The DOI matches its Crossref record; 45 of the 45 references it cites were found in a registry or an index.
Controlled Formation of Highly Organized Mesoporous Titania Thin Films: From Mesostructured Hybrids to Mesoporous Nanoanatase TiO2
Abstract
In this paper, we report the complete synthesis and characterization procedures to generate highly organized and oriented mesoporous titania thin films, using poly(ethylene oxide) (PEO)-based templates. Controlled conditions in the deposition, postsynthesis, and thermal treatment steps allow one to tailor the final mesostructure (2D hexagonal, p6m, or 3D cubic, Im3m). Various techniques were used to determine the time evolution of the mesostructure. Spectroscopic techniques (UV/vis, (17)O NMR) and EXAFS/XANES have been used to follow the chemical changes in the Ti(IV) environment. Crossing these techniques spanning all ranges permits a complete description of the chemistry all the way from solution to the mesostructured metal oxide. A critical discussion on all important chemical and processing parameters is provided; the understanding of these features is essential for a rational design and the reproducible construction of mesoporous materials.
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Cites
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Cited by
On the controllable soft-templating approach to mesoporous silicates
Wan, Y., & Zhao (2007) · Chemical Reviews · doi:10.1021/cr068020s · Cited by 2,371
Cao, S.-W., & Zhu, Y.-J. (2010) · Nanoscale Research Letters · doi:10.1007/s11671-010-9742-7 · Cited by 2,357
Biomimetism and bioinspiration as tools for the design of innovative materials and systems
Sanchez, C., Arribart, H., & Giraud Guille, M. M. (2005) · Nature Materials · doi:10.1038/nmat1339 · Cited by 1,449
Self-citationPhotoelectrocatalytic materials for environmental applications
Zhang, H., Chen, G., & Bahnemann, D. W. (2009) · Journal of Materials Chemistry · doi:10.1039/b821991e · Cited by 960
Mesoporous materials and electrochemistry
Walcarius, A. (2013) · Chemical Society Reviews · doi:10.1039/c2cs35322a · Cited by 623
Metadata
- Authors
- Crepaldi, E. L., Soler-Illia, G. J. D. A. A., Grosso, D., Cagnol, F., Ribot, F., & Sanchez, C.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2003-07-17
- Volume
- 125
- Issue
- 32
- Pages
- 9770-9786
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2019645703
- Cited by
- 911
- References
- 45
- FWCI
- 36.24
- Type
- journal article
- Language
- en
- Open access
- closed
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- Crepaldi, E. L., Soler-Illia, G. J. D. A. A., Grosso, D., Cagnol, F., Ribot, F., & Sanchez, C. (2003). Controlled Formation of Highly Organized Mesoporous Titania Thin Films: From Mesostructured Hybrids to Mesoporous Nanoanatase TiO2. Journal of the American Chemical Society. https://doi.org/10.1021/ja030070g
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