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Hybrid Dendritic−Linear Polyester−Ethers for in Situ Photopolymerization
Abstract
Novel first through fourth generation hybrid dendritic-linear copolymers, composed entirely of building blocks known to be biocompatible or degradable to natural metabolites in vivo, are described. Specifically, these copolymers are composed of poly(ethylene glycol), glycerol, and succinic acid and are synthesized using a divergent approach in high yield. A photo-cross-linkable derivative of this copolymer successfully seals 4.1 mm corneal lacerations. The mechanism of tissue repair is likely one of physical entrapment where an interpenetrating network (IPN) is formed between the cross-linked copolymer and the tissue.
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Cited by
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Parrish, B., Breitenkamp, R. B., & Emrick, T. (2005) · Journal of the American Chemical Society · doi:10.1021/ja050310n · Cited by 579
The chemistry of tissue adhesive materials
Bouten, P. J. M., Zonjee, M., Bender, J., Yauw, S. T. K., van Goor, H., van Hest, J. C. M., & Hoogenboom, R. (2014) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2014.02.001 · Cited by 448
Dendrimers Derived from 1 → 3 Branching Motifs
Newkome, G. R., & Shreiner, C. (2010) · Chemical Reviews · doi:10.1021/cr900341m · Cited by 347
Biodendrimer-Based Hydrogel Scaffolds for Cartilage Tissue Repair
Söntjens, S. H. M., Nettles, D. L., Carnahan, M. A., Setton, L. A., & Grinstaff, M. W. (2006) · Biomacromolecules · doi:10.1021/bm050663e · Cited by 230
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Metadata
- Authors
- Carnahan, M. A., Middleton, C., Kim, J., Kim, T., & Grinstaff, M. W.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2002-04-18
- Volume
- 124
- Issue
- 19
- Pages
- 5291-5293
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2002644771
- Cited by
- 161
- References
- 0
- FWCI
- 8.92
- Type
- journal article
- Language
- en
- Open access
- closed
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- Carnahan, M. A., Middleton, C., Kim, J., Kim, T., & Grinstaff, M. W. (2002). Hybrid Dendritic−Linear Polyester−Ethers for in Situ Photopolymerization. Journal of the American Chemical Society. https://doi.org/10.1021/ja025576y
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