The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Catalytic CO Oxidation by Free Au2-: Experiment and Theory
Abstract
Temperature-dependent rf-ion trap mass spectrometry and first-principles simulations reveal the detailed reaction mechanism of the catalytic gas-phase oxidation of CO by free Au(2)(-) ions in the presence of O(2). A metastable intermediate with a mass of Au(2)CO(3)(-) was observed at low temperatures. Two alternative structures corresponding to digold carbonate or peroxyformate are predicted for this intermediate. Both structures are characterized by low activation barriers for the formation of CO(2). These combined experimental and theoretical investigations provide a comprehensive understanding of the kinetics, energetics, and atomic arrangements along the reaction path, thus allowing a formulation of the catalytic cycle for the oxidation reaction.
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Barnett, R. N., & Landman, U. (1993) · Physical Review B · doi:10.1103/physrevb.48.2081 · Cited by 629
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Cited by
Charging Effects on Bonding and Catalyzed Oxidation of CO on Au 8 Clusters on MgO
Yoon, B., Häkkinen, H., Landman, U., Wörz, A. S., Antonietti, J.-M., Abbet, S., Judai, K., & Heiz, U. (2005) · Science · doi:10.1126/science.1104168 · Cited by 1,430
Self-citationPhotochemistry on Metal Nanoparticles
Watanabe, K., Menzel, D., Nilius, N., & Freund, H.-J. (2006) · Chemical Reviews · doi:10.1021/cr050167g · Cited by 486
Tsunoyama, H., Sakurai, H., Ichikuni, N., Negishi, Y., & Tsukuda, T. (2004) · Langmuir · doi:10.1021/la0478189 · Cited by 373
Electron Transfer at Oxide Surfaces. The MgO Paradigm: from Defects to Ultrathin Films
Pacchioni, G., & Freund, H. (2013) · Chemical Reviews · doi:10.1021/cr3002017 · Cited by 320
Metadata
- Authors
- Socaciu, L. D., Hagen, J., Bernhardt, T. M., Wöste, L., Heiz, U., Häkkinen, H., & Landman, U.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2003-08-01
- Volume
- 125
- Issue
- 34
- Pages
- 10437-10445
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2030580274
- Cited by
- 395
- References
- 1
- FWCI
- 16.53
- Type
- journal article
- Language
- en
- Open access
- closed
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