Heterogeneous or Homogeneous Catalysis? Mechanistic Studies of the Rhodium-Catalyzed Dehydrocoupling of Amine-Borane and Phosphine-Borane Adducts

Large clusters and colloids. Metals in the embryonic state

Schmid, G. (1992) · Chemical Reviews · doi:10.1021/cr00016a002 · Cited by 1,867

Reduced Transition Metal Colloids: A Novel Family of Reusable Catalysts?

Roucoux, A., Schulz, J., & Patin, H. (2002) · Chemical Reviews · doi:10.1021/cr010350j · Cited by 1,864

Ultraviolet–visible absorption spectra of the colloidal metallic elements

Creighton, J. A., & Eadon, D. G. (1991) · J. Chem. Soc., Faraday Trans. · doi:10.1039/ft9918703881 · Cited by 1,625

A review of the problem of distinguishing true homogeneous catalysis from soluble or other metal-particle heterogeneous catalysis under reducing conditions

Widegren, J. A., & Finke, R. G. (2003) · Journal of Molecular Catalysis A: Chemical · doi:10.1016/s1381-1169(02)00728-8 · Cited by 1,245

Transition Metal Nanocluster Formation Kinetic and Mechanistic Studies. A New Mechanism When Hydrogen Is the Reductant: Slow, Continuous Nucleation and Fast Autocatalytic Surface Growth

Watzky, M. A., & Finke, R. G. (1997) · Journal of the American Chemical Society · doi:10.1021/ja9705102 · Cited by 951

Exchange reactions of hydrogen on metallic catalysts

Horiuti, I., & Polanyi, M. (1934) · Transactions of the Faraday Society · doi:10.1039/tf9343001164 · Cited by 934

Transition Metal-Catalyzed Formation of Boron−Nitrogen Bonds: Catalytic Dehydrocoupling of Amine-Borane Adducts to Form Aminoboranes and Borazines

Jaska, C. A., Temple, K., Lough, A. J., & Manners, I. (2003) · Journal of the American Chemical Society · doi:10.1021/ja030160l · Cited by 599

Formation of Colloidal Transition Metals in Organic Phases and Their Application in Catalysis

Bönnemann, H., Brijoux, W., Brinkmann, R., Joußen, T., Korall, B., & Dinjus, E. (1991) · Angewandte Chemie International Edition in English · doi:10.1002/anie.199113121 · Cited by 380

Nanoscale colloidal metals and alloys stabilized by solvents and surfactants Preparation and use as catalyst precursors

Bönnemann, H., Braun, G., Brijoux, W., Brinkmann, R., Tilling, A. S., Seevogel, K., & Siepen, K. (1996) · Journal of Organometallic Chemistry · doi:10.1016/0022-328x(96)06273-0 · Cited by 354

Platinum-catalyzed hydrosilylation - colloid formation as the essential step

Lewis, L. N., & Lewis, N. (1986) · Journal of the American Chemical Society · doi:10.1021/ja00283a016 · Cited by 348

Are Heterogeneous Catalysts Precursors to Homogeneous Catalysts?

Davies, I. W., Matty, L., Hughes, D. L., & Reider, P. J. (2001) · Journal of the American Chemical Society · doi:10.1021/ja016877v · Cited by 328

In Situ Determination of the Active Catalyst in Hydrosilylation Reactions Using Highly Reactive Pt(0) Catalyst Precursors

Stein, J., Lewis, L. N., Gao, Y., & Scott, R. A. (1999) · Journal of the American Chemical Society · doi:10.1021/ja9825377 · Cited by 323

A More General Approach to Distinguishing "Homogeneous" from "Heterogeneous" Catalysis: Discovery of Polyoxoanion- and Bu4N+-Stabilized, Isolable and Redissolvable, High-Reactivity Ir.apprx.190-450 Nanocluster Catalysts

