The DOI matches its Crossref record; 24 of the 24 references it cites were found in a registry or an index.
Controlled Functionalization of Multiwalled Carbon Nanotubes by in Situ Atom Transfer Radical Polymerization
Abstract
The in situ ATRP (atom transfer radical polymerization) "grafting from" approach was successfully applied to graft poly(methyl methacrylate) (PMMA) onto the convex surfaces of multiwalled carbon nanotubes (MWNT). The thickness of the coated polymer layers can be conveniently controlled by the feed ratio of MMA to preliminarily functionalized MWNT (MWNT-Br). The resulting MWNT-based polymer brushes were characterized and confirmed with FTIR, 1H NMR, SEM, TEM, and TGA. Moreover, the approach has been extended to the copolymerization system, affording novel hybrid core-shell nanoobjects with MWNT as the core and amphiphilic poly(methyl methacrylate)-block-poly(hydroxyethyl methacrylate) (PMMA-b-PHEMA) as the shell. The approach presented here may open an avenue for exploring and preparing novel carbon nanotubes-based nanomaterials and molecular devices with tailor-made structure, architecture, and properties.
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Cited by
Chemical oxidation of multiwalled carbon nanotubes
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Flexible Nanodielectric Materials with High Permittivity for Power Energy Storage
Dang, Z., Yuan, J., Yao, S., & Liao, R. (2013) · Advanced Materials · doi:10.1002/adma.201301752 · Cited by 1,454
In situ Polymerization Approach to Graphene-Reinforced Nylon-6 Composites
Xu, Z., & Gao, C. (2010) · Macromolecules · doi:10.1021/ma1009337 · Cited by 667
Self-citationPolymers containing fullerene or carbon nanotube structures
Wang, C., Guo, Z.-X., Fu, S., Wu, W., & Zhu, D. (2004) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2004.08.001 · Cited by 470
Metadata
- Authors
- Kong, H., Gao, C., & Yan, D.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2003-12-24
- Volume
- 126
- Issue
- 2
- Pages
- 412-413
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2152928931
- Cited by
- 658
- References
- 24
- FWCI
- 27.34
- Type
- journal article
- Language
- en
- Open access
- closed
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