The DOI matches its Crossref record.
Self-Terminating, Oxidative Radical Cyclizations: A Novel Reaction of Acyloxyl Radicals
Abstract
Acyloxyl radicals RC(O)O* (with R = alkyl, aryl) could be trapped through addition to cyclic and open-chain alkynes, where they were found to act as a donor of oxygen atoms. Mechanistically, this radical oxygenation proceeded through a transannular or intramolecular, respectively, radical cyclization cascade, which was finally terminated by release of an acyl radical RC*(O). The reaction led to stereoselective formation of cyclized products, which contained a carbonyl group at the former site of the alkyne triple bond.
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Metadata
- Authors
- Wille, U.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2001-12-08
- Volume
- 124
- Issue
- 1
- Pages
- 14-15
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W1969449710
- Cited by
- 183
- References
- 0
- FWCI
- 15.51
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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