The DOI matches its Crossref record; 79 of the 79 references it cites were found in a registry or an index.
Fenton chemistry at aqueous interfaces
Open accessAbstract
Significance: The Fenton reaction, Fe 2+ + H 2 O 2 , plays fundamental roles in vivo and in advanced oxidation processes. Its mechanism and the identity of the intermediates involved, however, remain controversial. Here we present direct, mass-specific evidence of the prompt formation of mono- and poly-iron Fe IV =O (ferryl) species on the surface of aqueous FeCl 2 microjets exposed to gaseous H 2 O 2 or O 3 beams. Remarkably, Fe 2+ ions at the aqueous surface react with H 2 O 2 and O 3 >10 3 times faster than Fe(H 2 O) 6 2+ in bulk water. Our results suggest that interfacial Fenton and Fenton-like chemistries could play a more significant role than hitherto envisioned.
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Atmospheric Chemistry and Physics: From Air Pollution to Climate Change
Seinfeld, J. H., Pandis, S. N., & Noone, K. (1998) · Physics Today · doi:10.1063/1.882420 · Cited by 8,731
Atmospheric chemistry and physics: from air pollution to climate change
(2007) · Choice Reviews Online · doi:10.5860/choice.44-4512 · Cited by 4,124
LXXIII.—Oxidation of tartaric acid in presence of iron
Fenton, H. J. H. (1894) · J. Chem. Soc., Trans. · doi:10.1039/ct8946500899 · Cited by 3,179
A Common Mechanism of Cellular Death Induced by Bactericidal Antibiotics
Kohanski, M. A., Dwyer, D. J., Hayete, B., Lawrence, C. A., & Collins, J. J. (2007) · Cell · doi:10.1016/j.cell.2007.06.049 · Cited by 2,982
Antimicrobial activity of metals: mechanisms, molecular targets and applications
Lemire, J. A., Harrison, J. J., & Turner, R. J. (2013) · Nature Reviews Microbiology · doi:10.1038/nrmicro3028 · Cited by 2,746
H 2 O 2 , a Necessary Evil for Cell Signaling
Rhee, S. G. (2006) · Science · doi:10.1126/science.1130481 · Cited by 2,160
Chemistry of the Upper and Lower Atmosphere
(2000) · Elsevier eBooks · doi:10.1016/b978-0-12-257060-5.x5000-x · Cited by 1,796
Advanced Oxidation Processes for Wastewater Treatment: Formation of Hydroxyl Radical and Application
WANG, J. L., & XU, L. J. (2012) · Critical Reviews in Environmental Science and Technology · doi:10.1080/10643389.2010.507698 · Cited by 1,586
Oxidation of tartaric acid in presence of iron
Fenton, H. J. H. (1894) · Journal of the Chemical Society (Resumed) · Cited by 1,498
Heterogeneous chemistry and tropospheric ozone
Jacob, D. (2000) · Atmospheric Environment · doi:10.1016/s1352-2310(99)00462-8 · Cited by 1,289
Cited by
Li, X., Wang, Z., Zhang, B., Rykov, A. I., Ahmed, M. A., & Wang, J. (2016) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2015.08.050 · Cited by 473
Molecular reactions at aqueous interfaces
Ruiz-Lopez, M. F., Francisco, J. S., Martins-Costa, M. T. C., & Anglada, J. M. (2020) · Nature Reviews Chemistry · doi:10.1038/s41570-020-0203-2 · Cited by 411
Adachi, T., Tanaka, H., Nonomura, S., Hara, H., Kondo, S.-I., & Hori, M. (2015) · Free Radical Biology and Medicine · doi:10.1016/j.freeradbiomed.2014.11.014 · Cited by 334
Fluorescent probes for the detection of catalytic Fe(II) ion
Hirayama, T. (2019) · Free Radical Biology and Medicine · doi:10.1016/j.freeradbiomed.2018.07.004 · Cited by 79
The microbial contribution to reactive oxygen species dynamics in marine ecosystems
Zinser, E. R. (2018) · Environmental Microbiology Reports · doi:10.1111/1758-2229.12626 · Cited by 78
Metadata
- Authors
- Enami, S., Sakamoto, Y., & Colussi, A. J.
- Venue
- Proceedings of the National Academy of Sciences
- Published
- 2013-12-30
- Volume
- 111
- Issue
- 2
- Pages
- 623-628
- ISSN
- 0027-8424 (ISSN-L)
- 1091-6490
- OpenAlex
- W1993130948
- Cited by
- 349
- References
- 79
- FWCI
- 7.54
- Type
- journal article
- Language
- en
- Open access
- green
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