Lin, Y., & Finke, R. G. (1994) · Inorganic Chemistry · doi:10.1021/ic00100a012 · Cited by 300

Rhodium-catalyzed formation of boron–nitrogen bonds: a mild route to cyclic aminoboranes and borazines

Jaska, C. A., Temple, K., Lough, A. J., & Manners, I. (2001) · Chemical Communications · doi:10.1039/b102361f · Cited by 253

Is It Homogeneous or Heterogeneous Catalysis? Identification of Bulk Ruthenium Metal as the True Catalyst in Benzene Hydrogenations Starting with the Monometallic Precursor, Ru(II)(η6-C6Me6)(OAc)2, Plus Kinetic Characterization of the Heterogeneous Nucleation, Then Autocatalytic Surface-Growth Mechanism of Metal Film Formation

Widegren, J. A., Bennett, M. A., & Finke, R. G. (2003) · Journal of the American Chemical Society · doi:10.1021/ja021436c · Cited by 244

Novel Polyoxoanion- and Bu4N+-Stabilized, Isolable, and Redissolvable, 20-30-.ANG. Ir300-900 Nanoclusters: The Kinetically Controlled Synthesis, Characterization, and Mechanism of Formation of Organic Solvent-Soluble, Reproducible Size, and Reproducible Catalytic Activity Metal Nanoclusters

Lin, Y., & Finke, R. G. (1994) · Journal of the American Chemical Society · doi:10.1021/ja00097a047 · Cited by 238

Transition Metal-Catalyzed Formation of Phosphorus−Boron Bonds: A New Route to Phosphinoborane Rings, Chains, and Macromolecules

Dorn, H., Singh, R. A., Massey, J. A., Nelson, J. M., Jaska, C. A., Lough, A. J., & Manners, I. (2000) · Journal of the American Chemical Society · doi:10.1021/ja000732r · Cited by 215

Stabilized Rhodium(0) Nanoparticles: A Reusable Hydrogenation Catalyst for Arene Derivatives in a Biphasic Water-Liquid System

Schulz, J., Roucoux, A., & Patin, H. (2000) · Chemistry - A European Journal · doi:10.1002/(sici)1521-3765(20000218)6:4<618::aid-chem618>3.0.co;2-a · Cited by 197

Rh(0) Nanoclusters in Benzene Hydrogenation Catalysis: Kinetic and Mechanistic Evidence that a Putative [(C8H17)3NCH3]+[RhCl4]-Ion-Pair Catalyst Is Actually a Distribution of Cl-and [(C8H17)3NCH3]+Stabilized Rh(0) Nanoclusters

Weddle, K. S., Aiken, J. D., & Finke, R. G. (1998) · Journal of the American Chemical Society · doi:10.1021/ja973045h · Cited by 193

Developments in transition metal cluster chemistry — The way to large clusters

Schmid, G. (2005) · Structure and Bonding · doi:10.1007/bfb0009185 · Cited by 158

Ruthenium-Catalyzed Heck-Type Olefination and Suzuki Coupling Reactions: Studies on the Nature of Catalytic Species

Na, Y., Park, S., Han, S. B., Han, H., Ko, S., & Chang, S. (2003) · Journal of the American Chemical Society · doi:10.1021/ja038742q · Cited by 152

Synthesis, Characterization, and Properties of the Polyphosphinoboranes [RPH−BH2]n(R = Ph,iBu,p-nBuC6H4,p-dodecylC6H4): Inorganic Polymers with a Phosphorus−Boron Backbone

Dorn, H., Rodezno, J. M., Brunnhöfer, B., et al. (2002) · Macromolecules · doi:10.1021/ma021447q · Cited by 116

The Nature of the Active Catalyst in Late Transition Metal-Mediated Ring-Opening Polymerization (ROP) Reactions: Mechanistic Studies of the Platinum-Catalyzed ROP of Silicon-Bridged [1]Ferrocenophanes

