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Cited by 170

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Interactions between poly(ethylene oxide)-based surfactants and transition metal alkoxides: their role in the templated construction of mesostructured hybrid organic–inorganic composites

Soler–Illia, Galo J. de A. A., Sanchez, Clément·2000·New Journal of Chemistry
DOI 10.1039/b002518f
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Abstract

The interactions between PEO-based templates and metallic centres are key in the synthesis of mesostructured materials. In low-water-content media, strong chelation between metal centres and the non-ionic polar heads leads to polymer unfolding, and thus to worm-like phases. Larger quantities of water and acid added to the reaction bath weaken the coordination bonds that compose the hybrid interface. These resulting weak interactions (mainly hydrogen bonding) help the folding of the templating agents, and yield more ordered mesophases.

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Metadata

Authors
Soler–Illia, G. J. D. A. A., & Sanchez, C.
Venue
New Journal of Chemistry
Publisher
Royal Society of Chemistry (RSC)
Published
2000
Volume
24
Issue
7
Pages
493-499
ISSN
  • 0398-9836 (ISSN-L)
  • 1144-0546
  • 1369-9261
DOI
10.1039/b002518f
OpenAlex
W2069588604
Cited by
170
References
0
FWCI
7.65
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Interactions between poly(ethylene oxide)-based surfactants and transition metal alkoxides: their role in the templated construction of mesostructured hybrid organic–inorganic composites. https://app.cochat.ai/papers/10.1039/b002518f
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Soler–Illia, G. J. D. A. A., & Sanchez, C. (2000). Interactions between poly(ethylene oxide)-based surfactants and transition metal alkoxides: their role in the templated construction of mesostructured hybrid organic–inorganic composites. New Journal of Chemistry. https://doi.org/10.1039/b002518f

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.