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Cited by 225

The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.

Synthesis and Characterization of New Chiral Schiff Base Complexes with Diiminobinaphthyl or Diiminocyclohexyl Moieties as Potential Enantioselective Epoxidation Catalysts

Bernardo, Katia, Leppard, Simon, Robert, Anne, Commenges, Gérard, Dahan, Françoise, Meunier, Bernard·1996·Inorganic Chemistry

Abstract

New chiral Schiff base complexes have been obtained by condensation of 2,2'-diamino-1,1'-binaphthalene or 1,2-diaminocyclohexane and various salicylaldehydes and by subsequent metalation with manganese, iron, cobalt, nickel, copper, or zinc. The complete (1)H and (13)C NMR characterization of the ligands is reported, as are the X-ray crystal structures of (1R,2R)-(-)-N,N'-bis[3-(N,N-dimethylamino)salicylidene]-trans-1,2-cyclohexanediimine and [(1R,2R)-(-)-N,N'-bis(salicylidene)-trans-1,2-cyclohexanediiminato]copper(II). The new chiral manganese complexes have been evaluated in the oxygenation of prochiral olefins and sulfides using sodium hypochlorite, hydrogen peroxide, or N-methylmorpholine N-oxide/m-chloroperbenzoic acid as oxidant.

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Metadata

Authors
Bernardo, K., Leppard, S., Robert, A., Commenges, G., Dahan, F., & Meunier, B.
Venue
Inorganic Chemistry
Published
1996-01-01
Volume
35
Issue
2
Pages
387-396
ISSN
  • 0020-1669 (ISSN-L)
  • 1520-510X
OpenAlex
W1988303767
Cited by
225
References
1
FWCI
6.58
Type
journal article
Language
en
Open access
closed

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