The DOI matches its Crossref record; 45 of the 45 references it cites were found in a registry or an index.
Controlled Formation of Highly Organized Mesoporous Titania Thin Films: From Mesostructured Hybrids to Mesoporous Nanoanatase TiO2
Abstract
In this paper, we report the complete synthesis and characterization procedures to generate highly organized and oriented mesoporous titania thin films, using poly(ethylene oxide) (PEO)-based templates. Controlled conditions in the deposition, postsynthesis, and thermal treatment steps allow one to tailor the final mesostructure (2D hexagonal, p6m, or 3D cubic, Im3m). Various techniques were used to determine the time evolution of the mesostructure. Spectroscopic techniques (UV/vis, (17)O NMR) and EXAFS/XANES have been used to follow the chemical changes in the Ti(IV) environment. Crossing these techniques spanning all ranges permits a complete description of the chemistry all the way from solution to the mesostructured metal oxide. A critical discussion on all important chemical and processing parameters is provided; the understanding of these features is essential for a rational design and the reproducible construction of mesoporous materials.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism
Kresge, C. T., Leonowicz, M. E., Roth, W. J., Vartuli, J. C., & Beck, J. S. (1992) · Nature · doi:10.1038/359710a0 · Cited by 16,275
Triblock Copolymer Syntheses of Mesoporous Silica with Periodic 50 to 300 Angstrom Pores
Zhao, D., Feng, J., Huo, Q., Melosh, N., Fredrickson, G. H., Chmelka, B. F., & Stucky, G. D. (1998) · Science · doi:10.1126/science.279.5350.548 · Cited by 11,753
A new family of mesoporous molecular sieves prepared with liquid crystal templates
Beck, J. S., Vartuli, J. C., Roth, W. J., Leonowicz, M. E., Kresge, C. T., Schmitt, K. D., Chu, C. T. W., Olson, D. H., Sheppard, E. W., McCullen, S. B., et al. (1992) · Journal of the American Chemical Society · doi:10.1021/ja00053a020 · Cited by 10,967
Zhao, D., Huo, Q., Feng, J., Chmelka, B. F., & Stucky, G. D. (1998) · Journal of the American Chemical Society · doi:10.1021/ja974025i · Cited by 6,697
Light-Induced Redox Reactions in Nanocrystalline Systems
Hagfeldt, A., & Graetzel, M. (1995) · Chemical Reviews · doi:10.1021/cr00033a003 · Cited by 5,357
Bach, U., Lupo, D., Comte, P., Moser, J. E., Weissörtel, F., Salbeck, J., Spreitzer, H., & Grätzel, M. (1998) · Nature · doi:10.1038/26936 · Cited by 3,528
Gas Adsorption Characterization of Ordered Organic−Inorganic Nanocomposite Materials
Kruk, M., & Jaroniec, M. (2001) · Chemistry of Materials · doi:10.1021/cm0101069 · Cited by 3,413
Theoretical approaches to x-ray absorption fine structure
Rehr, J. J., & Albers, R. C. (2000) · Reviews of Modern Physics · doi:10.1103/revmodphys.72.621 · Cited by 3,301
Multiple-scattering calculations of x-ray-absorption spectra
Zabinsky, S. I., Rehr, J. J., Ankudinov, A., Albers, R. C., & Eller, M. J. (1995) · Physical Review B · doi:10.1103/physrevb.52.2995 · Cited by 2,944
Evaporation-Induced Self-Assembly: Nanostructures Made Easy
Brinker, C. J., Lu, Y., Sellinger, A., & Fan, H. (1999) · Advanced Materials · doi:10.1002/(sici)1521-4095(199905)11:7<579::aid-adma579>3.0.co;2-r · Cited by 2,079
Soler-Illia, G. J. D. A. A., Sanchez, C., Lebeau, B., & Patarin, J. (2002) · Chemical Reviews · doi:10.1021/cr0200062 · Cited by 1,958
Self-citationEXAFS: Basic Principles and Data Analysis
Teo, B. K. (1986) · Inorganic Chemistry Concepts · doi:10.1007/978-3-642-50031-2 · Cited by 1,735
Surfactant Control of Phases in the Synthesis of Mesoporous Silica-Based Materials
Huo, Q., Margolese, D. I., & Stucky, G. D. (1996) · Chemistry of Materials · doi:10.1021/cm960137h · Cited by 1,567
