A study of superoxide reactivity. Reaction of potassium superoxide with alkyl halides and tosylates
Abstract
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTA study of superoxide reactivity. Reaction of potassium superoxide with alkyl halides and tosylatesChuen-Ing Chern, Robert DiCosimo, Reynalda De Jesus, and Joseph San Filippo Jr.Cite this: J. Am. Chem. Soc. 1978, 100, 23, 7317–7327Publication Date (Print):November 1, 1978Publication History Published online1 May 2002Published inissue 1 November 1978https://pubs.acs.org/doi/10.1021/ja00491a032https://doi.org/10.1021/ja00491a032research-articleACS PublicationsRequest reuse permissionsArticle Views424Altmetric-Citations32LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose Get e-Alerts
Integrity signals
Registry
Cites
Statistics
Claims the paper makes
Claims other papers make about this one
Each is checked against this paper’s own text: does it say what the citing paper says it does?
Na2O has been found to be less reactive than K2O due to its reduced solubility.
“Na2O has been found to be less reactive than K2O due to its reduced solubility [56].”
From Superoxide Anion Chemistry—Its Role at the Core of the Innate Immunity (2023) · cites this paper as [56]
O2•− is a nucleophile in reactions with alkyl halides and alkyl tosylates in DMSO, leading to alkylperoxy radicals and then peroxy anions via one-electron reduction.
“O2•− is a nucleophile in the reaction with alkyl halides and alkyl tosylates in DMSO and leads to the formation of alkylperoxy radicals and subsequently to peroxy anions via one-electron reduction [56,129], Figure 47.”
From Superoxide Anion Chemistry—Its Role at the Core of the Innate Immunity (2023) · cites this paper as [56]
Cited by
Sorted by citations
Superoxide Anion Chemistry—Its Role at the Core of the Innate Immunity
Andrés, C. M. C., Pérez de la Lastra, J. M., Andrés Juan, C., Plou, F. J., & Pérez-Lebeña, E. (2023) · International Journal of Molecular Sciences · doi:10.3390/ijms24031841 · Cited by 342 · see citing works
Moorcroft, M. J., Hahn, C. E. W., & Compton, R. G. (2003) · Journal of Electroanalytical Chemistry · doi:10.1016/s0022-0728(02)01424-9 · Cited by 16 · see citing works
- Authors
- Chern, C.-I., DiCosimo, R., De Jesus, R., & San Filippo, J.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 1978-11
- Volume
- 100
- Issue
- 23
- Pages
- 7317-7327
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2953227684
- Cited by
- 43
- References
- 0
- Citations by year
- 2025: 2 · 2024: 1 · 2023: 1 · 2021: 1 · 2016: 2 · 2015: 1 · 2014: 1 · 2013: 2
- FWCI
- 4.70
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of the American Chemical Society (publishedVersion)
- Topics
- Physical Sciences › Chemistry › Organic Chemistry › Physical Organic Chemistry and Reaction Kinetics
- Physical Sciences › Chemistry › Organic Chemistry › Coordination Chemistry and Organometallics
- Physical Sciences › Chemistry › Organic Chemistry › Oxidative Organic Chemistry Reactions
- Keywords
- potassium superoxide, alkyl halides, tosylate, alkyl radicals
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
