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Synthetic Architectures of TiO2/H2Ti5O11·H2O, ZnO/H2Ti5O11·H2O, ZnO/TiO2/H2Ti5O11·H2O, and ZnO/TiO2 Nanocomposites

Yang, Hua Gui, Zeng, Hua Chun·2005·Journal of the American Chemical Society

Abstract

Although synthetic investigations of inorganic nanomaterials had been carried out extensively over the past decade, few of them have been devoted to fabrication of complex nanostructures that comprise multicomponents/phases (i.e., composite nanobuilding blocks), especially in the area of structural/morphological architecture. In this work, nanobelts of a protonated pentatitanate (H(2)Ti(5)O(11).H(2)O) were synthesized hydrothermally for the first time. Two technologically important transition-metal-oxides TiO(2) and ZnO were then grown respectively or sequentially onto the surface of the as-prepared nanobelts in aqueous mediums. With a main emphasis on organizational manipulation, the present investigation examines general issues of morphological complexity, synthetic interconvertibility, and material combinability related to fabrication of inorganic nanocomposites. Using this model material system, we demonstrate that complex binary and tertiary composite building blocks of TiO(2)/H(2)Ti(5)O(11).H(2)O, ZnO/H(2)Ti(5)O(11).H(2)O, ZnO/TiO(2)/H(2)Ti(5)O(11).H(2)O, and ZnO/TiO(2) can be architected stepwise in solution. Structural features of these nanocomposites have also been addressed.

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Metadata

Authors
Yang, H. G., & Zeng, H. C.
Venue
Journal of the American Chemical Society
Published
2004-12-13
Volume
127
Issue
1
Pages
270-278
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W2325819330
Cited by
161
References
2
FWCI
6.67
Type
journal article
Language
en
Open access
closed

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