The DOI matches its Crossref record; 11 of the 11 references it cites were found in a registry or an index.
Room-Temperature Catalytic Hydrodefluorination of C(sp3)−F Bonds
Abstract
Room-temperature catalytic hydrodefluorination of the strong C(sp3)-F bonds in benzotrifluorides and fluoropentane is catalyzed by Et3Si[B(C6F5)4] and uses Et3SiH as the source of H. Ar-CF3 compounds are converted to Ar-CH3 and fluropentane to pentane. The reaction is thought to proceed via abstraction of F- by Et3Si[B(C6F5)4], and the substituent effects are consistent with this hypothesis.
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Cites
A survey of Hammett substituent constants and resonance and field parameters
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The search for larger and more weakly coordinating anions
Strauss, S. H. (1993) · Chemical Reviews · doi:10.1021/cr00019a005 · Cited by 1,029
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Kiplinger, J. L., Richmond, T. G., & Osterberg, C. E. (1994) · Chemical Reviews · doi:10.1021/cr00026a005 · Cited by 789
Chemistry of organic fluorine compounds
Hudlický, M. (1961) · Medical Entomology and Zoology · Cited by 474
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Homogeneous rhodium complex-catalyzed hydrogenolysis of C-F bonds.
Aizenberg, M., & Milstein, D. (1995) · Journal of the American Chemical Society · doi:10.1021/ja00138a027 · Cited by 220
Reed, C. A., Kim, K., Stoyanov, E. S., Stasko, D. J., Tham, F. S., Mueller, L. J., & Boyd, P. D. W. (2003) · Journal of the American Chemical Society · doi:10.1021/ja027336o · Cited by 186
Infrared band intensities and global warming potentials of CF4, C2F6, C3F8, C4F10, C5F12, and C6F14
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Cited by
Main-Group Lewis Acids for C–F Bond Activation
Stahl, T., Klare, H. F. T., & Oestreich, M. (2013) · ACS Catalysis · doi:10.1021/cs4003244 · Cited by 470
Metadata
- Authors
- Scott, V. J., Çelenligil-Çetin, R., & Ozerov, O. V.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2005-02-08
- Volume
- 127
- Issue
- 9
- Pages
- 2852-2853
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2007131118
- Cited by
- 329
- References
- 11
- FWCI
- 6.42
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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