Organocatalytic Ring-Opening Polymerization
Abstract
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTOrganocatalytic Ring-Opening PolymerizationNahrain E. Kamber, Wonhee Jeong, Robert M. Waymouth, Russell C. Pratt, Bas G. G. Lohmeijer, and James L. HedrickView Author Information Department of Chemistry, Stanford University, Stanford, California 94305 IBM Almaden Research Center, 650 Harry Road, San Jose, California 95120 Cite this: Chem. Rev. 2007, 107, 12, 5813–5840Publication Date (Web):November 8, 2007Publication History Received15 March 2007Published online8 November 2007Published inissue 1 December 2007https://pubs.acs.org/doi/10.1021/cr068415bhttps://doi.org/10.1021/cr068415bresearch-articleACS PublicationsCopyright © 2007 American Chemical SocietyRequest reuse permissionsArticle Views25920Altmetric-Citations1289LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose SUBJECTS:Alcohols,Carbene compounds,Catalysts,Monomers,Ring-opening polymerization Get e-Alerts
Integrity signals
Registry
Cites
Statistics
Claims the paper makes
Claims other papers make about this one
Each is checked against this paper’s own text: does it say what the citing paper says it does?
Since the pioneering work of Hedrick in 2001, the application of organic catalysts to ROP has witnessed significant progress in the last 15 years and this field has grown to the point that it now provides a powerful and, in some cases, better alternative to the use of traditional metal-based catalysts.
“Since the pioneering work of Hedrick in 2001, 324 the application of organic catalysts to ROP has witnessed significant progress in the last 15 years and this field has grown to the point that it now provides a powerful and, in some cases, better alternative to the use of traditional metal-based catalysts.325,326”
From Catalysis as an Enabling Science for Sustainable Polymers (2018) · cites this paper as [325]
Cites
Room-Temperature Ionic Liquids: Solvents for Synthesis and Catalysis. 2
Hallett, J. P., & Welton, T. (2011) · Chemical Reviews · doi:10.1021/cr1003248 · Cited by 12,581 · see citing works
Room-Temperature Ionic Liquids. Solvents for Synthesis and Catalysis
Welton, T. (1999) · Chemical Reviews · doi:10.1021/cr980032t · Cited by 11,866 · see citing works
Atom Transfer Radical Polymerization
Matyjaszewski, K. A., & Xia, J. (2001) · Chemical Reviews · doi:10.1021/cr940534g · Cited by 7,646 · see citing works
Odian, G. (2004) · doi:10.1002/047147875x · Cited by 7,158 · see citing works
Chiefari, J., Chong, Y. K. (., Ercole, F., Krstina, J., Jeffery, J. L., Le, T. P. T., Mayadunne, R. T. A., Meijs, G. F., Moad, C. L., Moad, G., et al. (1998) · Macromolecules · doi:10.1021/ma9804951 · Cited by 5,154 · see citing works
The Atom Economy—A Search for Synthetic Efficiency
Trost, B. (1991) · Science · doi:10.1126/science.1962206 · Cited by 4,809 · see citing works
Arduengo, A. J., Harlow, R. L., & Kline, M. (1991) · Journal of the American Chemical Society · doi:10.1021/ja00001a054 · Cited by 4,243 · see citing works
New Polymer Synthesis by Nitroxide Mediated Living Radical Polymerizations
Hawker, C. J., Bosman, A. W., & Harth, E. M. (2001) · Chemical Reviews · doi:10.1021/cr990119u · Cited by 3,853 · see citing works
Ionic Liquid (Molten Salt) Phase Organometallic Catalysis
Dupont, J., de Souza, R. F., & Suarez, P. A. Z. (2002) · Chemical Reviews · doi:10.1021/cr010338r · Cited by 3,753 · see citing works
Bourissou, D., Guerret, O., Gabbaı̈, F. P., & Bertrand, G. (1999) · Chemical Reviews · doi:10.1021/cr940472u · Cited by 3,635 · see citing works
The Development of L 2 X 2 RuCHR Olefin Metathesis Catalysts: An Organometallic Success Story
Trnka, T. M., & Grubbs, R. H. (2000) · Accounts of Chemical Research · doi:10.1021/ar000114f · Cited by 3,561 · see citing works
Scholl, M., Ding, S., Lee, C. W., & Grubbs, R. H. (1999) · Organic Letters · doi:10.1021/ol990909q · Cited by 3,469 · see citing works
Metal-Catalyzed Living Radical Polymerization
Kamigaito, M., Ando, T., & Sawamoto, M. (2001) · Chemical Reviews · doi:10.1021/cr9901182 · Cited by 3,277 · see citing works
Surfactants and Polymers in Aqueous Solution
Holmberg, K., Jönsson, B., Kronberg, B., et al. (2002) · Wiley eBooks · doi:10.1002/0470856424 · Cited by 3,010 · see citing works
Catalytic reactions in ionic liquids.
Sheldon, R. A. (2001) · Chemical Communications · doi:10.1039/b107270f · Cited by 2,654 · see citing works
In the Golden Age of Organocatalysis
Dalko, P. I., & Moisan, L. (2004) · Angewandte Chemie International Edition · doi:10.1002/anie.200400650 · Cited by 2,594 · see citing works
Living Radical Polymerization by the RAFT Process
Moad, G., Rizzardo, E., & Thang, S. H. (2005) · Australian Journal of Chemistry · doi:10.1071/ch05072 · Cited by 2,289 · see citing works
Controlled Ring-Opening Polymerization of Lactide and Glycolide
Dechy-Cabaret, O., Martin-Vaca, B., & Bourissou, D. (2004) · Chemical Reviews · doi:10.1021/cr040002s · Cited by 2,257 · see citing works
Schwab, P., Grubbs, R. H., & Ziller, J. W. (1996) · Journal of the American Chemical Society · doi:10.1021/ja952676d · Cited by 2,118 · see citing works
Asymmetric Catalysis by Chiral Hydrogen‐Bond Donors
Taylor, M. S., & Jacobsen, E. N. (2006) · Angewandte Chemie International Edition · doi:10.1002/anie.200503132 · Cited by 1,919 · see citing works
On the Mechanism of Thiamine Action. IV.1 Evidence from Studies on Model Systems
Breslow, R. (1958) · Journal of the American Chemical Society · doi:10.1021/ja01547a064 · Cited by 1,722 · see citing works
Welton, T. (2004) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2004.04.015 · Cited by 1,610 · see citing works
Recent Developments in Ring Opening Polymerization of Lactones for Biomedical Applications
Albertsson, A.-C., & Varma, I. K. (2003) · Biomacromolecules · doi:10.1021/bm034247a · Cited by 1,582 · see citing works
Living ring-opening metathesis polymerization
Bielawski, C. W., & Grubbs, R. H. (2006) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2006.08.006 · Cited by 1,522 · see citing works
Okino, T., Hoashi, Y., & Takemoto, Y. (2003) · Journal of the American Chemical Society · doi:10.1021/ja036972z · Cited by 1,430 · see citing works
Encyclopedia of Reagents for Organic Synthesis
Caïjo, F., Ret, C. L., Crévisy, C., & Mauduit, M. (2001) · Wiley eBooks · doi:10.1002/047084289x · Cited by 1,426 · see citing works
Transesterification of vegetable oils: a review
Schuchardt, U. F., Sercheli, R., & Vargas, R. M. (1998) · Journal of the Brazilian Chemical Society · doi:10.1590/s0103-50531998000300002 · Cited by 1,346 · see citing works
Berkessel, A., & Gröger, H. (2005) · Wiley eBooks · doi:10.1002/3527604677 · Cited by 1,335 · see citing works
Polymers with Complex Architecture by Living Anionic Polymerization
Hadjichristidis, N., Pitsikalis, M., Pispas, S., & Iatrou, H. (2001) · Chemical Reviews · doi:10.1021/cr9901337 · Cited by 1,329 · see citing works
The convergence of synthetic organic and polymer chemistries
