. E. P., & Layfield, R. A. (2013) · Chemical Reviews · doi:10.1021/cr400018q · Cited by 2,781
Slow magnetization dynamics in a series of two-coordinate iron(ii) complexes
Zadrozny, J. M., Atanasov, M., Bryan, A. M., Lin, C.-Y., Rekken, B. D., Power, P. P., Neese, F., & Long, J. R. (2013) · Chem. Sci. · doi:10.1039/c2sc20801f · Cited by 579
Zhao, J.-W., Li, Y.-Z., Chen, L.-J., & Yang, G.-Y. (2016) · Chemical Communications · doi:10.1039/c5cc10447e · Cited by 284
Metadata
- Authors
- AlDamen, M. A., Cardona-Serra, S., Clemente-Juan, J. M., Coronado, E., Gaita-Ariño, A., Martí-Gastaldo, C., Luis, F., & Montero, O.
- Venue
- Inorganic Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 2009-04-13
- Volume
- 48
- Issue
- 8
- Pages
- 3467-3479
- ISSN
- 0020-1669 (ISSN-L)
- 1520-510X
- OpenAlex
- W1973141298
- Cited by
- 502
- References
- 2
- FWCI
- 17.60
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Mononuclear Lanthanide Single Molecule Magnets Based on the Polyoxometalates [Ln(W5O18)2]9− and [Ln(β2-SiW11O39)2]13−(LnIII = Tb, Dy, Ho, Er, Tm, and Yb). https://app.cochat.ai/papers/10.1021/ic801630z
- The paper
- AlDamen, M. A., Cardona-Serra, S., Clemente-Juan, J. M., Coronado, E., Gaita-Ariño, A., Martí-Gastaldo, C., Luis, F., & Montero, O. (2009). Mononuclear Lanthanide Single Molecule Magnets Based on the Polyoxometalates [Ln(W5O18)2]9− and [Ln(β2-SiW11O39)2]13−(LnIII = Tb, Dy, Ho, Er, Tm, and Yb). Inorganic Chemistry. https://doi.org/10.1021/ic801630z
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