The DOI matches its Crossref record; 15 of the 15 references it cites were found in a registry or an index.
Solvent-Free Functionalization of Carbon Nanotubes
Abstract
A fundamentally new single-walled and multiwalled carbon nanotube sidewall functionalization technique has been developed in which solvent is not required and the reaction times are greatly shortened (1 h at 60 degrees C). Exploiting the long linear dimension of the nanotube ropes by macroscopic mechanical deformation, reactive sites are generated merely by mechanically deforming the tubes using a stir bar. This approach eliminates the need for large volumes of solvent ( approximately 2 L/g), which were formerly considered essential due to the insolubility of carbon nanotubes. Using a series of 4-substituted anilines and a nitrite, the aryl diazonium intermediates were generated in situ and permitted to react with the tubes. Raman, IR, and UV spectroscopies, coupled with thermogravimetric analyses and solubility studies, support the assignments.
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Citations
Cites
Carbon Nanotubes--the Route Toward Applications
Baughman, R. H., Zakhidov, A. A., & de Heer, W. A. (2002) · Science · doi:10.1126/science.1060928 · Cited by 10,267
Single-shell carbon nanotubes of 1-nm diameter
Iijima, S., & Ichihashi, T. (1993) · Nature · doi:10.1038/363603a0 · Cited by 9,012
Functionalization of Single-Walled Carbon Nanotubes
Hirsch, A. (2002) · Angewandte Chemie International Edition · doi:10.1002/1521-3773(20020603)41:11<1853::aid-anie1853>3.0.co;2-n · Cited by 2,146
Solvent-Free Organic Synthesis
Tanaka, K., & Toda, F. (2000) · Chemical Reviews · doi:10.1021/cr940089p · Cited by 2,091
Gas-phase catalytic growth of single-walled carbon nanotubes from carbon monoxide
Nikolaev, P., Bronikowski, M. J., Bradley, R. K., Rohmund, F., Colbert, D. T., Smith, K. A., & Smalley, R. E. (1999) · Chemical Physics Letters · doi:10.1016/s0009-2614(99)01029-5 · Cited by 1,822
Carbon nanotubes, buckyballs, ropes, and a universal graphitic potential
Girifalco, L. A., Hodak, M., & Lee, R. S. (2000) · Physical Review B · doi:10.1103/physrevb.62.13104 · Cited by 1,601
Chemistry of Single-Walled Carbon Nanotubes
Niyogi, S., Hamon, M. A., Hu, H., Zhao, B., Bhowmik, P., Sen, R., Itkis, M. E., & Haddon, R. C. (2002) · Accounts of Chemical Research · doi:10.1021/ar010155r · Cited by 1,556
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Self-citationOrganic Functionalization of Carbon Nanotubes
Georgakilas, V., Kordatos, K., Prato, M., Guldi, D. M., Holzinger, M., & Hirsch, A. (2002) · Journal of the American Chemical Society · doi:10.1021/ja016954m · Cited by 1,194
Covalent chemistry of single-wall carbon nanotubes
Bahr, J. L., & Tour, J. M. (2002) · Journal of Materials Chemistry · doi:10.1039/b201013p · Cited by 871
Self-citation
Cited by
Advanced Carbon Electrode Materials for Molecular Electrochemistry
McCreery, R. L. (2008) · Chemical Reviews · doi:10.1021/cr068076m · Cited by 2,729
Mesoporous carbon materials: Synthesis and modification
Liang, C., Li, Z., & Dai, S. (2008) · Angewandte Chemie International Edition · doi:10.1002/anie.200702046 · Cited by 1,935
Metadata
- Authors
- Dyke, C. A., & Tour, J. M.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2003-01-09
- Volume
- 125
- Issue
- 5
- Pages
- 1156-1157
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2022179117
- Cited by
- 522
- References
- 15
- FWCI
- 20.77
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
