The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Prussian Blue Nanoparticles Protected by Poly(vinylpyrrolidone)
Abstract
Prussian blue (PB) nanoparticles protected by poly(vinylpyrrolidone) (PVP) were prepared by mixing aqueous Fe2+, Fe(CN)63-, and PVP solutions together and were characterized by UV-vis, IR, XRPD, and TEM. Averaged dimensions of the nanoparticles were controlled between 12 and 27 nm depending on initial Fe ion concentrations and feed ratios of Fe ion to PVP. Solubility of PB bulk in organic solvents is considerably low; nevertheless, formations of the PB nanoparticles dramatically increase the solubility in a variety of organic solvents. It is noteworthy that the PVP-protected PB nanoparticles stably maintain the cluster formations without further aggregations and dissociation in CHCl3 over 1 month. Measurement of the critical temperature (Tc) where PB nanoparticles exhibit a ferromagnetic property showed a gradual decrease of Tc for the nanoparticles as the particle sizes become smaller. This result could be ascribed to the reduction of the averaged numbers of magnetic interacted neighbors.
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Cites
Monodisperse FePt Nanoparticles and Ferromagnetic FePt Nanocrystal Superlattices
Sun, S., Murray, C. B., Weller, D., Folks, L., & Moser, A. (2000) · Science · doi:10.1126/science.287.5460.1989 · Cited by 6,137
Cited by
Sensor and biosensor preparation, optimisation and applications of Prussian Blue modified electrodes
Ricci, F., & Palleschi, G. (2005) · Biosensors and Bioelectronics · doi:10.1016/j.bios.2004.12.001 · Cited by 781
Controlled Multiscale Synthesis of Porous Coordination Polymer in Nano/Micro Regimes
Diring, S., Furukawa, S., Takashima, Y., Tsuruoka, T., & Kitagawa, S. (2010) · Chemistry of Materials · doi:10.1021/cm101778g · Cited by 527
Self-citationRecent advances in Prussian blue and Prussian blue analogues: synthesis and thermal treatments
Zakaria, M. B., & Chikyow, T. (2017) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2017.09.014 · Cited by 389
Metadata
- Authors
- Uemura, T., & Kitagawa, S.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2003-06-07
- Volume
- 125
- Issue
- 26
- Pages
- 7814-7815
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2053027138
- Cited by
- 456
- References
- 1
- FWCI
- 13.05
- Type
- journal article
- Language
- en
- Open access
- closed
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