The DOI matches its Crossref record; 5 of the 5 references it cites were found in a registry or an index.
Catalytic Activation of Carbon-Fluorine Bonds by a Soluble Transition Metal Complex
Abstract
Homogeneous catalytic activation of the strong carbon-fluorine bonds under mild conditions was achieved with the use of rhodium complexes as catalysts. The catalytic reactions between polyfluorobenzenes and hydrosilanes result in substitution of fluorine atoms by hydrogen atoms and are chemo- and regioselective. With individual stoichiometric steps observed and combined, and with intermediates isolated and fully characterized (including crystal structures), these systems demonstrate the effectiveness of a rational approach to catalytic design.
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Cites
Catalytic Hydrogenation Over Platinum Metals
(1967) · Elsevier eBooks · doi:10.1016/b978-0-12-395532-6.x5001-6 · Cited by 549
Chemistry of organic fluorine compounds
Hudlický, M. (1961) · Medical Entomology and Zoology · Cited by 474
Defluorination of perfluoroolefins by divalent lanthanoid reagents: activating carbon-fluorine bonds
Watson, P. L., Tulip, T. H., & Williams, I. D. (1990) · Organometallics · doi:10.1021/om00157a006 · Cited by 237
Weydert, M., Andersen, R. A., & Bergman, R. G. (1993) · Journal of the American Chemical Society · doi:10.1021/ja00072a046 · Cited by 64
Electron transfer reactions involving trans-[PtH2(PCy3)2] and fluorinated benzonitriles
Hintermann, S., Pregosin, P. S., Rüegger, H., & Clark, H. C. (1992) · Journal of Organometallic Chemistry · doi:10.1016/0022-328x(92)83474-v · Cited by 43
Cited by
Room-Temperature Catalytic Hydrodefluorination of C(sp3)−F Bonds
Scott, V. J., Çelenligil-Çetin, R., & Ozerov, O. V. (2005) · Journal of the American Chemical Society · doi:10.1021/ja0426138 · Cited by 329
Enzyme-Catalyzed Ring-Opening Polymerization of ε-Caprolactone in Supercritical Carbon Dioxide
Loeker, F. C., Duxbury, C. J., Kumar, R., Gao, W., Gross, R. A., & Howdle, S. M. (2004) · Macromolecules · doi:10.1021/ma0349884 · Cited by 126
Bratton, D., Brown, M., & Howdle, S. M. (2003) · Macromolecules · doi:10.1021/ma034453a · Cited by 47
Metadata
- Authors
- Aizenberg, M., & Milstein, D.
- Venue
- Science
- Published
- 1994-07-15
- Volume
- 265
- Issue
- 5170
- Pages
- 359-361
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2062566916
- Cited by
- 391
- References
- 5
- FWCI
- 8.62
- Type
- journal article
- Language
- en
- Open access
- closed
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- Aizenberg, M., & Milstein, D. (1994). Catalytic Activation of Carbon-Fluorine Bonds by a Soluble Transition Metal Complex. Science. https://doi.org/10.1126/science.265.5170.359
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