Hawker, C. J., & Wooley, K. L. (2005) · Science · doi:10.1126/science.1109778 · Cited by 1,298 · see citing works
Asymmetric synthesis of bicyclic intermediates of natural product chemistry
Hajos, Z. G., & Parrish, D. R. (1974) · The Journal of Organic Chemistry · doi:10.1021/jo00925a003 · Cited by 1,253 · see citing works
Polymerization of Lactide with Zinc and Magnesium β-Diiminate Complexes: Stereocontrol and Mechanism
Chamberlain, B. M., Cheng, M., Moore, D. R., Ovitt, T. M., Lobkovsky, E. B., & Coates, G. W. (2001) · Journal of the American Chemical Society · doi:10.1021/ja003851f · Cited by 1,207 · see citing works
4‐Dialkylaminopyridines as Highly Active Acylation Catalysts. [New synthetic method (25)]
Höfle, G., Steglich, W., & Vorbrüggen, H. (1978) · Angewandte Chemie International Edition in English · doi:10.1002/anie.197805691 · Cited by 1,204 · see citing works
Facile Synthesis of Silver(I)−Carbene Complexes. Useful Carbene Transfer Agents
Wang, H. M. J., & Lin, I. J. B. (1998) · Organometallics · doi:10.1021/om9709704 · Cited by 1,172 · see citing works
Wu, P., Feldman, A. K., Nugent, A. K., Hawker, C. J., Scheel, A., Voit, B. I., Pyun, J., Fréchet, J. M. J., Sharpless, K. B., & Fokin, V. V. (2004) · Angewandte Chemie International Edition · doi:10.1002/anie.200454078 · Cited by 1,167 · see citing works
Looking for Stable Carbenes: The Difficulty in Starting Anew
Arduengo, A. J. (1999) · Accounts of Chemical Research · doi:10.1021/ar980126p · Cited by 1,161 · see citing works
Electronic stabilization of nucleophilic carbenes
Arduengo, A. J., Dias, H. V. R., Harlow, R. L., & Kline, M. (1992) · Journal of the American Chemical Society · doi:10.1021/ja00040a007 · Cited by 1,141 · see citing works
Seayad, J., & List, B. (2005) · Organic & Biomolecular Chemistry · doi:10.1039/b415217b · Cited by 1,135 · see citing works
Supramolecular Materials: Self-Organized Nanostructures
Stupp, S. I., LeBonheur, V., Walker, K., et al. (1997) · Science · doi:10.1126/science.276.5311.384 · Cited by 1,127 · see citing works
Ag(I) N-Heterocyclic Carbene Complexes: Synthesis, Structure, and Application
Garrison, J. C., & Youngs, W. J. (2005) · Chemical Reviews · doi:10.1021/cr050004s · Cited by 1,092 · see citing works
Nucleophilic Carbenes in Asymmetric Organocatalysis
Enders, D., & Balensiefer, T. (2004) · Accounts of Chemical Research · doi:10.1021/ar030050j · Cited by 1,045 · see citing works
Nucleophilic Phosphine Organocatalysis
Methot, J. L., & Roush, W. R. (2004) · Advanced Synthesis & Catalysis · doi:10.1002/adsc.200404087 · Cited by 984 · see citing works
Kaljurand, I., Kütt, A., Sooväli, L., et al. (2005) · The Journal of Organic Chemistry · doi:10.1021/jo048252w · Cited by 961 · see citing works
Kobayashi, S., Uyama, H., & Kimura, S. (2001) · Chemical Reviews · doi:10.1021/cr990121l · Cited by 883 · see citing works
Single‐Site Heterogeneous Catalysts
Thomas, J. M., Raja, R., & Lewis, D. W. (2005) · Angewandte Chemie International Edition · doi:10.1002/anie.200462473 · Cited by 880 · see citing works
Chiral N-heterocyclic carbenes as stereodirecting ligands in asymmetric catalysis
César, V., Bellemin‐Laponnaz, S., & Gade, L. H. (2004) · Chemical Society Reviews · doi:10.1039/b406802p · Cited by 865 · see citing works
Webster, O. W., Hertler, W. R., Sogah, D. Y., et al. (1983) · Journal of the American Chemical Society · doi:10.1021/ja00355a039 · Cited by 863 · see citing works
Organocatalysis Mediated by (Thio)urea Derivatives
Connon, S. J. (2006) · Chemistry - A European Journal · doi:10.1002/chem.200501076 · Cited by 846 · see citing works
Polymerization of lactide and related cyclic esters by discrete metal complexes
O'Keefe, B. J., Hillmyer, M. A., & Tolman, W. B. (2001) · Journal of the Chemical Society, Dalton Transactions · doi:10.1039/b104197p · Cited by 825 · see citing works
Guanidine and Amidine Organocatalysts for Ring-Opening Polymerization of Cyclic Esters
Lohmeijer, B. G. G., Pratt, R. C., Leibfarth, F. A., Logan, J. W., Long, D. A., Dove, A. P., Nederberg, F., Choi, J., Wade, C. G., Waymouth, R. M., et al. (2006) · Macromolecules · doi:10.1021/ma0619381 · Cited by 815 · see citing works
Self-citationOtsu, T., & Yoshida, M. (1982) · Die Makromolekulare Chemie Rapid Communications · doi:10.1002/marc.1982.030030208 · Cited by 774 · see citing works
Recent advances in microbial polyhydroxyalkanoates
Khanna, S., & Srivastava, A. K. (2004) · Process Biochemistry · doi:10.1016/j.procbio.2004.01.053 · Cited by 766 · see citing works
Burstein, C., & Glorius, F. (2004) · Angewandte Chemie International Edition · doi:10.1002/anie.200461572 · Cited by 724 · see citing works
Sohn, S. S., Rosen, E. L., & Bode, J. W. (2004) · Journal of the American Chemical Society · doi:10.1021/ja044714b · Cited by 705 · see citing works
Polymer Synthesis by In Vitro Enzyme Catalysis
Gross, R. A., Kumar, A., & Kalra, B. (2001) · Chemical Reviews · doi:10.1021/cr0002590 · Cited by 695 · see citing works
Living alkene polymerization: New methods for the precision synthesis of polyolefins
Domski, G. J., Rose, J. M., Coates, G. W., Bolig, A. D., & Brookhart, M. (2007) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2006.11.001 · Cited by 663 · see citing works
An "Endless" Route to Cyclic Polymers
Bielawski, C. W., Benítez, D., & Grubbs, R. H. (2002) · Science · doi:10.1126/science.1075401 · Cited by 643 · see citing works
Polypeptides and 100 Years of Chemistry of α‐Amino Acid N‐Carboxyanhydrides
Kricheldorf, H. R. (2006) · Angewandte Chemie International Edition · doi:10.1002/anie.200600693 · Cited by 632 · see citing works
Modern strategies in organic catalysis: The advent and development of iminium activation
Lelais, G., & MacMillan, D. W. C. (2006) · Aldrichimica acta · Cited by 630 · see citing works
Catalyzed Addition of Aldehydes to Activated Double Bonds—A New Synthetic Approach
Stetter, H. (1976) · Angewandte Chemie International Edition in English · doi:10.1002/anie.197606391 · Cited by 624 · see citing works
A Highly Active Zinc Catalyst for the Controlled Polymerization of Lactide
Williams, C. K., Breyfogle, L. E., Choi, S. K., Nam, W., Young, V. G., Hillmyer, M. A., & Tolman, W. B. (2003) · Journal of the American Chemical Society · doi:10.1021/ja0359512 · Cited by 607 · see citing works
Kricheldorf, H. R., Berl, M., & Scharnagl, N. (1988) · Macromolecules · doi:10.1021/ma00180a002 · Cited by 597 · see citing works
Molecular Size Distribution in Ethylene Oxide Polymers
Flory, P. J. (1940) · Journal of the American Chemical Society · doi:10.1021/ja01863a066 · Cited by 575 · see citing works
4-Dialkylaminopyridines: super acylation and alkylation catalysts
Scriven, E. F. V. (1983) · Chemical Society Reviews · doi:10.1039/cs9831200129 · Cited by 573 · see citing works
McCormick, C. L., & Lowe, A. B. (2004) · Accounts of Chemical Research · doi:10.1021/ar0302484 · Cited by 556 · see citing works