Organization of Organic Molecules with Inorganic Molecular Species into Nanocomposite Biphase Arrays
Huo, Q., Margolese, D. I., Ciesla, U., Demuth, D. G., Feng, P., Gier, T. E., Sieger, P., Firouzi, A., & Chmelka, B. F. (1994) · Chemistry of Materials · doi:10.1021/cm00044a016 · Cited by 1,483
Continuous formation of supported cubic and hexagonal mesoporous films by sol–gel dip-coating
Lu, Y., Ganguli, R., Drewien, C. A., Anderson, M. T., Brinker, C. J., Gong, W., Guo, Y., Soyez, H., Dunn, B., Huang, M. H., et al. (1997) · Nature · doi:10.1038/38699 · Cited by 1,467
Thermodynamic analysis of phase stability of nanocrystalline titania
Zhang, H., & Banfield, J. F. (1998) · Journal of Materials Chemistry · doi:10.1039/a802619j · Cited by 1,322
Toll-like receptor-2 mediates lipopolysaccharide-induced cellular signalling
Yang, R.-B., Mark, M. R., Gray, A., Huang, A., Xie, M. H., Zhang, M., Goddard, A., Wood, W. I., Gurney, A. L., & Godowski, P. J. (1998) · Nature · doi:10.1038/26239 · Cited by 1,205
Yang, P., Zhao, D., Margolese, D. I., Chmelka, B. F., & Stucky, G. D. (1999) · Chemistry of Materials · doi:10.1021/cm990185c · Cited by 1,135
Synthesis of Hexagonally Packed Mesoporous TiO2 by a Modified Sol–Gel Method
Antonelli, D. M., & Ying, J. Y. (1995) · Angewandte Chemie International Edition in English · doi:10.1002/anie.199520141 · Cited by 1,109
Aerosol-assisted self-assembly of mesostructured spherical nanoparticles
Lu, Y., Fan, H., Stump, A., Ward, T. L., Rieker, T., & Brinker, C. J. (1999) · Nature · doi:10.1038/18410 · Cited by 985
Continuous Mesoporous Silica Films with Highly Ordered Large Pore Structures
Zhao, D., Yang, P., Melosh, N., Feng, J., Chmelka, B. F., & Stucky, G. D. (1998) · Advanced Materials · doi:10.1002/(sici)1521-4095(199811)10:16<1380::aid-adma1380>3.0.co;2-8 · Cited by 886
Direct imaging of the pores and cages of three-dimensional mesoporous materials
Sakamoto, Y., Kaneda, M., Terasaki, O., Zhao, D. Y., Kim, J. M., Stucky, G., Shin, H. J., & Ryoo, R. (2000) · Nature · doi:10.1038/35044040 · Cited by 876
Non-siliceous Mesostructured and Mesoporous Materials
Schüth, F. (2001) · Chemistry of Materials · doi:10.1021/cm011030j · Cited by 847
Chemical modification of alkoxide precursors
Sanchez, C., Livage, J., Henry, M., & Babonneau, F. (1988) · Journal of Non-Crystalline Solids · doi:10.1016/0022-3093(88)90007-5 · Cited by 797
Self-citationBarton, T. J., Bull, L. M., Klemperer, W. G., Loy, D. A., McEnaney, B., Misono, M., Monson, P. A., Pez, G., Scherer, G. W., Vartuli, J. C., et al. (1999) · Chemistry of Materials · doi:10.1021/cm9805929 · Cited by 764
Template-Based Approaches to the Preparation of Amorphous, Nanoporous Silicas
Raman, N. K., Anderson, M. T., & Brinker, C. J. (1996) · Chemistry of Materials · doi:10.1021/cm960138+ · Cited by 742
Synthesis of oriented films of mesoporous silica on mica
Yang, H., Kuperman, A., Coombs, N., Mamiche-Afara, S., & Ozin, G. A. (1996) · Nature · doi:10.1038/379703a0 · Cited by 692
Alberius, P. C. A., Frindell, K. L., Hayward, R. C., Kramer, E. J., Stucky, G. D., & Chmelka, B. F. (2002) · Chemistry of Materials · doi:10.1021/cm011209u · Cited by 671
Impéror-Clerc, M., Davidson, P., & Davidson, A. (2000) · Journal of the American Chemical Society · doi:10.1021/ja002245h · Cited by 619
Molecular and Mesoscopic Structures of Transparent Block Copolymer−Silica Monoliths
Melosh, N. A., Lipic, P., Bates, F. S., Wudl, F., Stucky, G. D., Fredrickson, G. H., & Chmelka, B. F. (1999) · Macromolecules · doi:10.1021/ma9817323 · Cited by 291
Yu, C., Yu, Y., & Zhao, D. (2000) · Chemical Communications · doi:10.1039/b000603n · Cited by 272
Non-silica periodic mesostructured materials: recent progress
