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Formation of ordered two-dimensional gold colloid lattices by electrophoretic deposition
Abstract
The preparation of ordered two dimensional 2D gold colloid lattices using an electrophoretic technique is reported. The lattices can be readily observed by electron microscope and the lattice constants determined by electron diffraction. Using image processing, it can be shown that the gold particles condense into a hexagonal lattice and also that the crystallographic axes of the individual gold particles are randomly oriented. The equilibrium distance between the particles corresponds approximately to the size of the adsorbed stabilizers. The structures are therefore stabilized by short range steric repulsion and not by a diffuse layer electrostatic barrier, as is normally the case for latex sols. The method is of general interest as a means to prepare monolayer films of nanosized metal or semiconductor particles
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Citations
Cited by
Photophysical, Photochemical and Photocatalytic Aspects of Metal Nanoparticles
Kamat, P. V. (2002) · The Journal of Physical Chemistry B · doi:10.1021/jp0209289 · Cited by 1,924
Subramanian, V., Wolf, E., & Kamat, P. V. (2001) · The Journal of Physical Chemistry B · doi:10.1021/jp011118k · Cited by 916
Synthesis, structure and properties of metal nanoclusters
Wilcoxon, J. P., & Abrams, B. L. (2006) · Chemical Society Reviews · doi:10.1039/b517312b · Cited by 760
Chen, S., & Kimura, K. (1999) · Langmuir · doi:10.1021/la9812828 · Cited by 362
Time-Resolved Electrochemical Detection of Discrete Adsorption Events
Quinn, B. M., van't Hof, P. G., & Lemay, S. G. (2004) · Journal of the American Chemical Society · doi:10.1021/ja0478577 · Cited by 274
Metadata
- Authors
- Giersig, M., & Mulvaney, P.
- Venue
- The Journal of Physical Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 1993-06
- Volume
- 97
- Issue
- 24
- Pages
- 6334-6336
- ISSN
- 0022-3654 (ISSN-L)
- 1541-5740
- OpenAlex
- W1990683044
- Cited by
- 220
- References
- 0
- FWCI
- 6.42
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Formation of ordered two-dimensional gold colloid lattices by electrophoretic deposition. https://app.cochat.ai/papers/10.1021/j100126a003
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- Giersig, M., & Mulvaney, P. (1993). Formation of ordered two-dimensional gold colloid lattices by electrophoretic deposition. The Journal of Physical Chemistry. https://doi.org/10.1021/j100126a003
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