Trnka, T. M., Morgan, J. P., Sanford, M. S., Wilhelm, T. E., Scholl, M., Choi, T., Ding, S., Day, M. W., & Grubbs, R. H. (2003) · Journal of the American Chemical Society · doi:10.1021/ja021146w · Cited by 547 · see citing works
Chiral N-heterocyclic carbene-transition metal complexes in asymmetric catalysis
Perry, M. C., & Burgess, K. (2003) · Tetrahedron Asymmetry · doi:10.1016/s0957-4166(03)00037-5 · Cited by 544 · see citing works
Enders, D., Breuer, K., Raabe, G., et al. (1995) · Angewandte Chemie International Edition in English · doi:10.1002/anie.199510211 · Cited by 544 · see citing works
Pratt, R. C., Lohmeijer, B. G. G., Long, D. A., Waymouth, R. M., & Hedrick, J. L. (2006) · Journal of the American Chemical Society · doi:10.1021/ja060662+ · Cited by 543 · see citing works
Self-citationN,N‐Dimethyl‐4‐pyridinamine, a Very Effective Acylation Catalyst
Steglich, W., & Höfle, G. (1969) · Angewandte Chemie International Edition in English · doi:10.1002/anie.196909811 · Cited by 531 · see citing works
Crystallization and Melting Behavior of Polylactides
Sarasua, J.-R., Prud'homme, R. E., Wisniewski, M., Le Borgne, A., & Spassky, N. (1998) · Macromolecules · doi:10.1021/ma971545p · Cited by 525 · see citing works
A Highly Enantioselective Catalytic Intramolecular Stetter Reaction
Kerr, M. S., de Alaniz, J. R., & Rovis, T. (2002) · Journal of the American Chemical Society · doi:10.1021/ja027411v · Cited by 504 · see citing works
Connor, E. F., Nyce, G. W., Myers, M. B., Möck, A., & Hedrick, J. L. (2002) · Journal of the American Chemical Society · doi:10.1021/ja0173324 · Cited by 474 · see citing works
Self-citationSteinbüchel, A., & Lütke‐Eversloh, T. (2003) · Biochemical Engineering Journal · doi:10.1016/s1369-703x(03)00036-6 · Cited by 472 · see citing works
A novel synthesis of functional dithioesters, dithiocarbamates, xanthates and trithiocarbonates
Thang, S. H., Chong, (. K., Mayadunne, R. T. A., Moad, G., & Rizzardo, E. (1999) · Tetrahedron Letters · doi:10.1016/s0040-4039(99)00177-x · Cited by 459 · see citing works
Arduengo, A. J., Goerlich, J. R., & Marshall, W. (1995) · Journal of the American Chemical Society · doi:10.1021/ja00149a034 · Cited by 452 · see citing works
Basicity of Nucleophilic Carbenes in Aqueous and Nonaqueous SolventsTheoretical Predictions
Magill, A. M., Cavell, K. J., & Yates, B. F. (2004) · Journal of the American Chemical Society · doi:10.1021/ja038973x · Cited by 451 · see citing works
Thiourea-Based Bifunctional Organocatalysis: Supramolecular Recognition for Living Polymerization
Dove, A. P., Pratt, R. C., Lohmeijer, B. G. G., Waymouth, R. M., & Hedrick, J. L. (2005) · Journal of the American Chemical Society · doi:10.1021/ja0543346 · Cited by 439 · see citing works
Self-citationAspects of Nucleophilic Carbene Chemistry
Wanzlick, H. (1962) · Angewandte Chemie International Edition in English · doi:10.1002/anie.196200751 · Cited by 438 · see citing works
Holden, G. (1987) · Springer eBooks · doi:10.1007/978-1-4615-7823-9_16 · Cited by 436 · see citing works
Pratt, R. C., Lohmeijer, B. G. G., Long, D. A., Lundberg, P., Dove, A. P., Li, H., Wade, C. G., Waymouth, R. M., & Hedrick, J. L. (2006) · Macromolecules · doi:10.1021/ma061607o · Cited by 419 · see citing works
Self-citationPeralkylated Polyaminophosphazenes— Extremely Strong, Neutral Nitrogen Bases
Schwesinger, R., & Schlemper, H. (1987) · Angewandte Chemie International Edition in English · doi:10.1002/anie.198711671 · Cited by 417 · see citing works
Rieth, L. R., Moore, D. R., Lobkovsky, E. B., & Coates, G. W. (2002) · Journal of the American Chemical Society · doi:10.1021/ja020978r · Cited by 414 · see citing works
Reynolds, N. T., de Alaniz, J. R., & Rovis, T. (2004) · Journal of the American Chemical Society · doi:10.1021/ja046991o · Cited by 383 · see citing works
Enantioselective Aza-Henry Reaction Catalyzed by a Bifunctional Organocatalyst
Okino, T., Nakamura, S., Furukawa, T., & Takemoto, Y. (2004) · Organic Letters · doi:10.1021/ol0364531 · Cited by 380 · see citing works
Lebel, H., Janes, M. K., Charette, A. B., et al. (2004) · Journal of the American Chemical Society · doi:10.1021/ja049759r · Cited by 376 · see citing works
Culkin, D. A., Jeong, W., Csihony, S., Gomez, E. D., Balsara, N. P., Hedrick, J. L., & Waymouth, R. M. (2007) · Angewandte Chemie International Edition · doi:10.1002/anie.200604740 · Cited by 375 · see citing works
Self-citationChisholm, M. H., Gallucci, J. C., & Phomphrai, K. (2002) · Chemical Communications · doi:10.1039/b208679d · Cited by 370 · see citing works
Grasa, G. A., Kissling, R. M., & Nolan, S. P. (2002) · Organic Letters · doi:10.1021/ol0264760 · Cited by 356 · see citing works
Organocatalytic Ring Opening Polymerization of Trimethylene Carbonate
Nederberg, F., Lohmeijer, B. G. G., Leibfarth, F. A., Pratt, R. C., Choi, J., Dove, A. P., Waymouth, R. M., & Hedrick, J. L. (2006) · Biomacromolecules · doi:10.1021/bm060795n · Cited by 346 · see citing works
Self-citationThe Organic Approach to Asymmetric Catalysis
List, B., & Yang, J. W. (2006) · Science · doi:10.1126/science.1131945 · Cited by 343 · see citing works
Herrmann, W. A., Öfele, K., Preysing, D. V., et al. (2003) · Journal of Organometallic Chemistry · doi:10.1016/j.jorganchem.2003.07.028 · Cited by 338 · see citing works
Nyce, G. W., Lamboy, J. A., Connor, E. F., Waymouth, R. M., & Hedrick, J. L. (2002) · Organic Letters · doi:10.1021/ol0267228 · Cited by 333 · see citing works
Self-citationBosman, A. W., Vestberg, R., Heumann, A., et al. (2002) · Journal of the American Chemical Society · doi:10.1021/ja028392s · Cited by 321 · see citing works
An Air Stable Carbene and Mixed Carbene “Dimers”
Arduengo, A. J., Davidson, F., Dias, H. V. R., et al. (1997) · Journal of the American Chemical Society · doi:10.1021/ja973241o · Cited by 319 · see citing works
Tributylphosphine: a remarkable acylation catalyst
Vedējs, E., & Diver, S. T. (1993) · Journal of the American Chemical Society · doi:10.1021/ja00061a056 · Cited by 316 · see citing works
Duong, H. A., Tekavec, T. N., Arif, A. M., et al. (2003) · Chemical Communications · doi:10.1039/b311350g · Cited by 310 · see citing works
Nyce, G. W., Glauser, T., Connor, E. F., Möck, A., Waymouth, R. M., & Hedrick, J. L. (2003) · Journal of the American Chemical Society · doi:10.1021/ja021084+ · Cited by 301 · see citing works
Self-citationThe First Asymmetric Intramolecular Stetter Reaction. Preliminary Communication
Enders, D., Breuer, K., Runsink, J., et al. (1996) · Helvetica Chimica Acta · doi:10.1002/hlca.19960790712 · Cited by 300 · see citing works
N-Heterocyclic Carbene-Catalyzed Amidation of Unactivated Esters with Amino Alcohols
Movassaghi, M., & Schmidt, M. A. (2005) · Organic Letters · doi:10.1021/ol050773y · Cited by 300 · see citing works
Stable carbenes as strong bases
Alder, R. W., Allen, P. R., & Williams, S. J. (1995) · Journal of the Chemical Society Chemical Communications · doi:10.1039/c39950001267 · Cited by 284 · see citing works
Semiconductor Nanohelices Templated by Supramolecular Ribbons
