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Investigation of Physicochemical Parameters That Influence Photocatalytic Degradation of Methyl Orange over TiO2 Nanotubes
Abstract
The photocatalytic degradation of a model textile dye, methyl orange (MO), using anodized titanium dioxide (TiO 2 ) nanotubes has been investigated. The effects of light intensity, dye concentration, external bias, pH, and nanotube dimensions (length, diameter, and wall thickness) on MO photodegradation have been examined. The application of a minimal bias of +0.0 versus saturated calomel electrode (SCE) can enhance the dye degradation at least 10 times compared to unbiased conditions for dye concentrations between 20 and 100 μM. The overall initial dye degradation rate demonstrates three types of dependence on dye concentration over a range from 2.5−100 μM. For lower dye concentrations (2.5−40 μM) and natural pH (∼6.0) conditions, Langmuir−Hinshelwood (LH) kinetics was observed. The nanotubes diameter, calcination condition, and the anatase-to-rutile ratio in the crystalline TiO 2 nanotubes together influence the photocatalytic and photoelectrochemical properties of the TiO 2 nanotubes.
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Cited by
Paramasivam, I., Jha, H., Liu, N., & Schmuki, P. (2012) · Small · doi:10.1002/smll.201200564 · Cited by 687
Sharma, S., Dutta, V., Singh, P., Raizada, P., Rahmani-Sani, A., Hosseini-Bandegharaei, A., & Thakur, V. K. (2019) · Journal of Cleaner Production · doi:10.1016/j.jclepro.2019.04.292 · Cited by 444
Electrospun Nanofibers of ZnO−SnO2 Heterojunction with High Photocatalytic Activity
Zhang, Z., Shao, C., Li, X., Zhang, L., Xue, H., Wang, C., & Liu, Y. (2010) · The Journal of Physical Chemistry C · doi:10.1021/jp100262q · Cited by 370
Yu, H., Zhang, H., Huang, H., Liu, Y., Li, H., Ming, H., & Kang, Z. (2012) · New Journal of Chemistry · doi:10.1039/c2nj20959d · Cited by 271
Synthesis of core–shell bioaffinity chitosan–TiO2 composite and its environmental applications
Xiao, G., Su, H., & Tan, T. (2015) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2014.10.047 · Cited by 85
Metadata
- Authors
- Smith, Y. R., Kar, A., & Subramanian, V. (.
- Venue
- Industrial & Engineering Chemistry Research
- Publisher
- American Chemical Society (ACS)
- Published
- 2009-10-13
- Volume
- 48
- Issue
- 23
- Pages
- 10268-10276
- ISSN
- 0888-5885 (ISSN-L)
- 1520-5045
- OpenAlex
- W2049741799
- Cited by
- 164
- References
- 0
- FWCI
- 4.68
- Type
- journal article
- Language
- en
- Open access
- closed
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- Smith, Y. R., Kar, A., & Subramanian, V. (. (2009). Investigation of Physicochemical Parameters That Influence Photocatalytic Degradation of Methyl Orange over TiO2 Nanotubes. Industrial & Engineering Chemistry Research. https://doi.org/10.1021/ie801851p
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