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Structure of Amorphous MoS3
Open accessAbstract
The amorphous compound MoS3 has been investigated by monochromatic X-ray photoemission ( X P S) and vibrational spectroscopy, as well as by chemical extrusion aimed at identifying structural units inside MoS3. XPS shows that all molybdenum in MoS3 occurs in the 4-t oxidation state, while sulfur is present in at least two states, including S2- and Sz2- ligands in different types of coordination. This composition corresponds to a formal charge state of MorV(S2-)&-). The emission infrared spectrum of MOS3 exhibits characteristic vibrations that are also encountered in the spectra of triangular MON3Sx cluster compounds. Three of such cluster compounds, i.e. (NH&[MotV3S~3]*H20, K s [ M o ~ S ~ ( C N) ~ ~. ~ H ~ O, and (NEt&[MotV3S7C16] can be extruded from MoS3 by reactions that are essentially destructive. On the basis of these results it is proposed that MoS3 is essentially an aggregation of M~(IV)~-sulfur cluster types.
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Cited by
Catalyzing the hydrogen evolution reaction (HER) with molybdenum sulfide nanomaterials
Benck, J. D., Hellstern, T. R., Kibsgaard, J., Chakthranont, P., & Jaramillo, T. F. (2014) · ACS Catalysis · doi:10.1021/cs500923c · Cited by 1,617
Recent developments of molybdenum and tungsten sulfides as hydrogen evolution catalysts
Merki, D., & Hu, X. (2011) · Energy & Environmental Science · doi:10.1039/c1ee01970h · Cited by 1,172
Benck, J. D., Chen, Z., Kuritzky, L. Y., Forman, A. J., & Jaramillo, T. F. (2012) · ACS Catalysis · doi:10.1021/cs300451q · Cited by 1,091
Kibsgaard, J., Jaramillo, T. F., & Besenbacher, F. (2014) · Nature Chemistry · doi:10.1038/nchem.1853 · Cited by 839
Hydrogen evolution catalyzed by MoS3 and MoS2 particles
Vrubel, H., Merki, D., & Hu, X. (2012) · Energy & Environmental Science · doi:10.1039/c2ee02835b · Cited by 726
Metadata
- Authors
- Weber, T., Muijsers, J. C., & Niemantsverdriet, J. W.
- Venue
- The Journal of Physical Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 1995-06
- Volume
- 99
- Issue
- 22
- Pages
- 9194-9200
- ISSN
- 0022-3654 (ISSN-L)
- 1541-5740
- OpenAlex
- W2150950804
- Cited by
- 403
- References
- 0
- FWCI
- 3.56
- Type
- journal article
- Language
- en
- Open access
- green
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- Weber, T., Muijsers, J. C., & Niemantsverdriet, J. W. (1995). Structure of Amorphous MoS3. The Journal of Physical Chemistry. https://doi.org/10.1021/j100022a037
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