Sone, E. D., Zubarev, E. R., & Stupp, S. I. (2002) · Angewandte Chemie International Edition · doi:10.1002/1521-3773(20020517)41:10 · Cited by 275 · see citing works
Hoashi, Y., Okino, T., & Takemoto, Y. (2005) · Angewandte Chemie International Edition · doi:10.1002/anie.200500459 · Cited by 275 · see citing works
Enzyme catalyzed synthesis of polyesters
Varma, I. K., Albertsson, A.-C., Rajkhowa, R., & Srivastava, R. K. (2005) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2005.06.010 · Cited by 274 · see citing works
Zhang, L., Nederberg, F., Pratt, R. C., Waymouth, R. M., Hedrick, J. L., & Wade, C. G. (2007) · Macromolecules · doi:10.1021/ma070316s · Cited by 273 · see citing works
Self-citationSpivey, A. C., & Arseniyadis, S. (2004) · Angewandte Chemie International Edition · doi:10.1002/anie.200460373 · Cited by 269 · see citing works
Highly Efficient Dynamic Kinetic Resolution of Azlactones by Urea‐Based Bifunctional Organocatalysts
Berkessel, A., Cleemann, F., Mukherjee, S., et al. (2005) · Angewandte Chemie International Edition · doi:10.1002/anie.200461442 · Cited by 268 · see citing works
Ein neuer Zugang zur Carben‐Chemie
Wanzlick, H., & Schikora, E. (1960) · Angewandte Chemie · doi:10.1002/ange.19600721409 · Cited by 255 · see citing works
XCVI.—Reactions involving the addition of hydrogen cyanide to carbon compounds
Lapworth, A. (1903) · Journal of the Chemical Society Transactions · doi:10.1039/ct9038300995 · Cited by 235 · see citing works
Efficient Transesterification/Acylation Reactions Mediated byN-Heterocyclic Carbene Catalysts
Grasa, G. A., Güveli, T., Singh, R., & Nolan, S. P. (2003) · The Journal of Organic Chemistry · doi:10.1021/jo0267551 · Cited by 235 · see citing works
Enantioselective Acylations Catalyzed by Chiral Phosphines
Vedējs, E., Daugulis, O., & Diver, S. T. (1996) · The Journal of Organic Chemistry · doi:10.1021/jo951661v · Cited by 231 · see citing works
Controlled Cationic Polymerization of Lactide
Bourissou, D., Martin-Vaca, B., Dumitrescu, A., Graullier, M., & Lacombe, F. (2005) · Macromolecules · doi:10.1021/ma051646k · Cited by 226 · see citing works
Enzymatic Ring-Opening Polymerization of Lactones Catalyzed by Lipase
Uyama, H., & Kobayashi, S. (1993) · Chemistry Letters · doi:10.1246/cl.1993.1149 · Cited by 217 · see citing works
Basicity of a Stable Carbene, 1,3-Di-tert-butylimidazol-2-ylidene, in THF1
Kim, Y., & STREITWIESER, A. J. (2002) · Journal of the American Chemical Society · doi:10.1021/ja025628j · Cited by 216 · see citing works
Statistics of Polymer Molecular Size Distribution for an Invariant Number of Propagating Chains
Gold, L. (1958) · The Journal of Chemical Physics · doi:10.1063/1.1744088 · Cited by 215 · see citing works
Organic Spirocyclic Initiators for the Ring-Expansion Polymerization of β-Lactones
Jeong, W., Hedrick, J. L., & Waymouth, R. M. (2007) · Journal of the American Chemical Society · doi:10.1021/ja072037q · Cited by 212 · see citing works
Self-citationShibasaki, Y., Sanada, H., Yokoi, M., Sanda, F., & Endo, T. (2000) · Macromolecules · doi:10.1021/ma992138b · Cited by 210 · see citing works
A General and Versatile Approach to Thermally Generated N‐Heterocyclic Carbenes
Nyce, G. W., Csihony, S., Waymouth, R. M., & Hedrick, J. L. (2004) · Chemistry - A European Journal · doi:10.1002/chem.200400196 · Cited by 209 · see citing works
Self-citationDual Living Free Radical and Ring Opening Polymerizations from a Double-Headed Initiator
Hawker, C. J., Hedrick, J. L., Malmström, E., Trollsås, M., Mecerreyes, D., Moineau, G., Dúbois, P., & Jérôme, R. (1998) · Macromolecules · doi:10.1021/ma971335c · Cited by 206 · see citing works
Self-citationKnight, R. L., & Leeper, F. J. (1998) · Journal of the Chemical Society Perkin Transactions 1 · doi:10.1039/a803635g · Cited by 205 · see citing works
Percec, V., Barboiu, B., Grigoras, C. V., et al. (2003) · Journal of the American Chemical Society · doi:10.1021/ja034746j · Cited by 203 · see citing works
Tributylphosphine-catalyzed acylations of alcohols: scope and related reactions
Vedējs, E., Bennett, N., Conn, L. M., Diver, S. T., Gingras, M., Lin, S., Oliver, P. A., & Peterson, M. J. (1993) · The Journal of Organic Chemistry · doi:10.1021/jo00077a064 · Cited by 202 · see citing works
Murry, J. A., Frantz, D. E., Soheili, A., et al. (2001) · Journal of the American Chemical Society · doi:10.1021/ja0165943 · Cited by 200 · see citing works
Polypeptide and Polypeptide Hybrid Copolymer Synthesis via NCA Polymerization
Deming, T. J. (2006) · Springer eBooks · doi:10.1007/12_080 · Cited by 200 · see citing works
Dove, A. P., Li, H., Pratt, R. C., Lohmeijer, B. G. G., Culkin, D. A., Waymouth, R. M., & Hedrick, J. L. (2006) · Chemical Communications · doi:10.1039/b601393g · Cited by 195 · see citing works
Self-citationEnantioselective Acylation of Secondary Alcohols Catalyzed by Chiral N-Heterocyclic Carbenes
Kano, T., Sasaki, K., & Maruoka, K. (2005) · Organic Letters · doi:10.1021/ol050174r · Cited by 194 · see citing works
Teles, J. H., Melder, J., Ebel, K., et al. (1996) · Helvetica Chimica Acta · doi:10.1002/hlca.19960790108 · Cited by 188 · see citing works
In Situ Preparation of a Highly Active N-Heterocyclic Carbene-Coordinated Olefin Metathesis Catalyst
Morgan, J. P., & Grubbs, R. H. (2000) · Organic Letters · doi:10.1021/ol0063510 · Cited by 185 · see citing works
Vedējs, E., & Daugulis, O. (1999) · Journal of the American Chemical Society · doi:10.1021/ja990133o · Cited by 185 · see citing works
Catalytic Dehalogenation of Aryl Halides Mediated by a Palladium/Imidazolium Salt System
Viciu, M. S., Grasa, G. A., & Nolan, S. P. (2001) · Organometallics · doi:10.1021/om010332s · Cited by 184 · see citing works
Säureamid‐Reaktionen, L; Orthoamide, I Darstellung und Eigenschaften der Amidacetale und Aminalester
Bredereck, H., Simchen, G., Rebsdat, S., et al. (1968) · Chemische Berichte · doi:10.1002/cber.19681010108 · Cited by 183 · see citing works
Transesterification/Acylation of Secondary Alcohols Mediated by N -Heterocyclic Carbene Catalysts
Singh, R., Kissling, R. M., Letellier, M., & Nolan, S. P. (2003) · The Journal of Organic Chemistry · doi:10.1021/jo035431p · Cited by 183 · see citing works
Homogeneous Asymmetric Catalysis
Sheehan, J. C., & Hunneman, D. H. (1966) · Journal of the American Chemical Society · doi:10.1021/ja00967a049 · Cited by 183 · see citing works
Single-Component Catalyst/Initiators for the Organocatalytic Ring-Opening Polymerization of Lactide
Csihony, S., Culkin, D. A., Sentman, A. C., Dove, A. P., Waymouth, R. M., & Hedrick, J. L. (2005) · Journal of the American Chemical Society · doi:10.1021/ja050909n · Cited by 180 · see citing works
Self-citationKowalski, A., Libiszowski, J., Biela, T., Cypryk, M., Duda, A., & Penczek, S. (2005) · Macromolecules · doi:10.1021/ma050752j · Cited by 179 · see citing works
Star Polymer Synthesis from ε-Caprolactone Utilizing Polyol/Protonic Acid Initiator
Sanda, F., Sanada, H., Shibasaki, Y., & Endo, T. (2001) · Macromolecules · doi:10.1021/ma011341f · Cited by 176 · see citing works
