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Rate constants for the reactions of free radicals with oxygen in solution
Abstract
The kinetics of the reactions of several free radicals with oxygen have been examined in solution at 300 K using laser flash photolysis techniques. The reactions of resonance-stabilized radicals are only slightly slower than those of nonstabilized radicals: for example, for tert-butyl (in cyclohexane), 4.93 × 109; benzyl, 2.36 × 109 (in cyclohexane); cyclohexadienyl (in benzene), 1.64 × 109 M-1 s-1. The reaction of n-Bu3Sn• radicals is unusually fast (7.5 × 109 M-1 s-), a fact that has been tentatively attributed to a relaxation of spin selection rules due to heavy atom effects. © 1983 American Chemical Society.
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Cited by
β-Carotene: an Unusual Type of Lipid Antioxidant
Burton, G. W., & Ingold, K. U. (1984) · Science · doi:10.1126/science.6710156 · Cited by 2,150
Self-citationBurton, G. W., & Ingold, K. U. (1986) · Accounts of Chemical Research · doi:10.1021/ar00127a001 · Cited by 1,123
Self-citationIngold, K. U., & Pratt, D. A. (2014) · Chemical Reviews · doi:10.1021/cr500226n · Cited by 531
Self-citationAlberti, A., Bolognini, L., Macciantelli, D., & Caratelli, M. (2000) · Research on Chemical Intermediates · doi:10.1163/156856700x00769 · Cited by 386
Pratt, D. A., Tallman, K. A., & Porter, N. A. (2011) · Accounts of Chemical Research · doi:10.1021/ar200024c · Cited by 352
Metadata
- Authors
- Maillard, B., Ingold, K. U., & Scaiano, J. C.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 1983-07
- Volume
- 105
- Issue
- 15
- Pages
- 5095-5099
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2045765337
- Cited by
- 502
- References
- 0
- FWCI
- 8.59
- Type
- journal article
- Language
- en
- Open access
- closed
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- Maillard, B., Ingold, K. U., & Scaiano, J. C. (1983). Rate constants for the reactions of free radicals with oxygen in solution. Journal of the American Chemical Society. https://doi.org/10.1021/ja00353a039
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