The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Orthogonal Control of Dissociation Dynamics Relative to Thermodynamics in a Main-Chain Reversible Polymer
Abstract
A pair of homologous and soluble reversible polymers display nearly identical solution structures but dramatically different dissociation dynamics (1.0 vs ca. 100 s-1) along their main chains. The polymers are formed by organopalladium-pyridine coordination, and steric effects at the metal center control the dynamics. Importantly, the association constant is not significantly affected by the sterics. The resulting orthogonal control over dissociation kinetics provides a general tool for studying the effects of dynamics independent of thermodynamics in supramolecular systems, particularly main-chain reversible polymers.
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Cites
A chiroselective peptide replicator
Saghatelian, A., Yokobayashi, Y., Soltani, K., & Ghadiri, M. R. (2001) · Nature · doi:10.1038/35057238 · Cited by 310
Cited by
Weng, W., Beck, J. B., Jamieson, A. M., & Rowan, S. J. (2006) · Journal of the American Chemical Society · doi:10.1021/ja063408q · Cited by 531
Self-Sorting Organization of Two Heteroditopic Monomers to Supramolecular Alternating Copolymers
Wang, F., Han, C., He, C., Zhou, Q., Zhang, J., Wang, C., Li, N., & Huang, F. (2008) · Journal of the American Chemical Society · doi:10.1021/ja8035465 · Cited by 448
Yount, W. C., Loveless, D. M., & Craig, S. L. (2005) · Journal of the American Chemical Society · doi:10.1021/ja054298a · Cited by 388
Self-citationKautz, H., van Beek, D. J. M., Sijbesma, R. P., & Meijer, E. W. (2006) · Macromolecules · doi:10.1021/ma060706z · Cited by 263
Metadata
- Authors
- Yount, W. C., Juwarker, H., & Craig, S. L.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2003-11-20
- Volume
- 125
- Issue
- 50
- Pages
- 15302-15303
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2062274477
- Cited by
- 171
- References
- 1
- FWCI
- 7.04
- Type
- journal article
- Language
- en
- Open access
- closed
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