Polylactones, 8. Mechanism of the cationic polymerization of L,L ‐dilactide
Kricheldorf, H. R., & Dunsing, R. (1986) · Die Makromolekulare Chemie · doi:10.1002/macp.1986.021870706 · Cited by 168 · see citing works
Stereoelective polymerization of d,l-lactide using N-heterocyclic carbene based compounds
Jensen, T. R., Breyfogle, L. E., Hillmyer, M. A., & Tolman, W. B. (2004) · Chemical Communications · doi:10.1039/b405362a · Cited by 162 · see citing works
Coulembier, O., Lohmeijer, B. G. G., Dove, A. P., Pratt, R. C., Mespouille, L., Culkin, D. A., Benight, S. J., Dúbois, P., Waymouth, R. M., & Hedrick, J. L. (2006) · Macromolecules · doi:10.1021/ma0611366 · Cited by 159 · see citing works
Self-citationHydroacylation of Activated Ketones Catalyzed by N -Heterocyclic Carbenes
Chan, A., & Scheidt, K. A. (2006) · Journal of the American Chemical Society · doi:10.1021/ja060833a · Cited by 158 · see citing works
Novel Amine Chemistry Based on DMAP-Catalyzed Acylation
Ragnarsson, U., & Grehn, L. (1998) · Accounts of Chemical Research · doi:10.1021/ar980001k · Cited by 156 · see citing works
Latent, Thermally Activated Organic Catalysts for the On‐Demand Living Polymerization of Lactide
Coulembier, O., Dove, A. P., Pratt, R. C., Sentman, A. C., Culkin, D. A., Mespouille, L., Dúbois, P., Waymouth, R. M., & Hedrick, J. L. (2005) · Angewandte Chemie International Edition · doi:10.1002/anie.200500723 · Cited by 155 · see citing works
Self-citationN-Heterocyclic carbenes: Effective organic catalysts for living polymerization
Dove, A. P., Pratt, R. C., Lohmeijer, B. G. G., Culkin, D. A., Hagberg, E. C., Nyce, G. W., Waymouth, R. M., & Hedrick, J. L. (2006) · Polymer · doi:10.1016/j.polymer.2006.02.037 · Cited by 154 · see citing works
Self-citationNucleophile Carben‐Chemie Darstellung des Bis‐[1.3‐diphenyl‐imidazolidinyliden‐(2)]
Wanzlick, H., & Kleiner, H. ‐. (1961) · Angewandte Chemie · doi:10.1002/ange.19610731408 · Cited by 153 · see citing works
Application of Complex Macromolecular Architectures for Advanced Microelectronic Materials
Hedrick, J. L., Magbitang, T., Connor, E. F., Glauser, T., Volksen, W., Hawker, C. J., Lee, V. Y., & Miller, R. D. (2002) · Chemistry - A European Journal · doi:10.1002/1521-3765(20020802)8:15 · Cited by 153 · see citing works
Self-citationPolylactones, 19. Anionic polymerization of <scp>L</scp>‐lactide in solution
Kricheldorf, H. R., & Kreiser‐Saunders, I. (1990) · Die Makromolekulare Chemie · doi:10.1002/macp.1990.021910508 · Cited by 149 · see citing works
Kinetik und Mechanismus der ringöffnenden Polymerisation von L(—)‐Lactid
Dittrich, V. W., & Schulz, R. C. (1971) · Die Angewandte Makromolekulare Chemie · doi:10.1002/apmc.1971.050150109 · Cited by 149 · see citing works
Schlaad, H., Kukula, H., Rudloff, J., & Below, I. (2001) · Macromolecules · doi:10.1021/ma010311+ · Cited by 148 · see citing works
An Activated Equivalent of Lactide toward Organocatalytic Ring-Opening Polymerization
Boullay, O. T. D., Marchal, E., Martín-Vaca, B. M., Cossío, F. P., & Bourissou, D. (2006) · Journal of the American Chemical Society · doi:10.1021/ja067046y · Cited by 144 · see citing works
Berkessel, A., Mukherjee, S., Cleemann, F., et al. (2005) · Chemical Communications · doi:10.1039/b418666d · Cited by 143 · see citing works
First example of chiral N-heterocyclic carbenes as catalysts for kinetic resolution
Suzuki, Y., Yamauchi, K., Muramatsu, K., et al. (2004) · Chemical Communications · doi:10.1039/b411855c · Cited by 143 · see citing works
Tetraaminoethylenes. The Question of Dissociation
Lemal, D. M., Lovald, R. A., & Kawano, K. I. (1964) · Journal of the American Chemical Society · doi:10.1021/ja01066a044 · Cited by 142 · see citing works
Enzymatic Synthesis of Polyesters via Ring-Opening Polymerization
Matsumura, S. (2005) · Advances in polymer science · doi:10.1007/12_030 · Cited by 139 · see citing works
Organocatalytic Living Ring-Opening Polymerization of Cyclic Carbosiloxanes
Lohmeijer, B. G. G., Dubois, G., Leibfarth, F. A., et al. (2006) · Organic Letters · doi:10.1021/ol0614166 · Cited by 136 · see citing works
Self-citationChemical Reactions of the Stable Carbene 1,3,4‐Triphenyl‐4,5‐dihydro‐1H‐1,2,4‐triazol‐5‐ylidene
Enders, D., Breuer, K., Runsink, J., et al. (1996) · Liebigs Annalen · doi:10.1002/jlac.199619961212 · Cited by 136 · see citing works
1.2‐Dianilino‐äthan als Aldehydreagens
Wanzlick, H., & Löchel, W. (1953) · Chemische Berichte · doi:10.1002/cber.19530861116 · Cited by 127 · see citing works
Synthesis of Block Copolymers of 2- and 4-Vinylpyridine by RAFT Polymerization
Convertine, A. J., Sumerlin, B. S., Thomas, D. B., Lowe, A. B., & McCormick, C. L. (2003) · Macromolecules · doi:10.1021/ma034361l · Cited by 127 · see citing works
Winberg, H. E., Carnahan, J. E., Coffman, D. D., et al. (1965) · Journal of the American Chemical Society · doi:10.1021/ja01087a040 · Cited by 127 · see citing works
Enhancing the Catalytic Activity of 4‐(Dialkylamino)pyridines by Conformational Fixation
Heinrich, M. R., Klisa, H. S., Mayr, H., et al. (2003) · Angewandte Chemie International Edition · doi:10.1002/anie.200352289 · Cited by 124 · see citing works
Wanzlick, H., Esser, F., & Kleiner, H. (1963) · Chemische Berichte · doi:10.1002/cber.19630960505 · Cited by 121 · see citing works
Lou, X., Detrembleur, C., & Jérôme, R. (2002) · Macromolecules · doi:10.1021/ma0113677 · Cited by 119 · see citing works
Jedliński, Z., Wałach, W., Kurcok, P., & Adamus, G. (1991) · Die Makromolekulare Chemie · doi:10.1002/macp.1991.021920914 · Cited by 116 · see citing works
A fast catalyst system for the ring‐opening polymerization of cyclosiloxanes
Molenberg, A., & Möller, M. (1995) · Macromolecular Rapid Communications · doi:10.1002/marc.1995.030160606 · Cited by 115 · see citing works
New Developments in the Origins of the Homochirality of Biologically Relevant Molecules
Buschmann, H., Thede, R., & Heller, D. (2000) · Angewandte Chemie International Edition · doi:10.1002/1521-3773(20001117)39:22 · Cited by 111 · see citing works
Ring-Opening Polymerization of ε-Caprolactone Initiated by Natural Amino Acids
Liu, J., & Liu, L. (2004) · Macromolecules · doi:10.1021/ma0348066 · Cited by 108 · see citing works
Stereochemistry of the ring-opening polymerization of (S)-.beta.-butyrolactone
Zhang, Y., Gross, R. A., & Lenz, R. W. (1990) · Macromolecules · doi:10.1021/ma00215a002 · Cited by 107 · see citing works
Sentman, A. C., Csihony, S., Waymouth, R. M., & Hedrick, J. L. (2005) · The Journal of Organic Chemistry · doi:10.1021/jo048555q · Cited by 104 · see citing works
Self-citationSynthesis and Catalyst Issues Associated with ADMET Polymerization
Schwendeman, J. E., Church, A. C., & Wagener, K. B. (2002) · Advanced Synthesis & Catalysis · doi:10.1002/1615-4169(200208)344:6/7 · Cited by 104 · see citing works
Catalytic activity of N-heterocyclic carbenes in ring opening polymerization of cyclic siloxanes
