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Cited by 368

The DOI matches its Crossref record; 17 of the 17 references it cites were found in a registry or an index.

Conformational and Coordination Equilibria on DOTA Complexes of Lanthanide Metal Ions in Aqueous Solution Studied by 1H-NMR Spectroscopy

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Aime, Silvio, Botta, Mauro, Fasano, Mauro, Marques, M. Paula M., Geraldes, Carlos F. G. C., Pubanz, Dirk, Merbach, André E.·1997·Inorganic Chemistry
DOI 10.1021/ic961364o
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Abstract

A variable-temperature, -pressure, and -ionic strength (1)H NMR study of the DOTA complexes of different trivalent cations (Sc, Y, La, Ce --> Lu) (DOTA = 1,4,7,10-tetraaza-1,4,7,10-tetrakis(carboxymethyl)cyclododecane) yielded data that are in contradiction with the hitherto used model of only two enantiomeric pairs of diastereoisomers that differ in the ligand conformations. A two-isomer equilibrium cannot explain the newly observed apparent reversal of the isomer ratio at the end of the series. As both conformers may lose their inner sphere water molecule, a coordination equilibrium may be superimposed on this conformational equilibrium, as shown by large positive reaction volumes for the isomerization of [Ln(DOTA)(H(2)O)(x)()](-) (Ln = Yb, Lu; x = 1, 0). The isomerization of [Nd(DOTA)(H(2)O)](-) and [Eu(DOTA)(H(2)O)](-) is purely conformational, as shown by near-zero reaction volumes. The measured isomerization enthalpies and entropies agree with this model. The shift of the isomerization equilibria by a variety of non-coordinative salts depends on the ligand conformation rather than the presence or absence of the inner sphere water molecule. This results from weak ion binding and water solvent stabilization of one ligand conformation, rather than the decrease of the activity of the bulk water in the solution, as shown by UV-vis measurements of the coordination number sensitive transition (5)F(0) --> (7)D(0) of Eu(III) as a function of ionic strength. Fluoride ions replace a water molecule in the inner coordination sphere, preferentially for one of the conformational isomers, as proven by (19)F-NMR shifts and the appearance of a third set of resonances corresponding to [Eu(DOTA)F](2)(-) in the (1)H-NMR spectrum of [Eu(DOTA)(H(2)O)](-).

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Metadata

Authors
Aime, S., Botta, M., Fasano, M., Marques, M. P. M., Geraldes, C. F. G. C., Pubanz, D., & Merbach, A. E.
Venue
Inorganic Chemistry
Publisher
American Chemical Society (ACS)
Published
1997-05-01
Volume
36
Issue
10
Pages
2059-2068
ISSN
  • 0020-1669 (ISSN-L)
  • 1520-510X
DOI
10.1021/ic961364o
OpenAlex
W2023073862
Cited by
368
References
17
FWCI
8.50
Type
journal article
Language
en
Open access
green

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