The DOI matches its Crossref record; 15 of the 15 references it cites were found in a registry or an index.
Solvent-Free Functionalization of Carbon Nanotubes
Abstract
A fundamentally new single-walled and multiwalled carbon nanotube sidewall functionalization technique has been developed in which solvent is not required and the reaction times are greatly shortened (1 h at 60 degrees C). Exploiting the long linear dimension of the nanotube ropes by macroscopic mechanical deformation, reactive sites are generated merely by mechanically deforming the tubes using a stir bar. This approach eliminates the need for large volumes of solvent ( approximately 2 L/g), which were formerly considered essential due to the insolubility of carbon nanotubes. Using a series of 4-substituted anilines and a nitrite, the aryl diazonium intermediates were generated in situ and permitted to react with the tubes. Raman, IR, and UV spectroscopies, coupled with thermogravimetric analyses and solubility studies, support the assignments.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Carbon Nanotubes--the Route Toward Applications
Baughman, R. H., Zakhidov, A. A., & de Heer, W. A. (2002) · Science · doi:10.1126/science.1060928 · Cited by 10,267
Single-shell carbon nanotubes of 1-nm diameter
Iijima, S., & Ichihashi, T. (1993) · Nature · doi:10.1038/363603a0 · Cited by 9,012
Functionalization of Single-Walled Carbon Nanotubes
Hirsch, A. (2002) · Angewandte Chemie International Edition · doi:10.1002/1521-3773(20020603)41:11<1853::aid-anie1853>3.0.co;2-n · Cited by 2,146
Solvent-Free Organic Synthesis
Tanaka, K., & Toda, F. (2000) · Chemical Reviews · doi:10.1021/cr940089p · Cited by 2,091
Gas-phase catalytic growth of single-walled carbon nanotubes from carbon monoxide
Nikolaev, P., Bronikowski, M. J., Bradley, R. K., Rohmund, F., Colbert, D. T., Smith, K. A., & Smalley, R. E. (1999) · Chemical Physics Letters · doi:10.1016/s0009-2614(99)01029-5 · Cited by 1,822
Carbon nanotubes, buckyballs, ropes, and a universal graphitic potential
Girifalco, L. A., Hodak, M., & Lee, R. S. (2000) · Physical Review B · doi:10.1103/physrevb.62.13104 · Cited by 1,601
Chemistry of Single-Walled Carbon Nanotubes
Niyogi, S., Hamon, M. A., Hu, H., Zhao, B., Bhowmik, P., Sen, R., Itkis, M. E., & Haddon, R. C. (2002) · Accounts of Chemical Research · doi:10.1021/ar010155r · Cited by 1,556
Bahr, J. L., Yang, J., Kosynkin, D. V., Bronikowski, M. J., Smalley, R. E., & Tour, J. M. (2001) · Journal of the American Chemical Society · doi:10.1021/ja010462s · Cited by 1,412
Self-citationOrganic Functionalization of Carbon Nanotubes
Georgakilas, V., Kordatos, K., Prato, M., Guldi, D. M., Holzinger, M., & Hirsch, A. (2002) · Journal of the American Chemical Society · doi:10.1021/ja016954m · Cited by 1,194
Covalent chemistry of single-wall carbon nanotubes
Bahr, J. L., & Tour, J. M. (2002) · Journal of Materials Chemistry · doi:10.1039/b201013p · Cited by 871
Self-citationChiang, I. W., Brinson, B. E., Huang, A. Y., Willis, P. A., Bronikowski, M. J., Margrave, J. L., Smalley, R. E., & Hauge, R. H. (2001) · The Journal of Physical Chemistry B · doi:10.1021/jp0114891 · Cited by 744
Highly Functionalized Carbon Nanotubes Using in Situ Generated Diazonium Compounds
Bahr, J. L., & Tour, J. M. (2001) · Chemistry of Materials · doi:10.1021/cm0109903 · Cited by 687
Self-citationDispersion of Functionalized Carbon Nanotubes in Polystyrene
Mitchell, C. A., Bahr, J. L., Arepalli, S., Tour, J. M., & Krishnamoorti, R. (2002) · Macromolecules · doi:10.1021/ma020890y · Cited by 595
Self-citationElectronic band structure of isolated and bundled carbon nanotubes
Reich, S., Thomsen, C., & Ordejón, P. (2002) · Physical Review B · doi:10.1103/physrevb.65.155411 · Cited by 379
Transformation of carbon nanotubes to nanoparticles by ball milling process
Li, Y. B., Wei, B. Q., Liang, J., Yu, Q., & Wu, D. H. (1999) · Carbon · doi:10.1016/s0008-6223(98)00218-8 · Cited by 194
Cited by
Advanced Carbon Electrode Materials for Molecular Electrochemistry
McCreery, R. L. (2008) · Chemical Reviews · doi:10.1021/cr068076m · Cited by 2,729
Mesoporous carbon materials: Synthesis and modification
Liang, C., Li, Z., & Dai, S. (2008) · Angewandte Chemie International Edition · doi:10.1002/anie.200702046 · Cited by 1,935
Metadata
- Authors
- Dyke, C. A., & Tour, J. M.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2003-01-09
- Volume
- 125
- Issue
- 5
- Pages
- 1156-1157
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2022179117
- Cited by
- 522
- References
- 15
- FWCI
- 20.77
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
