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Solvent reorganization in optical and thermal electron-transfer processes
Open accessAbstract
Dielectric continuum models used to calculate the solvent reorganization energy in thermal and photochemical electron-transfer reactions are discussed.Expressions are derived for the reorganization energy for charge redistribution within a single ellipsoidal or spherical solvent cavity.The expressions for the ellipsoidal cavity model differ in important respects from those derived previously.The Marcus two-sphere and the ellipsoidal cavity models can satisfactorily predict the band maximum for the metal-to-metal charge-transfer transition in a number of ion-paired and bridged binuclear systems, provided careful consideration is given to the cavity dimensions.In complexes containing 2,2'-bipyridine ligands the solvent can approach close to the charge centers by filling the space between the ligands: this results in a smaller effective radius and relatively large values for the Series 58; D.
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Cited by
Proton-coupled electron transfer
Huynh, M. H. V., & Meyer, T. J. (2007) · Chemical Reviews · doi:10.1021/cr0500030 · Cited by 1,659
The Localized-to-Delocalized Transition in Mixed-Valence Chemistry
Demadis, K. D., Hartshorn, C. M., & Meyer, T. J. (2001) · Chemical Reviews · doi:10.1021/cr990413m · Cited by 1,074
PROTON-COUPLED ELECTRON TRANSFER
Cukier, R. I., & Nocera, D. G. (1998) · Annual Review of Physical Chemistry · doi:10.1146/annurev.physchem.49.1.337 · Cited by 854
Organic Mixed‐Valence Compounds: A Playground for Electrons and Holes
Heckmann, A., & Lambert, C. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201100944 · Cited by 560
Biochemistry and Theory of Proton-Coupled Electron Transfer
Migliore, A., Polizzi, N. F., Therien, M. J., & Beratan, D. N. (2014) · Chemical Reviews · doi:10.1021/cr4006654 · Cited by 520
Metadata
- Authors
- Brunschwig, B. S., Ehrenson, S., & Sutin, N.
- Venue
- The Journal of Physical Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 1986-07
- Volume
- 90
- Issue
- 16
- Pages
- 3657-3668
- ISSN
- 0022-3654 (ISSN-L)
- 1541-5740
- OpenAlex
- W2052767617
- Cited by
- 229
- References
- 0
- FWCI
- 4.91
- Type
- journal article
- Language
- en
- Open access
- bronze
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- Brunschwig, B. S., Ehrenson, S., & Sutin, N. (1986). Solvent reorganization in optical and thermal electron-transfer processes. The Journal of Physical Chemistry. https://doi.org/10.1021/j100407a037
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