Rodriguez, M., Marrot, S., Kato, T., et al. (2006) · Journal of Organometallic Chemistry · doi:10.1016/j.jorganchem.2006.10.006 · Cited by 103 · see citing works
Polylactones, 11. Cationic copolymerization of glycolide with L , L ‐dilactide
Kricheldorf, H. R., & Kreiser‐Saunders, I. (1987) · Die Makromolekulare Chemie · doi:10.1002/macp.1987.021880810 · Cited by 102 · see citing works
Kemnitzer, J. E., McCarthy, S. P., & Gross, R. A. (1992) · Macromolecules · doi:10.1021/ma00048a011 · Cited by 102 · see citing works
Berkessel, A., Mukherjee, S., Müller, T. N., et al. (2006) · Organic & Biomolecular Chemistry · doi:10.1039/b607574f · Cited by 100 · see citing works
Multiblock Copolymers of l -Lactide and Trimethylene Carbonate
Pospiech, D., Komber, H., Jehnichen, D., Häußler, L., Eckstein, K., Scheibner, H., Janke, A., Kricheldorf, H. R., & Petermann, O. (2004) · Biomacromolecules · doi:10.1021/bm049393a · Cited by 99 · see citing works
Kinetic Resolution of Allylic Alcohols Using a Chiral Phosphine Catalyst
Vedējs, E., & MacKay, J. A. (2001) · Organic Letters · doi:10.1021/ol006923g · Cited by 99 · see citing works
1,5,7-Triazabicyclo[4.4.0]dec-5-ene (TBD) catalyzed Michael reactions
Ye, W., Xu, J., Tan, C., et al. (2005) · Tetrahedron Letters · doi:10.1016/j.tetlet.2005.08.010 · Cited by 99 · see citing works
Direct Organocatalytic Ring‐Opening Polymerizations of Lactones
Casas, J., Persson, P. V., Iversen, T., & Córdova, A. (2004) · Advanced Synthesis & Catalysis · doi:10.1002/adsc.200404082 · Cited by 96 · see citing works
Nederberg, F., Connor, E. F., Glausser, T., & Hedrick, J. L. (2001) · Chemical Communications · doi:10.1039/b106125a · Cited by 95 · see citing works
Self-citationVedējs, E., & Rozners, E. (2001) · Journal of the American Chemical Society · doi:10.1021/ja0035405 · Cited by 92 · see citing works
Chemie nucleophiler Carbene, XVIII1) 1.3.4.5‐Tetraphenyl‐imidazoliumperchlorat
Schönherr, H. ‐., & Wanzlick, H. (1970) · Justus Liebig s Annalen der Chemie · doi:10.1002/jlac.19707310121 · Cited by 90 · see citing works
Samantaray, M. K., Katiyar, V., Roy, D., Pang, K., Nanavati, H., Stephen, R., Sunoj, R. B., & Ghosh, P. (2006) · European Journal of Inorganic Chemistry · doi:10.1002/ejic.200600209 · Cited by 90 · see citing works
Nucleophilic carbenes and the wanzlick equilibrium: A reinvestigation
Denk, M. K., Hatano, K., & Ma, M. (1999) · Tetrahedron Letters · doi:10.1016/s0040-4039(99)00164-1 · Cited by 88 · see citing works
Dubois, P., Barakat, I., Jerome, R., & Teyssie, P. (1993) · Macromolecules · doi:10.1021/ma00069a003 · Cited by 86 · see citing works
Jedliński, Z., Kurcok, P., & Lenz, R. W. (1998) · Macromolecules · doi:10.1021/ma980663p · Cited by 86 · see citing works
One-Pot Chemoenzymatic Cascade Polymerization under Kinetic Resolution Conditions
van As, B. A. C., Thomassen, P. J., Kalra, B., et al. (2004) · Macromolecules · doi:10.1021/ma048827r · Cited by 85 · see citing works
Theoretical study on the mechanism of N-heterocyclic carbene catalyzed transesterification reactions
Lai, C.-L., Lee, H. M., & Hu, C.-H. (2005) · Tetrahedron Letters · doi:10.1016/j.tetlet.2005.07.046 · Cited by 83 · see citing works
Structure of active species in the cationic polymerization of β‐propiolactone and ε‐caprolactone
Hofman, A., Szymański, R., Słomkowski, S., & Penczek, S. (1984) · Die Makromolekulare Chemie · doi:10.1002/macp.1984.021850405 · Cited by 79 · see citing works
Chiral N-heterocyclic carbenes as asymmetric acylation catalysts
Suzuki, Y., Muramatsu, K., Yamauchi, K., et al. (2005) · Tetrahedron · doi:10.1016/j.tet.2005.09.071 · Cited by 79 · see citing works
Kim, M. S., Seo, K. S., Khang, G., & Lee, H. B. (2005) · Macromolecular Rapid Communications · doi:10.1002/marc.200400650 · Cited by 79 · see citing works
Persson, P. V., Schröder, J., Wickholm, K., Hedenström, E., & Iversen, T. (2004) · Macromolecules · doi:10.1021/ma049562j · Cited by 78 · see citing works
Stereoelective polymerization of β-butyrolactone
Borgne, A. L., & Spassky, N. (1989) · Polymer · doi:10.1016/0032-3861(89)90267-x · Cited by 77 · see citing works
Jafarpour, L., & Nolan, S. P. (2000) · Organometallics · doi:10.1021/om000203w · Cited by 75 · see citing works
Introduction to macromolecular science
(2002) · Choice Reviews Online · doi:10.5860/choice.39-6436 · Cited by 74 · see citing works
Murayama, M., Sanda, F., & Endo, T. (1998) · Macromolecules · doi:10.1021/ma970878j · Cited by 73 · see citing works
Investigation of Factors Influencing the Chemoenzymatic Synthesis of Block Copolymers
de Geus, M., Peeters, J. W., Wolffs, M., et al. (2005) · Macromolecules · doi:10.1021/ma0473871 · Cited by 71 · see citing works
Preparation of polyacetylene chains in low-polydispersity diblock and triblock copolymers
Krouse, S. A., & Schrock, R. R. (1988) · Macromolecules · doi:10.1021/ma00184a064 · Cited by 69 · see citing works
Cyclic Polypeptides by Solvent-Induced Polymerizations of α-Amino Acid N-Carboxyanhydrides
Kricheldorf, H. R., von Lossow, C., & Schwarz, G. (2005) · Macromolecules · doi:10.1021/ma0401368 · Cited by 68 · see citing works
β-Thiopeptides: Synthesis, NMR Solution Structure, CD Spectra, and Photochemistry
Sifferlen, T., Rueping, M., Gademann, K., Jaun, B., & Seebàch, D. (1999) · Helvetica Chimica Acta · doi:10.1002/(sici)1522-2675(19991215)82:12 · Cited by 68 · see citing works
Polylactones 26. Lithium alkoxide‐initiated polymerizations of L ‐lactide
Kricheldorf, H. R., & Boettcher, C. (1993) · Die Makromolekulare Chemie · doi:10.1002/macp.1993.021940614 · Cited by 66 · see citing works
Hori, Y., & Hagiwara, T. (1999) · International Journal of Biological Macromolecules · doi:10.1016/s0141-8130(99)00038-0 · Cited by 65 · see citing works
Selective Ring Opening Cross Metathesis of Cyclooctadiene and Trisubstituted Cycloolefins
Morgan, J. P., Morrill, C., & Grubbs, R. H. (2001) · Organic Letters · doi:10.1021/ol016918s · Cited by 63 · see citing works
Flagged first, then by citations
Cited by
Sorted by citations
Chemical recycling to monomer for an ideal, circular polymer economy
Coates, G. W., & Getzler, Y. D. Y. L. (2020) · Nature Reviews Materials · doi:10.1038/s41578-020-0190-4 · Cited by 1,644 · see citing works
Catalysis as an Enabling Science for Sustainable Polymers
Zhang, X., Fevre, M., Jones, G. O., & Waymouth, R. M. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00329 · Cited by 936 · see citing works
Self-citationOrganocatalysis: Opportunities and Challenges for Polymer Synthesis
Kiesewetter, M. K., Shin, E. J., Hedrick, J. L., & Waymouth, R. M. (2010) · Macromolecules · doi:10.1021/ma9025948 · Cited by 907 · see citing works
Self-citationChemically recyclable polymers: a circular economy approach to sustainability
Hong, M., & Chen, E. Y.-X. (2017) · Green Chemistry · doi:10.1039/c7gc01496a · Cited by 876 · see citing works
Hong, M., & Chen, E. Y.-X. (2016) · Nature Chemistry · doi:10.1038/nchem.2391 · Cited by 677 · see citing works
Aliphatic Polyester Block Polymers: Renewable, Degradable, and Sustainable
