The DOI matches its Crossref record; 15 of the 15 references it cites were found in a registry or an index.
Reactivity of Aqueous Fe(IV) in Hydride and Hydrogen Atom Transfer Reactions
Abstract
Oxidation of cyclobutanol by aqueous Fe(IV) generates cyclobutanone in approximately 70% yield. In addition to this two-electron process, a smaller fraction of the reaction takes place by a one-electron process, believed to yield ring-opened products. A series of aliphatic alcohols, aldehydes, and ethers also react in parallel hydrogen atom and hydride transfer reactions, but acetone and acetonitrile react by hydrogen atom transfer only. Precise rate constants for each pathway for a number of substrates were obtained from a combination of detailed kinetics and product studies and kinetic simulations. Solvent kinetic isotope effect for the self-decay of Fe(IV), kH2O/kD2O = 2.8, is consistent with hydrogen atom abstraction from water.
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Zong, Y., Shao, Y., Zeng, Y., Shao, B., Xu, L., Zhao, Z., Liu, W., & Wu, D. (2021) · Environmental Science & Technology · doi:10.1021/acs.est.1c00375 · Cited by 499
Fenton chemistry at aqueous interfaces
Enami, S., Sakamoto, Y., & Colussi, A. J. (2014) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1314885111 · Cited by 349
Metadata
- Authors
- Pestovsky, O., & Bakac, A.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2004-10-01
- Volume
- 126
- Issue
- 42
- Pages
- 13757-13764
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2099872405
- Cited by
- 313
- References
- 15
- FWCI
- 3.81
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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