The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Cation Pool-Initiated Controlled/Living Polymerization Using Microsystems
Abstract
The "cation pool" of an N-acyliminium ion was found to serve as an effective initiator of cationic polymerization of vinyl ethers in a microsystem consisting of two micromixers and a microtube reactor. The polymerization led to very narrow molecular weight distribution (Mw/Mn = 1.14). The molecular weight (Mn) increased linearly with an increase in the amount of the monomer. The carbocationic polymer end was effectively trapped by allyltrimethylsilane. The present observations illustrate the potential of microsystems, in conjunction with the cation pool, to effect polymerization in a highly controlled manner without the deceleration inherent in the dynamic equilibrium between active and dormant species.
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Citations
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Kato, M., Kamigaito, M., Sawamoto, M., & Higashimura, T. (1995) · Macromolecules · doi:10.1021/ma00109a056 · Cited by 3,046
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Electrogenerated Cationic Reactive Intermediates: The Pool Method and Further Advances
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Yoshida, J., Nagaki, A., & Yamada, T. (2008) · Chemistry – A European Journal · doi:10.1002/chem.200800582 · Cited by 537
Self-citationFlash chemistry: flow chemistry that cannot be done in batch
Yoshida, J.-I., Takahashi, Y., & Nagaki, A. (2013) · Chem. Commun. · doi:10.1039/c3cc44709j · Cited by 450
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Metadata
- Authors
- Nagaki, A., Kawamura, K., Suga, S., Ando, T., Sawamoto, M., & Yoshida, J.-I.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2004-10-15
- Volume
- 126
- Issue
- 45
- Pages
- 14702-14703
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2076751343
- Cited by
- 211
- References
- 1
- FWCI
- 8.05
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
