The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
A Modular Approach toward Functionalized Three-Dimensional Macromolecules: From Synthetic Concepts to Practical Applications
Abstract
A new strategy for the preparation of functional, multiarm star polymers via nitroxide-mediated "living" radical polymerization has been explored. The generality of this approach to the synthesis of three-dimensional macromolecular architectures allows for the construction of nanoscopically defined materials from a wide range of different homo, block, and random copolymers combining both apolar and polar vinylic repeat units. Functional groups can also be included along the backbone or as peripheral/chain end groups, thereby modulating the reactivity and polarity of defined portions of the stars. This modular approach to the synthesis of three-dimensional macromolecules permits the application of these tailored materials as multifunctional hosts for hydrogen bonding, nanoparticle formation, and as scaffolds for catalytic groups. Examples of applications of the functional stars in catalysis include their use in a Heck-type coupling as well as an enantioselective addition reaction.
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Benoit, D., Harth, E., Fox, P., Waymouth, R. M., & Hawker, C. J. (2000) · Macromolecules · doi:10.1021/ma991187l · Cited by 216
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Cited by
Organocatalytic Ring-Opening Polymerization
Kamber, N. E., Jeong, W., Waymouth, R. M., Pratt, R. C., Lohmeijer, B. G. G., & Hedrick, J. L. (2007) · Chemical Reviews · doi:10.1021/cr068415b · Cited by 1,489
Nitroxide-mediated polymerization
Nicolas, J., Guillaneuf, Y., Lefay, C., Bertin, D., Gigmes, D., & Charleux, B. (2013) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2012.06.002 · Cited by 1,380
Macromolecular architectures by living and controlled/living polymerizations
Hadjichristidis, N., Iatrou, H., Pitsikalis, M., & Mays, J. (2006) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2006.07.002 · Cited by 642
Metadata
- Authors
- Bosman, A. W., Vestberg, R., Heumann, A., Fréchet, J. M. J., & Hawker, C. J.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2002-12-18
- Volume
- 125
- Issue
- 3
- Pages
- 715-728
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2022897389
- Cited by
- 321
- References
- 1
- FWCI
- 14.18
- Type
- journal article
- Language
- en
- Open access
- closed
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