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Electrogenerated Cationic Reactive Intermediates: The Pool Method and Further Advances
Abstract
Electrochemistry serves as a powerful method for generating reactive intermediates, such as organic cations. In general, there are two ways to use reactive intermediates for chemical reactions: (1) generation in the presence of a reaction partner and (2) generation in the absence of a reaction partner with accumulation in solution as a "pool" followed by reaction with a subsequently added reaction partner. The former approach is more popular because reactive intermediates are usually short-lived transient species, but the latter method is more flexible and versatile. This review focuses on the latter approach and provides a concise overview of the current methods for the generation and accumulation of cationic reactive intermediates as a pool using modern techniques of electrochemistry and their reactions with subsequently added nucleophilic reaction partners.
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Modern Strategies in Electroorganic Synthesis
Yoshida, J.-I., Kataoka, K., Horcajada, R., & Nagaki, A. (2008) · Chemical Reviews · doi:10.1021/cr0680843 · Cited by 1,417
Self-citationDiaryliodonium Salts: A Journey from Obscurity to Fame
Merritt, E. A., & Olofsson, B. (2009) · Angewandte Chemie International Edition · doi:10.1002/anie.200904689 · Cited by 1,188
Activated Dimethyl Sulfoxide: Useful Reagents for Synthesis
Mancuso, A. J., & Swern, D. (1981) · Synthesis · doi:10.1055/s-1981-29377 · Cited by 1,160
Synthetic Organic Electrochemistry: An Enabling and Innately Sustainable Method
Horn, E. J., Rosen, B. R., & Baran, P. S. (2016) · ACS Central Science · doi:10.1021/acscentsci.6b00091 · Cited by 1,068
Living polymerization of isobutyl vinyl ether with hydrogen iodide/iodine initiating system
Miyamoto, M., Sawamoto, M., & Higashimura, T. (1984) · Macromolecules · doi:10.1021/ma00133a001 · Cited by 479
Direct α‐Functionalization of Saturated Cyclic Amines
Mitchell, E. A., Peschiulli, A., Lefevre, N., Meerpoel, L., & Maes, B. U. W. (2012) · Chemistry – A European Journal · doi:10.1002/chem.201201539 · Cited by 452
Understanding Reactivity Patterns of Radical Cations
Schmittel, M., & Burghart, A. (1997) · Angewandte Chemie International Edition in English · doi:10.1002/anie.199725501 · Cited by 362
Suga, S., Okajima, M., Fujiwara, K., & Yoshida, J. (2001) · Journal of the American Chemical Society · doi:10.1021/ja015823i · Cited by 247
Self-citationProstaglandin Syntheses by Three‐Component Coupling. New Synthetic Methods (49)
Noyori, R., & Suzuki, M. (1984) · Angewandte Chemie International Edition in English · doi:10.1002/anie.198408471 · Cited by 239
Cation Pool-Initiated Controlled/Living Polymerization Using Microsystems
Nagaki, A., Kawamura, K., Suga, S., Ando, T., Sawamoto, M., & Yoshida, J. (2004) · Journal of the American Chemical Society · doi:10.1021/ja044879k · Cited by 218
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Direct electrochemical defluorinative carboxylation of α-CF 3 alkenes with carbon dioxide
Gao, X.-T., Zhang, Z., Wang, X., Tian, J.-S., Xie, S.-L., Zhou, F., & Zhou, J. (2020) · Chemical Science · doi:10.1039/d0sc04091f · Cited by 142
Metadata
- Authors
- Yoshida, J.-I., Shimizu, A., & Hayashi, R.
- Venue
- Chemical Reviews
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-10-27
- Volume
- 118
- Issue
- 9
- Pages
- 4702-4730
- ISSN
- 0009-2665 (ISSN-L)
- 1520-6890
- OpenAlex
- W2766726503
- Cited by
- 555
- References
- 27
- FWCI
- 2.20
- Type
- journal article
- Language
- en
- Open access
- closed
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