Hillmyer, M. A., & Tolman, W. B. (2014) · Accounts of Chemical Research · doi:10.1021/ar500121d · Cited by 635 · see citing works
Metal-catalyzed immortal ring-opening polymerization of lactones, lactides and cyclic carbonates
Ajellal, N., Carpentier, J.-F., Guillaume, C., Guillaume, S. M., Helou, M., Poirier, V., Sarazin, Y., & Trifonov, A. (2010) · Dalton Transactions · doi:10.1039/c001226b · Cited by 494 · see citing works
Controlled Polymerization of Next-Generation Renewable Monomers and Beyond
Yao, K., & Tang, C. (2013) · Macromolecules · doi:10.1021/ma3019574 · Cited by 485 · see citing works
Tardy, A., Nicolas, J., Gigmes, D., Lefay, C., & Guillaneuf, Y. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00319 · Cited by 469 · see citing works
A circular economy approach to plastic waste
Payne, J., McKeown, P., & Jones, M. D. (2019) · Polymer Degradation and Stability · doi:10.1016/j.polymdegradstab.2019.05.014 · Cited by 385 · see citing works
Metal catalysts for ε-caprolactone polymerisation
Arbaoui, A., & Redshaw, C. (2010) · Polymer Chemistry · doi:10.1039/b9py00334g · Cited by 383 · see citing works
Tempelaar, S., Mespouille, L., Coulembier, O., Dubois, P., & Dove, A. P. (2013) · Chem. Soc. Rev. · doi:10.1039/c2cs35268k · Cited by 345 · see citing works
Makiguchi, K., Satoh, T., & Kakuchi, T. (2011) · Macromolecules · doi:10.1021/ma200043x · Cited by 338 · see citing works
Aliphatic Polyester Block Polymer Design
Schneiderman, D. K., & Hillmyer, M. A. (2016) · Macromolecules · doi:10.1021/acs.macromol.6b00211 · Cited by 290 · see citing works
McKinlay, C. J., Vargas, J. R., Blake, T. R., Hardy, J. W., Kanada, M., Contag, C. H., Wender, P. A., & Waymouth, R. M. (2017) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1614193114 · Cited by 288 · see citing works
Self-citationUrea Anions: Simple, Fast, and Selective Catalysts for Ring-Opening Polymerizations
Lin, B., & Waymouth, R. M. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.6b11864 · Cited by 278 · see citing works
Self-citationHong, M., & Chen, E. Y. ‐. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201601092 · Cited by 259 · see citing works
Zwitterionic Ring-Opening Polymerization for the Synthesis of High Molecular Weight Cyclic Polymers
Brown, H. A., & Waymouth, R. M. (2013) · Accounts of Chemical Research · doi:10.1021/ar400072z · Cited by 255 · see citing works
Self-citationThermodynamic Presynthetic Considerations for Ring-Opening Polymerization
Olsén, P., Odelius, K., & Albertsson, A.-C. (2016) · Biomacromolecules · doi:10.1021/acs.biomac.5b01698 · Cited by 244 · see citing works
Guillaume, S. M., Kirillov, E., Sarazin, Y., & Carpentier, J. (2015) · Chemistry – A European Journal · doi:10.1002/chem.201500613 · Cited by 251 · see citing works
Poly(phosphoester)s: A new platform for degradable polymers
Steinbach, T., & Wurm, F. R. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201500147 · Cited by 219 · see citing works
Bauer, K. N., Tee, H. T., Velencoso, M. M., & Wurm, F. R. (2017) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2017.05.004 · Cited by 189 · see citing works
Tang, X., Hong, M., Falivene, L., Caporaso, L., Cavallo, L., & Chen, E. Y.-X. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b07974 · Cited by 179 · see citing works
Zhu, J.-B., & Chen, E. Y.-X. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b08658 · Cited by 173 · see citing works
Synthetic biodegradable polyhydroxyalkanoates (PHAs): Recent advances and future challenges
Westlie, A. H., Quinn, E. C., Parker, C. R., & Chen, E. Y.-X. (2022) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2022.101608 · Cited by 166 · see citing works
Recent Developments in Ring-Opening Polymerization of Lactones
Lecomte, P., & Jérôme, C. (2011) · Advances in Polymer Science · doi:10.1007/12_2011_144 · Cited by 163 · see citing works
Makiguchi, K., Ogasawara, Y., Kikuchi, S., Satoh, T., & Kakuchi, T. (2013) · Macromolecules · doi:10.1021/ma4000495 · Cited by 165 · see citing works
Gazeau-Bureau, S., Delcroix, D., Martín-Vaca, B., Bourissou, D., Navarro, C., & Magnet, S. (2008) · Macromolecules · doi:10.1021/ma800626q · Cited by 165 · see citing works
Dyer, H. E., Huijser, S., Susperregui, N., Bonnet, F., Schwarz, A. D., Duchateau, R., Maron, L., & Mountford, P. (2010) · Organometallics · doi:10.1021/om100513j · Cited by 158 · see citing works
Bouyahyi, M., Pepels, M. P. F., Heise, A., & Duchateau, R. (2012) · Macromolecules · doi:10.1021/ma3001675 · Cited by 157 · see citing works
Synthesis of Poly(lactide)s with Modified Thermal and Mechanical Properties
Becker, J. M., Pounder, R. J., & Dove, A. P. (2010) · Macromolecular Rapid Communications · doi:10.1002/marc.201000088 · Cited by 146 · see citing works
Ke, X., Ng, V. W. L., Ono, R. J., Chan, J. M. W., Krishnamurthy, S., Wang, Y., Hedrick, J. L., & Yang, Y. Y. (2014) · Journal of Controlled Release · doi:10.1016/j.jconrel.2014.06.061 · Cited by 146 · see citing works
Self-citationTransforming polylactide into value‐added materials
Leibfarth, F. A., Moreno, N., Hawker, A. P., & Shand, J. D. (2012) · Journal of Polymer Science Part A: Polymer Chemistry · doi:10.1002/pola.26303 · Cited by 139 · see citing works
Ebrahim Attia, A. B., Yang, C., Tan, J. P. K., Gao, S., Williams, D. F., Hedrick, J. L., & Yang, Y.-Y. (2013) · Biomaterials · doi:10.1016/j.biomaterials.2013.01.042 · Cited by 131 · see citing works
Wang, Q., Zhao, W., He, J., Zhang, Y., & Chen, E. Y.-X. (2017) · Macromolecules · doi:10.1021/acs.macromol.6b02398 · Cited by 127 · see citing works
Arbaoui, A., Redshaw, C., & Hughes, D. L. (2008) · Chemical Communications · doi:10.1039/b810417d · Cited by 122 · see citing works
TBD catalysis with dimethyl carbonate: a fruitful and sustainable alliance
Mutlu, H., Ruiz, J., Solleder, S. C., & Meier, M. A. R. (2012) · Green Chemistry · doi:10.1039/c2gc35191a · Cited by 116 · see citing works
Drug releasing nanoplatforms activated by alternating magnetic fields
Mertz, D., Sandre, O., & Bégin-Colin, S. (2017) · Biochimica et Biophysica Acta (BBA) - General Subjects · doi:10.1016/j.bbagen.2017.02.025 · Cited by 119 · see citing works
Fastnacht, K. V., Spink, S. S., Dharmaratne, N. U., Pothupitiya, J. U., Datta, P. P., Kiesewetter, E. T., & Kiesewetter, M. K. (2016) · ACS Macro Letters · doi:10.1021/acsmacrolett.6b00527 · Cited by 109 · see citing works
Guillaume, S. M., & Carpentier, J.-F. (2012) · Catalysis Science & Technology · doi:10.1039/c2cy00507g · Cited by 102 · see citing works
Organocatalysis in biorefining for biomass conversion and upgrading
Liu, D. (. J. )., & Chen, E. Y.-X. (2014) · Green Chem. · doi:10.1039/c3gc41934g · Cited by 101 · see citing works
Naumann, S., Thomas, A. W., & Dove, A. P. (2016) · ACS Macro Letters · doi:10.1021/acsmacrolett.5b00873 · Cited by 97 · see citing works
Horn, H. W., Jones, G. O., Wei, D. S., Fukushima, K., Lecuyer, J. M., Coady, D. J., Hedrick, J. L., & Rice, J. E. (2012) · The Journal of Physical Chemistry A · doi:10.1021/jp304212y · Cited by 97 · see citing works
