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Novel Catalytic CO2 Incorporation Reaction: Nickel-Catalyzed Regio- and Stereoselective Ring-Closing Carboxylation of Bis-1,3-dienes
Abstract
Novel nickel-catalyzed carboxylation of bis-1,3-dienes using carbon dioxide (CO2) was investigated. In the presence of catalytic amounts of Ni(acac)2 and PPh3, various bis-1,3-dienes smoothly reacted with CO2 and an organozinc reagent (Et2Zn, Me2Zn, or Ph2Zn) under mild conditions. This catalytic carboxylation process was accompanied by carbocyclization of bis-1,3-diene followed by alkylation by an organozinc reagent to afford cyclic carboxylic acid derivatives in high yields with high regio- and stereoselectivities.
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Cited by
Ostapowicz, T. G., Schmitz, M., Krystof, M., Klankermayer, J., & Leitner, W. (2013) · Angewandte Chemie · doi:10.1002/ange.201304529 · Cited by 63
Metadata
- Authors
- Takimoto, M., & Mori, M.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2002-08-01
- Volume
- 124
- Issue
- 34
- Pages
- 10008-10009
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2109782609
- Cited by
- 187
- References
- 0
- FWCI
- 11.39
- Type
- journal article
- Language
- en
- Open access
- closed
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- Takimoto, M., & Mori, M. (2002). Novel Catalytic CO2 Incorporation Reaction: Nickel-Catalyzed Regio- and Stereoselective Ring-Closing Carboxylation of Bis-1,3-dienes. Journal of the American Chemical Society. https://doi.org/10.1021/ja026620c
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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