The DOI matches its Crossref record; 27 of the 27 references it cites were found in a registry or an index.
Frequency Selective Heteronuclear Dipolar Recoupling in Rotating Solids: Accurate13C−15N Distance Measurements in Uniformly13C,15N-labeled Peptides
Abstract
We describe a magic-angle spinning NMR experiment for selective (13)C-(15)N distance measurements in uniformly (13)C,(15)N-labeled solids, where multiple (13)C-(15)N and (13)C-(13)C interactions complicate the accurate measurement of structurally interesting, weak (13)C-(15)N dipolar couplings. The new experiment, termed FSR (frequency selective REDOR), combines the REDOR pulse sequence with a frequency selective spin-echo to recouple a single (13)C-(15)N dipolar interaction in a multiple spin system. Concurrently the remaining (13)C-(15)N dipolar couplings and all (13)C-(13)C scalar couplings to the selected (13)C are suppressed. The (13)C-(15)N coupling of interest is extracted by a least-squares fit of the experimentally observed modulation of the (13)C spin-echo intensity to the analytical expression describing the dipolar dephasing in an isolated heteronuclear spin pair under conventional REDOR. The experiment is demonstrated in three uniformly (13)C,(15)N-labeled model systems: asparagine, N-acetyl-L-Val-L-Leu and N-formyl-L-Met-L-Leu-L-Phe; in N-formyl-[U-(13)C,(15)N]L-Met-L-Leu-L-Phe we have determined a total of 16 internuclear distances in the 2.5-6 A range.
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Cites
NMR with Proteins and Nucleic Acids
Wüthrich, K. (1986) · Europhysics News · doi:10.1051/epn/19861701011 · Cited by 7,989
Hahn, E. L. (1950) · Physical Review · doi:10.1103/physrev.80.580 · Cited by 5,085
Proton-enhanced NMR of dilute spins in solids
Pines, A., Gibby, M. G., & Waugh, J. S. (1973) · The Journal of Chemical Physics · doi:10.1063/1.1680061 · Cited by 2,493
Principles of High Resolution NMR in Solids
Mehring, M. (1983) · Springer eBooks · doi:10.1007/978-3-642-68756-3 · Cited by 1,981
Principles of Nucleic Acid Structure
Parish, J. (1985) · Biochemical Education · doi:10.1016/0307-4412(85)90046-9 · Cited by 1,486
Principles of Nuclear Magnetic Resonance in One and Two Dimensions
Ernst, R. R., Bodenhausen, G., & Wokaun, A. (1990) · doi:10.1093/oso/9780198556473.001.0001 · Cited by 1,418
Nuclear Magnetic Resonance Spectra from a Crystal rotated at High Speed
ANDREW, E. R., BRADBURY, A., & EADES, R. G. (1958) · Nature · doi:10.1038/1821659a0 · Cited by 1,255
Ramped-Amplitude Cross Polarization in Magic-Angle-Spinning NMR
Metz, G., Wu, X. L., & Smith, S. O. (1994) · Journal of Magnetic Resonance, Series A · doi:10.1006/jmra.1994.1208 · Cited by 1,217
Free Induction Decays of Rotating Solids
Lowe, I. J. (1959) · Physical Review Letters · doi:10.1103/physrevlett.2.285 · Cited by 1,170
Coherent Averaging Effects in Magnetic Resonance
Haeberlen, U., & Waugh, J. S. (1968) · Physical Review · doi:10.1103/physrev.175.453 · Cited by 1,083
Cited by
Self-Propagating, Molecular-Level Polymorphism in Alzheimer's ß-Amyloid Fibrils
Petkova, A. T., Leapman, R. D., Guo, Z., Yau, W.-M., Mattson, M. P., & Tycko, R. (2005) · Science · doi:10.1126/science.1105850 · Cited by 1,687
Metadata
- Authors
- Jaroniec, C. P., Tounge, B. A., Herzfeld, J., & Griffin, R. G.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2001-03-22
- Volume
- 123
- Issue
- 15
- Pages
- 3507-3519
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2037844642
- Cited by
- 255
- References
- 27
- FWCI
- 8.31
- Type
- journal article
- Language
- en
- Open access
- closed
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- Jaroniec, C. P., Tounge, B. A., Herzfeld, J., & Griffin, R. G. (2001). Frequency Selective Heteronuclear Dipolar Recoupling in Rotating Solids: Accurate13C−15N Distance Measurements in Uniformly13C,15N-labeled Peptides. Journal of the American Chemical Society. https://doi.org/10.1021/ja003266e
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