Temple, K., Jäkle, F., Sheridan, J. B., & Manners, I. (2001) · Journal of the American Chemical Society · doi:10.1021/ja0033739 · Cited by 105

Ambient Temperature, Tandem Catalytic Dehydrocoupling−Hydrogenation Reactions Using Rh Colloids and Me2NH·BH3 as a Stoichiometric H2 Source

Jaska, C. A., & Manners, I. (2004) · Journal of the American Chemical Society · doi:10.1021/ja039696x · Cited by 93

Activity and resistance to leaching of Cu-based catalysts in the wet oxidation of phenol

Arena, F., Giovenco, R., Torre, T., Venuto, A., & Parmaliana, A. (2003) · Applied Catalysis B: Environmental · doi:10.1016/s0926-3373(03)00163-2 · Cited by 91

Transition-Metal Nanocluster Kinetic and Mechanistic Studies Emphasizing Nanocluster Agglomeration: Demonstration of a Kinetic Method That Allows Monitoring of All Three Phases of Nanocluster Formation and Aging

Hornstein, B. J., & Finke, R. G. (2003) · Chemistry of Materials · doi:10.1021/cm034585i · Cited by 90

Chemistry of Phosphine–Borane Adducts at Platinum Centers: Synthesis and Reactivity of PtII Complexes with Phosphinoborane Ligands

Jaska, C. A., Dorn, H., Lough, A. J., & Manners, I. (2002) · Chemistry - A European Journal · doi:10.1002/chem.200390020 · Cited by 60

Studies of boron-Nitrogen Compounds. VIII.1 Nuclear Magnetic Resonance Studies of Some μ-Aminodiboranes and Amine Boranes

Gaines, D. F., & Schaeffer, R. (1964) · Journal of the American Chemical Society · doi:10.1021/ja01062a011 · Cited by 58

Preparation of Hydrophobically Modified Poly(amidoamine) Dendrimer-Encapsulated Gold Nanoparticles in Organic Solvents

Esumi, K., Hosoya, T., Suzuki, A., et al. (2000) · Journal of Colloid and Interface Science · doi:10.1006/jcis.2000.6970 · Cited by 55

Synthesis of isobutanol by the Guerbet condensation of methanol with n-propanol in the presence of heterogeneous and homogeneous palladium-based catalytic systems

Carlini, C. (2003) · Journal of Molecular Catalysis A Chemical · doi:10.1016/s1381-1169(03)00357-1 · Cited by 51

Intermediates in the formation of N-methylaminoborane trimer and N,N-dimethylaminoborane dimer

Beachley, O. T. (1967) · Inorganic Chemistry · doi:10.1021/ic50051a004 · Cited by 28

B–N compounds for chemical hydrogenstorage

Hamilton, C. W., Baker, R. T., Staubitz, A., & Manners, I. (2009) · Chem. Soc. Rev. · doi:10.1039/b800312m · Cited by 1,087

Efficient Catalysis of Ammonia Borane Dehydrogenation

Denney, M. C., Pons, V., Hebden, T. J., Heinekey, D. M., & Goldberg, K. I. (2006) · Journal of the American Chemical Society · doi:10.1021/ja062419g · Cited by 630

Catalytic activities of non-noble metals for hydrogen generation from aqueous ammonia–borane at room temperature

Xu, Q., & Chandra, M. (2006) · Journal of Power Sources · doi:10.1016/j.jpowsour.2006.09.043 · Cited by 601

Transition-metal nanocluster stabilization for catalysis: A critical review of ranking methods and putative stabilizers

Ott, L. S., & Finke, R. G. (2007) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2006.08.016 · Cited by 454

Nanocluster nucleation and growth kinetic and mechanistic studies: A review emphasizing transition-metal nanoclusters

Finney, E. E., & Finke, R. G. (2008) · Journal of Colloid and Interface Science · doi:10.1016/j.jcis.2007.05.092 · Cited by 377