Sayari, A., & Liu, P. (1997) · Microporous Materials · doi:10.1016/s0927-6513(97)00059-x · Cited by 257
Holmqvist, P., Alexandridis, P., & Lindman, B. (1998) · The Journal of Physical Chemistry B · doi:10.1021/jp9730297 · Cited by 252
Grosso, D., Balkenende, A. R., Albouy, P. A., Ayral, A., Amenitsch, H., & Babonneau, F. (2001) · Chemistry of Materials · doi:10.1021/cm001225b · Cited by 248
Self-citationGeneralised syntheses of ordered mesoporous oxides: the atrane route
Cabrera, S., Haskouri, J. E., Guillem, C., Latorre, J., Beltrán-Porter, A., Beltrán-Porter, D., Marcos, M. D., & Amorós, P. (2000) · Solid State Sciences · doi:10.1016/s1293-2558(00)00152-7 · Cited by 241
Cagnol, F., Grosso, D., Soler-Illia, G. J. D. A. A., Crepaldi, E. L., Babonneau, F., Amenitsch, H., & Sanchez, C. (2003) · Journal of Materials Chemistry · doi:10.1039/b209640b · Cited by 211
Self-citationGrosso, D., Babonneau, F., Albouy, P.-A., Amenitsch, H., Balkenende, A. R., Brunet-Bruneau, A., & Rivory, J. (2002) · Chemistry of Materials · doi:10.1021/cm011255u · Cited by 207
Self-citationRecent advances in the formation mechanisms of organized mesoporous materials
Patarin, J., Lebeau, B., & Zana, R. (2002) · Current Opinion in Colloid & Interface Science · doi:10.1016/s1359-0294(02)00012-2 · Cited by 172
Soler–Illia, G. J. D. A. A., & Sanchez, C. (2000) · New Journal of Chemistry · doi:10.1039/b002518f · Cited by 170
Self-citationNanocrystalline Transition‐Metal Oxide Spheres with Controlled Multi‐Scale Porosity
Grosso, D., Soler‐Illia, G. J. A. A., Crepaldi, E. L., Charleux, B., & Sánchez, C. (2003) · Advanced Functional Materials · doi:10.1002/adfm.200390002 · Cited by 161
Self-citationFast preparation of highly ordered nonsiliceous mesoporous materials via mixed inorganic precursors
Tian, B., Yang, H., Liu, X., Xie, S., Yu, C., Fan, J., Tu, B., & Zhao, D. (2002) · Chem. Commun. · doi:10.1039/b205006d · Cited by 158
Çelik, Ö., & Dag, Ö. (2001) · Angewandte Chemie International Edition · doi:10.1002/1521-3773(20011015)40:20<3799::aid-anie3799>3.0.co;2-i · Cited by 149
Soler‐Illia, G. J. A. A., Crepaldi, E. L., Grosso, D., Durand, D., & Sánchez, C. (2002) · Chemical Communications · doi:10.1039/b207595d · Cited by 71
Self-citationGau, H., Lee, C.-S., Lin, C., Jiang, M.-K., Ho, Y., & Kuo, C.-N. (1996) · Journal of the American Chemical Society · doi:10.1021/ja952730q · Cited by 66
Yu, C., Yu, Y., Miao, L., & Zhao, D. (2001) · Microporous and Mesoporous Materials · doi:10.1016/s1387-1811(01)00169-x · Cited by 57
Cited by
On the controllable soft-templating approach to mesoporous silicates
Wan, Y., & Zhao (2007) · Chemical Reviews · doi:10.1021/cr068020s · Cited by 2,371
Cao, S.-W., & Zhu, Y.-J. (2010) · Nanoscale Research Letters · doi:10.1007/s11671-010-9742-7 · Cited by 2,357
Biomimetism and bioinspiration as tools for the design of innovative materials and systems
Sanchez, C., Arribart, H., & Giraud Guille, M. M. (2005) · Nature Materials · doi:10.1038/nmat1339 · Cited by 1,449
Self-citationPhotoelectrocatalytic materials for environmental applications
Zhang, H., Chen, G., & Bahnemann, D. W. (2009) · Journal of Materials Chemistry · doi:10.1039/b821991e · Cited by 960
Mesoporous materials and electrochemistry
Walcarius, A. (2013) · Chemical Society Reviews · doi:10.1039/c2cs35322a · Cited by 623
Metadata
- Authors
- Crepaldi, E. L., Soler-Illia, G. J. D. A. A., Grosso, D., Cagnol, F., Ribot, F., & Sanchez, C.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2003-07-17
- Volume
- 125
- Issue
- 32
- Pages
- 9770-9786
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2019645703
- Cited by
- 911
- References
- 45
- FWCI
- 36.24
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
