Cited by 63Carbon dioxide utilization in catalysisOrganometallic Complex Synthesis and CatalysisCO2 Reduction Techniques and Catalysts

Carbon Dioxide as a C1 Building Block for the Formation of Carboxylic Acids by Formal Catalytic Hydrocarboxylation

Ostapowicz, Thomas G., Schmitz, Marc, Krystof, Monika, Klankermayer, Jürgen, Leitner, Walter·2013·Angewandte Chemie

Abstract

Doppelrolle für Rhodium: Für die direkte Synthese von Carbonsäuren aus nicht-aktivierten Olefinen oder Alkoholen, CO2 und H2 wurde ein effektives katalytisches System gefunden. Detaillierte Analysen und Markierungsstudien ergaben, dass der Gesamtprozess der Hydrocarboxylierung einfacher Olefine aus einer Kombination der umgekehrten Wassergasreaktion (rWGS) mit einem Hydroxycarbonylierungsschritt resultiert, die beide jeweils durch einen Rh-Katalysator vermittelt werden.

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Crossref · 10.1002/ange.201304529

Cites

42 of 42 references verified0 citation errors · 0 not checkable

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  • Formation of C-C bonds is through direct carboxylation of CO2 with alkenes, alkynes, or aromatic heterocycles, affording carboxylic acid derivatives.

    “The formation of C–C bonds is through a direct carboxylation reaction (i.e., carboxylation of CO2 with alkenes, alkynes, or aromatic heterocycles), affording carboxylic acid derivatives as the target products.301,302”

    From Technologies and perspectives for achieving carbon neutrality (2021) · cites this paper as [302]

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Authors
Ostapowicz, T. G., Schmitz, M., Krystof, M., Klankermayer, J., & Leitner, W.
Affiliations
  • RWTH Aachen University (DE)
  • Max-Planck-Institut für Kohlenforschung (DE)
Corresponding author
Leitner, Walter
Venue
Angewandte Chemie
Publisher
Wiley
Published
2013-09-03
Volume
125
Issue
46
Pages
12341-12345
ISSN
  • 0044-8249 (ISSN-L)
  • 1521-3757
OpenAlex
W4253120259
Cited by
63
References
42
Citations by year
2025: 1 · 2024: 2 · 2023: 1 · 2022: 5 · 2021: 4 · 2020: 8 · 2019: 3 · 2018: 10 · 2017: 7 · 2016: 8 · 2015: 4 · 2014: 10
FWCI
3.15
Type
journal article
Language
en
Open access
closed
Locations
  • Angewandte Chemie (publishedVersion)
  • RWTH Publications (RWTH Aachen) (submittedVersion)
  • MPG.PuRe (Max Planck Society) (submittedVersion)
Topics
  • Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
  • Physical Sciences › Chemistry › Organic Chemistry › Organometallic Complex Synthesis and Catalysis
  • Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
Keywords
CO2 utilization, carboxylic acids, rhodium catalysis, alkenes, alcohol chemistry, reverse water-gas shift reaction, hydroxycarbonylation, C1 building blocks, hydrogenation, isotopic labeling

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