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Electrochemical Property: Structure Relationships in Monoclinic Li3-yV2(PO4)3
Abstract
Monoclinic lithium vanadium phosphate, alpha-Li(3)V(2)(PO(4))(3), is a highly promising material proposed as a cathode for lithium-ion batteries. It possesses both good ion mobility and high lithium capacity because of its ability to reversibly extract all three lithium ions from the lattice. Here, using a combination of neutron diffraction and (7)Li MAS NMR studies, we are able to correlate the structural features in the series of single-phase materials Li(3-y)V(2)(PO(4))(3) with the electrochemical voltage-composition profile. A combination of charge ordering on the vanadium sites and lithium ordering/disordering among lattice sites is responsible for the features in the electrochemical curve, including the observed hysteresis. Importantly, this work highlights the importance of ion-ion interactions in determining phase transitions in these materials.
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Cited by
A multifunctional 3.5 V iron-based phosphate cathode for rechargeable batteries
Ellis, B. L., Makahnouk, W. R. M., Makimura, Y., Toghill, K., & Nazar, L. F. (2007) · Nature Materials · doi:10.1038/nmat2007 · Cited by 964
Self-citationCore−Shell Li3V2(PO4)3@C Composites as Cathode Materials for Lithium-Ion Batteries
Ren, M. M., Zhou, Z., Gao, X. P., Peng, W. X., & Wei, J. P. (2008) · The Journal of Physical Chemistry C · doi:10.1021/jp800040s · Cited by 262
A Na3V2(PO4)3 cathode material for use in hybrid lithium ion batteries
Song, W., Ji, X., Pan, C., Zhu, Y., Chen, Q., & Banks, C. E. (2013) · Physical Chemistry Chemical Physics · doi:10.1039/c3cp52308j · Cited by 126
Qin, R., Wei, Y., Zhai, T., & Li, H. (2018) · Journal of Materials Chemistry A · doi:10.1039/c8ta01124a · Cited by 58
Jian, Z., Han, W., Liang, Y., Lan, Y., Fang, Z., Hu, Y.-S., & Yao, Y. (2014) · J. Mater. Chem. A · doi:10.1039/c4ta04630g · Cited by 49
Metadata
- Authors
- Yin, S.-C., Grondey, H., Strobel, P., Anne, M., & Nazar, L. F.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2003-07-31
- Volume
- 125
- Issue
- 34
- Pages
- 10402-10411
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2114562870
- Cited by
- 546
- References
- 0
- FWCI
- 7.37
- Type
- journal article
- Language
- en
- Open access
- closed
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- Yin, S.-C., Grondey, H., Strobel, P., Anne, M., & Nazar, L. F. (2003). Electrochemical Property: Structure Relationships in Monoclinic Li3-yV2(PO4)3. Journal of the American Chemical Society. https://doi.org/10.1021/ja034565h
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