Self-citationFliedel, C., Vila‐Viçosa, D., Calhorda, M. J., Dagorne, S., & Avilés, T. (2014) · ChemCatChem · doi:10.1002/cctc.201301015 · Cited by 95 · see citing works
Florczak, M., & Duda, A. (2008) · Angewandte Chemie International Edition · doi:10.1002/anie.200803540 · Cited by 94 · see citing works
Schwarz, A. D., Thompson, A. L., & Mountford, P. (2009) · Inorganic Chemistry · doi:10.1021/ic901524s · Cited by 91 · see citing works
Li, X., Clarke, R. W., An, H., Gowda, R. R., Jiang, J., Xu, T., & Chen, E. Y. ‐. (2023) · Angewandte Chemie International Edition · doi:10.1002/anie.202303791 · Cited by 93 · see citing works
Alamri, H., Zhao, J., Pahovnik, D., & Hadjichristidis, N. (2014) · Polym. Chem. · doi:10.1039/c4py00493k · Cited by 89 · see citing works
Zhao, J., Pahovnik, D., Gnanou, Y., & Hadjichristidis, N. (2014) · Polym. Chem. · doi:10.1039/c4py00429a · Cited by 79 · see citing works
Redox Control of Aluminum Ring-Opening Polymerization: A Combined Experimental and DFT Investigation
Wei, J., Riffel, M. N., & Diaconescu, P. L. (2017) · Macromolecules · doi:10.1021/acs.macromol.6b02402 · Cited by 76 · see citing works
Miyake, G. M., & Chen, E. Y.-X. (2011) · Macromolecules · doi:10.1021/ma2007199 · Cited by 78 · see citing works
Liu, B., Roisnel, T., Maron, L., Carpentier, J., & Sarazin, Y. (2013) · Chemistry – A European Journal · doi:10.1002/chem.201204340 · Cited by 74 · see citing works
Barros, N., Mountford, P., Guillaume, S. M., & Maron, L. (2008) · Chemistry – A European Journal · doi:10.1002/chem.200800377 · Cited by 73 · see citing works
Nifant’ev, I., & Ivchenko, P. (2019) · Molecules · doi:10.3390/molecules24224117 · Cited by 72 · see citing works
Quinn, E. C., Westlie, A. H., Sangroniz, A., Caputo, M. R., Xu, S., Zhang, Z., Urgun-Demirtas, M., Müller, A. J., & Chen, E. Y.-X. (2023) · Journal of the American Chemical Society · doi:10.1021/jacs.2c12897 · Cited by 70 · see citing works
Spink, S. S., Kazakov, O. I., Kiesewetter, E. T., & Kiesewetter, M. K. (2015) · Macromolecules · doi:10.1021/acs.macromol.5b01320 · Cited by 68 · see citing works
Gesslbauer, S., Savela, R., Chen, Y., White, A. J. P., & Romain, C. (2019) · ACS Catalysis · doi:10.1021/acscatal.9b00875 · Cited by 64 · see citing works
Fang, J., Yu, I., Mehrkhodavandi, P., & Maron, L. (2013) · Organometallics · doi:10.1021/om400399k · Cited by 59 · see citing works
Advances in urea and thiourea catalyzed ring opening polymerization: A brief overview
Jain, I., & Malik, P. (2020) · European Polymer Journal · doi:10.1016/j.eurpolymj.2020.109791 · Cited by 56 · see citing works
Walshe, A., Fang, J., Maron, L., & Baker, R. J. (2013) · Inorganic Chemistry · doi:10.1021/ic401275e · Cited by 50 · see citing works
Miao, Y., Rousseau, C., Mortreux, A., Martin, P., & Zinck, P. (2011) · Polymer · doi:10.1016/j.polymer.2011.08.040 · Cited by 50 · see citing works
Pappuru, S., Chokkapu, E. R., Chakraborty, D., & Ramkumar, V. (2013) · Dalton Transactions · doi:10.1039/c3dt52065j · Cited by 47 · see citing works
Guillerm, B., Lemaur, V., Cornil, J., Lazzaroni, R., Dubois, P., & Coulembier, O. (2014) · Chem. Commun. · doi:10.1039/c4cc03347g · Cited by 37 · see citing works
Marchetti, F., Pampaloni, G., Pinzino, C., Renili, F., Repo, T., & Vuorinen, S. (2013) · Dalton Trans. · doi:10.1039/c2dt31264f · Cited by 34 · see citing works
Zhao, W., Wang, Q., Cui, Y., He, J., & Zhang, Y. (2019) · Dalton Transactions · doi:10.1039/c8dt03941k · Cited by 29 · see citing works
Initiation of ring-opening polymerization of lactide: The effect of metal alkoxide catalyst
Cheshmedzhieva, D., Angelova, I., Ilieva, S., Georgiev, G. S., & Galabov, B. (2012) · Computational and Theoretical Chemistry · doi:10.1016/j.comptc.2012.06.015 · Cited by 27 · see citing works
Sattayanon, C., Kungwan, N., Punyodom, W., Meepowpan, P., & Jungsuttiwong, S. (2013) · Journal of Molecular Modeling · doi:10.1007/s00894-013-2026-2 · Cited by 25 · see citing works
Susperregui, N., Kramer, M. U., Okuda, J., & Maron, L. (2011) · Organometallics · doi:10.1021/om100606p · Cited by 22 · see citing works
Wang, B., Wei, Y., Li, Z., Pan, L., & Li, Y. (2018) · ChemCatChem · doi:10.1002/cctc.201801488 · Cited by 21 · see citing works
Deokar, M. D., Garnaik, B., & Sivaram, S. (2022) · ACS Omega · doi:10.1021/acsomega.1c04486 · Cited by 21 · see citing works
Jikei, M., Suga, T., Yamadoi, Y., & Matsumoto, K. (2017) · Polymer Journal · doi:10.1038/pj.2016.126 · Cited by 18 · see citing works
Poly(hydroxyalkanoate)s from Waste Biomass: A Combined Chemical–Biological Approach
Flanagan, J. C. A., Myung, J., Criddle, C. S., & Waymouth, R. M. (2016) · ChemistrySelect · doi:10.1002/slct.201600592 · Cited by 20 · see citing works
Self-citationUndin, J., Olsén, P., Godfrey, J., Odelius, K., & Albertsson, A.-C. (2016) · Polymer · doi:10.1016/j.polymer.2016.01.067 · Cited by 17 · see citing works
Progress in Catalytic Ring-Opening Polymerization of Biobased Lactones
Al-Shok, L., Haddleton, D. M., & Adams, F. (2022) · Advances in Polymer Science · doi:10.1007/12_2021_111 · Cited by 10 · see citing works
Wang, Y., Mehmood, A., Zhao, Y., Qu, J., & Luo, Y. (2017) · Inorganics · doi:10.3390/inorganics5030046 · Cited by 10 · see citing works
Wang, T.-F., Kosuru, S. R., Yu, S.-C., Chang, Y.-C., Lai, H.-Y., Chang, Y.-L., Wu, K.-H., Ding, S., & Chen, H.-Y. (2020) · RSC Advances · doi:10.1039/d0ra07824g · Cited by 9 · see citing works
Nifant’ev, I. E., Ivchenko, P. V., Shlyakhtin, A. V., & Ivanyuk, A. V. (2017) · Polymer Science, Series B · doi:10.1134/s1560090417020075 · Cited by 8 · see citing works
Naolou, T., Lendlein, A., & Neffe, A. T. (2019) · Frontiers in Chemistry · doi:10.3389/fchem.2019.00346 · Cited by 5 · see citing works
Organocatalyst‐Catalyzed Non‐Radical Photopolymerizations
Liao, Y., & Liao, S. (2025) · Organocatalysts in Polymer Chemistry · doi:10.1002/9783527843077.ch13
- Authors
- Kamber, N. E., Jeong, W., Waymouth, R. M., Pratt, R. C., Lohmeijer, B. G. G., & Hedrick, J. L.
- Affiliations
- Stanford University (US)
- IBM Research - Almaden (US)
- Corresponding author
- Waymouth, Robert M.
- Hedrick, James L.
- Venue
- Chemical Reviews
- Publisher
- American Chemical Society (ACS)
- Published
- 2007-11-08
- Volume
- 107
- Issue
- 12
- Pages
- 5813-5840
- ISSN
- 0009-2665 (ISSN-L)
- 1520-6890
- OpenAlex
- W2049930363
- Cited by
- 1,489
- References
- 249
- Citations by year
- 2026: 42 · 2025: 63 · 2024: 70 · 2023: 71 · 2022: 82 · 2021: 70 · 2020: 96 · 2019: 81 · 2018: 107 · 2017: 101 · 2016: 95 · 2015: 79 · 2014: 101 · 2013: 100 · 2012: 103
- FWCI
- 3.60
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Chemical Reviews (publishedVersion)
- PubMed (publishedVersion)
- Topics
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
- Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
- Keywords
- organocatalysis, ring-opening polymerization, polymerization catalysts, monomers, alcohol chemistry
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review