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Hybrid Microgels Photoresponsive in the Near-Infrared Spectral Range
Abstract
We report for the first time a photothermally responsive composite material based on polymer microgel particles doped with gold nanorods. We used the dependence of the longitudinal surface plasmon of the gold nanorods on their aspect ratio to synthesize nanoparticles with strong absorption in the near-IR spectral range (in the "water window"). The nanoparticles were incorporated in the interior of temperature-responsive poly(N-isopropylacrylamide-acrylic acid) microgels. Upon irradiation at lambda = 810 nm, hybrid microgel particles doped with Au nanorods underwent a strong deswelling phase transition. These photothermally responsive microgels can be used to carry and release small molecules (e.g., small protein molecules and drugs).
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Cited by
Gold Nanorods: From Synthesis and Properties to Biological and Biomedical Applications
Huang, X., Neretina, S., & El‐Sayed, M. A. (2009) · Advanced Materials · doi:10.1002/adma.200802789 · Cited by 1,921
Light‐sensitive Intelligent Drug Delivery Systems†
Alvarez‐Lorenzo, C., Bromberg, L., & Concheiro, A. (2009) · Photochemistry and Photobiology · doi:10.1111/j.1751-1097.2008.00530.x · Cited by 519
Self-Assembly of Amphiphilic Plasmonic Micelle-Like Nanoparticles in Selective Solvents
He, J., Huang, X., Li, Y.-C., Liu, Y., Babu, T., Aronova, M. A., Wang, S., Lu, Z., Chen, X., & Nie, Z. (2013) · Journal of the American Chemical Society · doi:10.1021/ja402015s · Cited by 288
Biomimetic Smart Interface Materials for Biological Applications
Sun, T., & Qing, G. (2011) · Advanced Materials · doi:10.1002/adma.201004326 · Cited by 261
Photoresponsive Surfactants in Microgel Dispersions
Bradley, M., Vincent, B., Warren, N., Eastoe, J., & Vesperinas, A. (2006) · Langmuir · doi:10.1021/la0523053 · Cited by 52
Metadata
- Authors
- Gorelikov, I., Field, L. M., & Kumacheva, E.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2004-11-16
- Volume
- 126
- Issue
- 49
- Pages
- 15938-15939
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2083861750
- Cited by
- 329
- References
- 0
- FWCI
- 6.79
- Type
- journal article
- Language
- en
- Open access
- closed
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