Rate of water exchange from hydrated magnesium ion
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ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTRate of water exchange from hydrated magnesium ionJames Neely and Robert ConnickCite this: J. Am. Chem. Soc. 1970, 92, 11, 3476–3478Publication Date (Print):June 1, 1970Publication History Published online1 May 2002Published inissue 1 June 1970https://pubs.acs.org/doi/10.1021/ja00714a048https://doi.org/10.1021/ja00714a048research-articleACS PublicationsRequest reuse permissionsArticle Views425Altmetric-Citations88LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose Get e-Alerts
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Similar behaviour has been reported for other metal ion-ligand complexes.
“Similar behaviour has been reported for other metal ion-ligand complexes, 69,70 but to the best of our knowledge no experimental values are available for water exchange around the Mg-CO 3 complex.”
From Computational Insights into Mg<sup>2+</sup> Dehydration in the Presence of Carbonate (2022) · cites this paper as [69]
Lincoln suggested that each metal ion-ligand complex behaves differently; for example, he reported that CrO4^2- increases the water lability of the aqueous Ca2+ ion but has little effect on the water exchange around Mg2+.
“However, Lincoln 69 suggested that each metal ion-ligand complex behaves differently; for example he reported that CrO 2 - 4 increases the water lability of the aqueous Ca 2+ ion but has little effect on the water exchange around Mg 2+ , therefore more experimental work on the magnesium carbonate system is required to corroborate our results.”
From Computational Insights into Mg<sup>2+</sup> Dehydration in the Presence of Carbonate (2022) · cites this paper as [69]
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Casey, W. H. (1991) · Journal of Colloid and Interface Science · doi:10.1016/0021-9797(91)90225-w · Cited by 95 · see citing works
Kinetic pathways of water exchange in the first hydration shell of magnesium
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Wood, C. E., Qafoku, O., Loring, J. S., & Chaka, A. M. (2019) · Environmental Science & Technology Letters · doi:10.1021/acs.estlett.9b00496 · Cited by 39 · see citing works
Computational Insights into Mg<sup>2+</sup> Dehydration in the Presence of Carbonate
Aufort, J., Raiteri, P., & Gale, J. D. (2022) · ACS Earth and Space Chemistry · doi:10.1021/acsearthspacechem.1c00389 · Cited by 26 · see citing works
- Authors
- Neely, J., & Connick, R.
- Affiliations
- Lawrence Berkeley National Laboratory (US)
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 1970-06
- Volume
- 92
- Issue
- 11
- Pages
- 3476-3478
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2014341239
- Cited by
- 108
- References
- 0
- Citations by year
- 2026: 5 · 2025: 3 · 2024: 1 · 2023: 2 · 2022: 7 · 2021: 5 · 2020: 4 · 2019: 3 · 2018: 1 · 2017: 4 · 2016: 1 · 2015: 3 · 2014: 5 · 2013: 3 · 2012: 3
- FWCI
- 2.92
- Type
- journal article
- Language
- en
- Open access
- green
- www.escholarship.org
- Locations
- Journal of the American Chemical Society (publishedVersion)
- eScholarship (California Digital Library) (submittedVersion)
- Topics
- Physical Sciences › Chemistry › Organic Chemistry › Inorganic and Organometallic Chemistry
- Physical Sciences › Chemistry › Organic Chemistry › Chemical Reaction Mechanisms
- Physical Sciences › Environmental Science › Waste Management and Disposal › Chemical Synthesis and Characterization
- Keywords
- water exchange, magnesium(II) complexes, coordination chemistry, reaction kinetics, ligand exchange
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