Carbon Dioxide as a C1 Building Block for the Formation of Carboxylic Acids by Formal Catalytic Hydrocarboxylation
Abstract
Doppelrolle für Rhodium: Für die direkte Synthese von Carbonsäuren aus nicht-aktivierten Olefinen oder Alkoholen, CO2 und H2 wurde ein effektives katalytisches System gefunden. Detaillierte Analysen und Markierungsstudien ergaben, dass der Gesamtprozess der Hydrocarboxylierung einfacher Olefine aus einer Kombination der umgekehrten Wassergasreaktion (rWGS) mit einem Hydroxycarbonylierungsschritt resultiert, die beide jeweils durch einen Rh-Katalysator vermittelt werden.
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Formation of C-C bonds is through direct carboxylation of CO2 with alkenes, alkynes, or aromatic heterocycles, affording carboxylic acid derivatives.
“The formation of C–C bonds is through a direct carboxylation reaction (i.e., carboxylation of CO2 with alkenes, alkynes, or aromatic heterocycles), affording carboxylic acid derivatives as the target products.301,302”
From Technologies and perspectives for achieving carbon neutrality (2021) · cites this paper as [302]
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Technologies and perspectives for achieving carbon neutrality
Wang, F., Harindintwali, J. D., Yuan, Z., Wang, M., Wang, F., Li, S., Yin, Z., Huang, L., Fu, Y., Li, L., et al. (2021) · The Innovation · doi:10.1016/j.xinn.2021.100180 · Cited by 1,330 · see citing works
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- Authors
- Ostapowicz, T. G., Schmitz, M., Krystof, M., Klankermayer, J., & Leitner, W.
- Affiliations
- RWTH Aachen University (DE)
- Max-Planck-Institut für Kohlenforschung (DE)
- Corresponding author
- Leitner, Walter
- Venue
- Angewandte Chemie
- Publisher
- Wiley
- Published
- 2013-09-03
- Volume
- 125
- Issue
- 46
- Pages
- 12341-12345
- ISSN
- 0044-8249 (ISSN-L)
- 1521-3757
- OpenAlex
- W4253120259
- Cited by
- 63
- References
- 42
- Citations by year
- 2025: 1 · 2024: 2 · 2023: 1 · 2022: 5 · 2021: 4 · 2020: 8 · 2019: 3 · 2018: 10 · 2017: 7 · 2016: 8 · 2015: 4 · 2014: 10
- FWCI
- 3.15
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Angewandte Chemie (publishedVersion)
- RWTH Publications (RWTH Aachen) (submittedVersion)
- MPG.PuRe (Max Planck Society) (submittedVersion)
- Topics
- Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
- Physical Sciences › Chemistry › Organic Chemistry › Organometallic Complex Synthesis and Catalysis
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
- Keywords
- CO2 utilization, carboxylic acids, rhodium catalysis, alkenes, alcohol chemistry, reverse water-gas shift reaction, hydroxycarbonylation, C1 building blocks, hydrogenation, isotopic labeling
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